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Studies Relevant to the Catalytic Activation of Carbon Monoxide
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
Date:
June 4, 1992
Creator:
Ford, P. C.
System:
The UNT Digital Library
Studies relevant to the catalytic activation of carbon monoxide. Technical progress report, September 1991
Research activity during the 1991--1992 funding period has been concerned with the following topics relevant to carbon monoxide activation. (1) Exploratory studies of water gas shift catalysts heterogenized on polystyrene based polymers. (2) Mechanistic investigation of the nucleophilic activation of CO in metal carbonyl clusters. (3) Application of fast reaction techniques to prepare and to investigate reactive organometallic intermediates relevant to the activation of hydrocarbons toward carbonylation and to the formation of carbon-carbon bonds via the migratory insertion of CO into metal alkyl bonds.
Date:
June 4, 1992
Creator:
Ford, P. C.
System:
The UNT Digital Library
Design of a high activity and selectivity alcohol catalyst
In order to explore the secondary dehydration of methanol over [gamma]-Al[sub 2]O[sub 3] support and over bimetallic Rh-Mo/[gamma]- Al[sub 2]O[sub 3], a new series of K-doped Rh-Mo/[gamma]-Al[sub 2]O[sub 3] catalysts was synthesized. Work on synthesis of bimetallic Rh-Mo clusters is reported.
Date:
June 4, 1992
Creator:
Foley, Henry C. & Mills, G. Alex
System:
The UNT Digital Library
Design of a high activity and selectivity alcohol catalyst. Seventh quarterly report, February 7, 1992--May 7, 1992
In order to explore the secondary dehydration of methanol over {gamma}-Al{sub 2}O{sub 3} support and over bimetallic Rh-Mo/{