Ab-initio modeling of water-semiconductor interfaces for direct solar-to-chemical energy conversion (open access)

Ab-initio modeling of water-semiconductor interfaces for direct solar-to-chemical energy conversion

None
Date: June 30, 2010
Creator: Wood, B; Ogitsu, T & Schwegler, E
Object Type: Article
System: The UNT Digital Library
American Recovery and Reinvestment Act (ARRA) FEMP Technical Assistance Federal Aviation Administration – Project 209 Control Tower and Support Building, Reno, Nevada (open access)

American Recovery and Reinvestment Act (ARRA) FEMP Technical Assistance Federal Aviation Administration – Project 209 Control Tower and Support Building, Reno, Nevada

Pacific Northwest National Laboratory (PNNL) and Redhorse Corporation (Redhorse) conducted an energy audit on the Federal Aviation Administration (FAA) control tower and base building in Reno, Nevada. This report presents the findings of the energy audit team that evaluated construction documents and operating specifications (at the 100% level) and completed a site visit. The focus of the review was to identify measures that could be incorporated into the final design and operating specifications that would result in additional energy savings for the FAA that would not have otherwise occurred.
Date: June 30, 2010
Creator: Arends, J. & Sandusky, William F.
Object Type: Report
System: The UNT Digital Library
The Americans with Disabilities Act and Emergency Preparedness and Response (open access)

The Americans with Disabilities Act and Emergency Preparedness and Response

This report discusses the Americans with Disabilities Act (ADA), which provides broad nondiscrimination protection for individuals with disabilities in employment, public services, and public accommodations and services operated by private entities. Although the ADA does not include provisions specifically discussing its application to disasters, its nondiscrimination provisions are applicable to emergency preparedness and responses to disasters.
Date: June 30, 2010
Creator: Jones, Nancy Lee
Object Type: Report
System: The UNT Digital Library
Armenia, Azerbaijan, and Georgia: Political Developments and Implications for U.S. Interests (open access)

Armenia, Azerbaijan, and Georgia: Political Developments and Implications for U.S. Interests

This report discusses the history and political background of Armenia, Azerbaijan, and Georgia since breaking away from the former Soviet Union at the end of 1991. It looks at key issues for the 112th Congress including economies, energy, regional politics, local crime, and terrorism.
Date: June 30, 2010
Creator: Nichol, Jim
Object Type: Report
System: The UNT Digital Library
Aviation Security: Progress Made but Actions Needed to Address Challenges in Meeting the Air Cargo Screening Mandate (open access)

Aviation Security: Progress Made but Actions Needed to Address Challenges in Meeting the Air Cargo Screening Mandate

Testimony issued by the Government Accountability Office with an abstract that begins "This testimony discusses air cargo screening. In 2008, about 7.3 billion pounds of cargo was transported on U.S. passenger flights--approximately 58 percent of which was transported domestically (domestic cargo) and 42 percent of which was transported on flights arriving in the United States from a foreign location (inbound cargo). The 2009 Christmas Day plot to detonate an explosive device during an international flight bound for Detroit provided a vivid reminder that terrorists continue to view passenger aircraft as attractive targets. According to the Transportation Security Administration (TSA), the security threat posed by terrorists introducing explosive devices in air cargo shipments is significant, and the risk and likelihood of such an attack directed at passenger aircraft is high. To help enhance the security of air cargo, the Implementing Recommendations of the 9/11 Commission Act of 2007 (9/11 Commission Act) mandated the Department of Homeland Security (DHS) to establish a system to physically screen 50 percent of cargo on passenger aircraft--including the domestic and inbound flights of foreign and U.S. passenger operations--by February 2009, and 100 percent of such cargo by August 2010. The 9/11 Commission Act defines screening for …
Date: June 30, 2010
Creator: United States. Government Accountability Office.
Object Type: Text
System: The UNT Digital Library
Biosurveillance: Efforts to Develop a National Biosurveillance Capability Need a National Strategy and a Designated Leader (open access)

Biosurveillance: Efforts to Develop a National Biosurveillance Capability Need a National Strategy and a Designated Leader

A letter report issued by the Government Accountability Office with an abstract that begins "The U.S. government has a history of employing health surveillance to help limit malady, loss of life, and economic impact of diseases. Recent legislation and presidential directives have called for a robust and integrated biosurveillance capability; that is, the ability to provide early detection and situational awareness of potentially catastrophic biological events. The Implementing Recommendations of the 9/11 Commission Act directed GAO to report on the state of biosurveillance and resource use in federal, state, local, and tribal governments. This report is one in a series responding to that mandate. This report addresses (1) federal efforts that support a national biosurveillance capability and (2) the extent to which mechanisms are in place to guide the development of a national biosurveillance capability. To conduct this work, GAO reviewed federal biosurveillance programs, plans, and strategies and interviewed agency officials from components of 12 federal departments with biosurveillance responsibilities."
Date: June 30, 2010
Creator: United States. Government Accountability Office.
Object Type: Report
System: The UNT Digital Library
Brazil’s WTO Case Against the U.S. Cotton Program (open access)

Brazil’s WTO Case Against the U.S. Cotton Program

U.S. and Brazilian trade negotiators reached agreement on June 17, 2010, on a "Framework agreement" regarding a World Trade Organization dispute settlement case over U.S. cotton subsidies and GSM-102 agricultural export credit guarantees. The Framework agreement - which lays out a number of "steps and discussions" - represents a path forward toward the ultimate goal of reaching a negotiated solution to the dispute, while avoiding World Trade Organization-sanctioned trade retaliation by Brazil against U.S. goods and services. This report includes information on the dispute, panel recommendations, implementation of recommendations, compliance panel review and ruling, arbitration of Brazil's proposed countermeasures, and more related the dispute.
Date: June 30, 2010
Creator: Schnepf, Randy
Object Type: Report
System: The UNT Digital Library
Brazil's WTO Case Against the U.S. Cotton Program (open access)

Brazil's WTO Case Against the U.S. Cotton Program

This report provides a description and status report on Brazil's challenge to certain aspects of the U.S. cotton program under the rules of the World Trade Organization's (WTO's) dispute settlement process in case DS267.1 The "Brazil cotton case" had its WTO origins in 2002 and has since evolved into a sprawling legal enterprise that is still ongoing as of mid-2010. The report begins by summarizing the most recent developments in the case. It then provides a detailed history of the case in chronological phases. Readers interested in the current status of the dispute, and in particular details of the negotiations to reach a mutual settlement and avoid trade retaliation against U.S. goods and services, should proceed directly to the report section entitled "Phase V: Retaliation or Settlement?"
Date: June 30, 2010
Creator: Schnepf, Randy
Object Type: Report
System: The UNT Digital Library
Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks (open access)

Carbon Dioxide Removal from Flue Gas Using Microporous Metal Organic Frameworks

UOP LLC, a Honeywell Company, in collaboration with Professor Douglas LeVan at Vanderbilt University (VU), Professor Adam Matzger at the University of Michigan (UM), Professor Randall Snurr at Northwestern University (NU), and Professor Stefano Brandani at the University of Edinburgh (UE), supported by Honeywell's Specialty Materials business unit and the Electric Power Research Institute (EPRI), have completed a three-year project to develop novel microporous metal organic frameworks (MOFs) and an associated vacuum-pressure swing adsorption (vPSA) process for the removal of CO{sub 2} from coal-fired power plant flue gas. The project leveraged the team's complementary capabilities: UOP's experience in materials development and manufacturing, adsorption process design and process commercialization; LeVan and Brandani's expertise in high-quality adsorption measurements; Matzger's experience in syntheis of MOFs and the organic components associated with MOFs; Snurr's expertise in molecular and other modeling; Honeywell's expertise in the manufacture of organic chemicals; and, EPRI's knowledge of power-generation technology and markets. The project was successful in that a selective CO{sub 2} adsorbent with good thermal stability and reasonable contaminant tolerance was discovered, and a low cost process for flue gas CO{sub 2} capture process ready to be evaluated further at the pilot scale was proposed. The team made significant …
Date: June 30, 2010
Creator: Lesch, David A.
Object Type: Report
System: The UNT Digital Library
Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas (open access)

Carbon Mineralization by Aqueous Precipitation for Beneficial Use of CO2 from Flue Gas

Calera's innovative Mineralization via Aqueous Precipitation (MAP) technology for the capture and conversion of CO{sub 2} to useful materials for use in the built environment was further developed and proven in the Phase 1 Department of Energy Grant. The process was scaled to 300 gallon batch reactors and subsequently to Pilot Plant scale for the continuous production of product with the production of reactive calcium carbonate material that was evaluated as a supplementary cementitious material (SCM). The Calera SCM{trademark} was evaluated as a 20% replacement for ordinary portland cement and demonstrated to meet the industry specification ASTM 1157 which is a standard performance specification for hydraulic cement. The performance of the 20% replacement material was comparable to the 100% ordinary portland cement control in terms of compressive strength and workability as measured by a variety of ASTM standard tests. In addition to the performance metrics, detailed characterization of the Calera SCM was performed using advanced analytical techniques to better understand the material interaction with the phases of ordinary portland cement. X-ray synchrotron diffraction studies at the Advanced Photon Source in Argonne National Lab confirmed the presence of an amorphous phase(s) in addition to the crystalline calcium carbonate phases in the …
Date: June 30, 2010
Creator: Constantz, Brent; Seeker, Randy & Devenney, Martin
Object Type: Report
System: The UNT Digital Library
Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study) (open access)

Cardiopulmonary Toxicity Induced by Ambient Particulate Matter (BI City Concentrated Ambient Particle Study)

Alterations in heart rate variability (HRV) have been reported in rodents exposed to concentrated ambient particles (CAPs) from different regions of the United States. The goal of this study was to compare alterations in cardiac function induced by CAPs in two distinct regional atmospheres. AirCARE 1, a mobile laboratory with an EPA/Harvard fine particle (particulate matter <2.5 {micro}m; PM{sub 2.5}) concentrator was located in urban Detroit, MI, where the PM mixture is heavily influenced by motor vehicles, and in Steubenville, OH, where PM is derived primarily from long-range transport and transformation of power plant emissions, as well as from local industrial operations. Each city was studied during both winter and summer months, for a total of four sampling periods. Spontaneously hypertensive rats instrumented for electrocardiogram (ECG) telemetry were exposed to CAPs 8 h/day for 13 consecutive days during each sampling period. Heart rate (HR), and indices of HRV (standard deviation of the average normal-to-normal intervals [SDNN]; square root of the mean squared difference of successive normal-to-normal intervals [rMSSD]), were calculated for 30-minute intervals during exposures. A large suite of PM components, including nitrate, sulfate, elemental and organic carbon, and trace elements, were monitored in CAPs and ambient air. In addition, …
Date: June 30, 2010
Creator: Rohr, Annette; Morishita, James Wagner Masako; Keeler, Gerald & Harkema, Jack
Object Type: Report
System: The UNT Digital Library
Cast CF8C-Plus Stainless Steel for Turbocharger Applications (open access)

Cast CF8C-Plus Stainless Steel for Turbocharger Applications

The purpose of this Cooperative Research and Development Agreement (CRADA) project is to provide the critical test data needed to qualify CF8C-Plus cast stainless steel for commercial production and use for turbocharger housings with upgraded performance and durability relative to standard commercial cast irons or stainless steels. The turbocharger technologies include, but are not limited to, heavy-duty highway diesel engines, and passenger vehicle diesel and gasoline engines. This CRADA provides additional critical high-temperature mechanical properties testing and data analysis needed to quality the new CF8C-Plus steels for turbocharger housing applications.
Date: June 30, 2010
Creator: Maziasz, P. J.; Shyam, A.; Evans, N. D. & Pattabiraman, K. (Honeywell Turbo Technologies
Object Type: Report
System: The UNT Digital Library
Catalyzed Nano-Framework Stablized High Density Reversible Hydrogen Storage Systems (open access)

Catalyzed Nano-Framework Stablized High Density Reversible Hydrogen Storage Systems

A wide range of high capacity on-board rechargeable material candidates have exhibited non-ideal behavior related to irreversible hydrogen discharge / recharge behavior, and kinetic instability or retardation. This project addresses these issues by incorporating solvated and other forms of complex metal hydrides, with an emphasis on borohydrides, into nano-scale frameworks of low density, high surface area skeleton materials to stabilize, catalyze, and control desorption product formation associated with such complex metal hydrides. A variety of framework chemistries and hydride / framework combinations were investigated to make a relatively broad assessment of the method'™s potential. In this project, the hydride / framework interactions were tuned to decrease desorption temperatures for highly stable compounds or increase desorption temperatures for unstable high capacity compounds, and to influence desorption product formation for improved reversibility. First principle modeling was used to explore heterogeneous catalysis of hydride reversibility by modeling H{sub 2} dissociation, hydrogen migration, and rehydrogenation. Atomic modeling also demonstrated enhanced NaTi(BH{sub 4}){sub 4} stabilization at nano-framework surfaces modified with multi-functional agents. Amine multi-functional agents were found to have more balanced interactions with nano-framework and hydride clusters than other functional groups investigated. Experimentation demonstrated that incorporation of Ca(BH{sub 4}){sub 2} and Mg(BH{sub 4}){sub 2} in …
Date: June 30, 2010
Creator: Tang, Xia; Opalka, Susanne M.; Mosher, David A.; Laube, Bruce L.; Brown, Ronald J.; Vanderspurt, Thomas H. et al.
Object Type: Report
System: The UNT Digital Library
Center for Technology for Advanced Scientific Component Software (TASCS) (open access)

Center for Technology for Advanced Scientific Component Software (TASCS)

The UO portion of the larger TASCS project was focused on the usability subproject identified in the original project proposal. The key usability issue that we tacked was that of supporting legacy code developers in migrating to a component-oriented design pattern and development model with minimal manual labor. It was observed during the lifetime of the TASCS (and previous CCA efforts) that more often than not, users would arrive with existing code that was developed previous to their exposure to component design methods. As such, they were faced with the task of both learning the CCA toolchain and at the same time, manually deconstructing and reassembling their existing code to fit the design constraints imposed by components. This was a common complaint (and occasional reason for a user to abandon components altogether), so our task was to remove this manual labor as much as possible to lessen the burden placed on the end-user when adopting components for existing codes. To accomplish this, we created a source-based static analysis tool that used code annotations to drive code generation and transformation operations. The use of code annotations is due to one of the key technical challenges facing this work | programming languages …
Date: June 30, 2010
Creator: Sottile, Dr. Mathew
Object Type: Report
System: The UNT Digital Library
Characterization of Secondary Phases and Other Defects in CDZNTE (open access)

Characterization of Secondary Phases and Other Defects in CDZNTE

Semiconducting CdZnTe or 'CZT' crystals are very suitable for use as a room temperature-based gamma radiation spectrometer. During the last decade, modifications in growth methods for CZT have significantly improved the quality of the produced crystals however there are material features that can influence the performance of these materials as radiation detectors. For example, various structural heterogeneities within the CZT crystals, such as, pipes, voids, polycrystallinity, and secondary phases (SP) can have a negative impact on the detector performance. In this study, a CZT material was grown by the modified vertical Bridgman growth (MVB) method with zone leveled growth in the absence of excess Te in the melt. Numerous SP were imaged using transmission IR at a volume % of 0.002. Samples from this material were analyzed using various analytical techniques to evaluate its electrical properties, purity and detector performance as radiation spectrometers and to determine the morphology, dimension and elemental /structural composition of one of the SP in this material. This material was found to have a high resistivity and good radiation spectrometer performance. It had SPs that were rich in calcium (Ca), carbon (C) and oxygen (O) (possibly CaCO{sub 3}) or only C and O that were 5 …
Date: June 30, 2010
Creator: Duff, M.
Object Type: Article
System: The UNT Digital Library
Combating Nuclear Smuggling: DHS Has Made Some Progress but Not Yet Completed a Strategic Plan for Its Global Nuclear Detection Efforts or Closed Identified Gaps (open access)

Combating Nuclear Smuggling: DHS Has Made Some Progress but Not Yet Completed a Strategic Plan for Its Global Nuclear Detection Efforts or Closed Identified Gaps

Testimony issued by the Government Accountability Office with an abstract that begins "In April 2005, a Presidential Directive established the Domestic Nuclear Detection Office (DNDO) within the Department of Homeland Security (DHS) to enhance and coordinate federal, state, and local efforts to combat nuclear smuggling abroad and domestically. DNDO was directed to develop, in coordination with the departments of Defense, Energy, and State, an enhanced global nuclear detection system of radiation detection equipment and interdiction activities. (DNDO refers to this system as an architecture.) DNDO is to implement the domestic portion of the architecture. Federal efforts to combat nuclear smuggling have largely focused on established ports of entry, such as seaports and land border crossings, and DNDO has also been examining nuclear detection strategies along other pathways. Over the past 7 years, GAO has issued numerous recommendations on nuclear or radiological detection to the Secretary of Homeland Security, most recently in January 2009. This testimony discusses the status of DHS efforts to (1) complete the deployment of radiation detection equipment to scan all cargo and conveyances entering the United States at ports of entry, (2) prevent smuggling of nuclear or radiological materials via the critical gaps DNDO identified, and (3) …
Date: June 30, 2010
Creator: United States. Government Accountability Office.
Object Type: Text
System: The UNT Digital Library
Consolidation of K Basin Sludge Data and Experiences on Agglomerate Formation (open access)

Consolidation of K Basin Sludge Data and Experiences on Agglomerate Formation

This report addresses observations of agglomerate formation, conditions that the data shows lead to agglomeration, the frequency of agglomerate formation and postulated physiochemical mechanisms that may lead to agglomeration.
Date: June 30, 2010
Creator: Hill, S.R.
Object Type: Report
System: The UNT Digital Library
Contracting Strategies: Better Data and Management Needed to Leverage Value of Interagency and Enterprisewide Contracts (open access)

Contracting Strategies: Better Data and Management Needed to Leverage Value of Interagency and Enterprisewide Contracts

Testimony issued by the Government Accountability Office with an abstract that begins "Agencies can use several different types of contracts to leverage the government's buying power for goods and services. These include interagency contracts--where one agency uses another's contract for its own needs--such as the General Services Administration (GSA) and the Department of Veterans Affairs multiple award schedule (MAS) contracts, multiagency contracts (MAC) for a wide range of goods and services, and governmentwide acquisition contracts (GWAC) for information technology. Agencies spent at least $60 billion in fiscal year 2008 through these contracts and similar single-agency enterprisewide contracts. GAO was asked to testify on the management and oversight of interagency contracts, and how the government can ensure that interagency contracting is efficient and transparent. GAO's testimony is based on its recent report, Contracting Strategies: Data and Oversight Problems Hamper Opportunities to Leverage Value of Interagency and Enterprisewide Contracts (GAO-10-367, April 2010). In that report, GAO made recommendations to the Office of Management and Budget (OMB) to strengthen policy, improve data, and better coordinate agencies' awards of MACs and enterprisewide contracts, and to GSA to improve MAS program pricing and management. Both agencies concurred with GAO's recommendations."
Date: June 30, 2010
Creator: United States. Government Accountability Office.
Object Type: Text
System: The UNT Digital Library
Department of Homeland Security: Assessments of Selected Complex Acquisitions (open access)

Department of Homeland Security: Assessments of Selected Complex Acquisitions

Other written product issued by the Government Accountability Office with an abstract that begins "Department of Homeland Security (DHS) acquisitions represent hundreds of billions of dollars in life-cycle costs to support a wide range of missions. Creating acquisition policies and processes to provide insight into the performance of a wide array of complex investments, while also providing oversight for many component agencies new to acquisition management, has been an ongoing challenge for DHS. GAO performed this review because DHS implementation and transformation is on GAO's high risk list. This report (1) provides an update on DHS's efforts to implement acquisition oversight for all investments; (2) describes acquisition performance and common challenges across selected programs; and (3) provides individual profiles for 18 selected programs, 15 of which were major programs that had initiated acquisition activities. GAO selected programs based on relevance to frontline homeland security missions and assessed cost and schedule performance and acquisition planning challenges."
Date: June 30, 2010
Creator: United States. Government Accountability Office.
Object Type: Text
System: The UNT Digital Library
Dimensional Measurements of Ultra Delicate Materials Using Micrometrology Tactile Sensing (open access)

Dimensional Measurements of Ultra Delicate Materials Using Micrometrology Tactile Sensing

None
Date: June 30, 2010
Creator: Bauza, M. B.; Woody, S. C.; Seugling, R. M. & Smith, S. T.
Object Type: Article
System: The UNT Digital Library
The Establishment of a Formal Midwest Renewable Energy Tracking System (M-RETS) Organization (open access)

The Establishment of a Formal Midwest Renewable Energy Tracking System (M-RETS) Organization

The objectives identified in requesting and utilizing this funding has been met. The goal was to establish a formal, multi-jurisdictional organization to: (1) ensure the policy objectives of the participating jurisdictions are addressed through increased tradability of the Renewable Energy Credits (RECs) from M-RETS and to eliminate the possibility that a single jurisdiction will be the sole arbiter of the operation of the system; (2) facilitate the establishment of REC standards including the attributes related to, the creation, trading, and interaction with other trading and tracking systems; and (3) have a centralized and established organization that will be responsible for the contracting and governance responsibilities of a multi-jurisdictional tracking system. The M-RETS Inc. Board ensures that the system remains policy neutral; that the attributes of generation are tracked in a way that allows the system users to easily identify and trade relevant RECs; that the system can add jurisdictions as needed or desired; and that the tracking system operate in such a way to allow for the greatest access possible for those participating in other tracking or trading systems by allowing those systems to negotiate with a single M-RETS entity for the import and export of RECs. M-RETS as an …
Date: June 30, 2010
Creator: Redmond, Maria & O'Connor, Chela Bordas
Object Type: Report
System: The UNT Digital Library
EU-U.S. Economic Ties: Framework, Scope, and Magnitude (open access)

EU-U.S. Economic Ties: Framework, Scope, and Magnitude

This report provides background information and analysis of the U.S.-EU economic relationship for Members of the 111th Congress as they contemplate the costs and benefits of closer U.S. economic ties with the EU. It examines the economic and political framework of the relationship and the scope and magnitude of the ties based on data from various sources. In addition, the report analyzes the implications these factors have for U.S. economic policy toward the EU.
Date: June 30, 2010
Creator: Cooper, William H.
Object Type: Report
System: The UNT Digital Library
EU-U.S. Economic Ties: Framework, Scope, and Magnitude. June 2010 (open access)

EU-U.S. Economic Ties: Framework, Scope, and Magnitude. June 2010

This report provides background information and analysis of the U.S.-EU economic relationship for Members of the 111th Congress as they contemplate the costs and benefits of closer U.S. economic ties with the EU.
Date: June 30, 2010
Creator: Cooper, William H.
Object Type: Report
System: The UNT Digital Library
Experimental Demonstration of Advanced Palladium Membrane Separators for Central High Purity Hydrogen Production (open access)

Experimental Demonstration of Advanced Palladium Membrane Separators for Central High Purity Hydrogen Production

The overall objectives for this project were to: (1) confirm the high stability and resistance of a PdCu trimetallic alloy to carbon and carbide formation and, in addition, resistance to sulfur, halides, and ammonia; (2) develop a sulfur, halide, and ammonia resistant alloy membrane with a projected hydrogen permeance of 25 m{sup 3}m{sup -2}atm{sup -0.5}h{sup -1} at 400 C and capable of operating at pressures of 12.1 MPa ({approx}120 atm, 1750 psia); and (3) construct and experimentally validate the performance of 0.1 kg/day H{sup 2} PdCu trimetallic alloy membrane separators at feed pressures of 2 MPa (290 psia) in the presence of H{sub 2}S, NH{sub 3}, and HCl. This project successfully increased the technology readiness level of palladium-based metallic membranes for hydrogen separation from coal-biomass gasifier exhaust or similar hydrogen-containing gas streams. The reversible tolerance of palladium-copper (PdCu) alloys was demonstrated for H{sub 2}S concentrations varying from 20 ppmv up to 487 ppmv and NH{sub 3} concentrations up to 9 ppmv. In addition, atomistic modeling validated the resistance of PdCu alloys to carbon formation, irreversible sulfur corrosion, and chlorine attack. The experimental program highlighted two key issues which must be addressed as part of future experimental programs: (1) tube defects …
Date: June 30, 2010
Creator: Emerson, Sean; Magdefrau, Neal; Opalka, Susanne; She, Ying; Thibaud-Erkey, Catherine; Vanderspurt, Thoman et al.
Object Type: Report
System: The UNT Digital Library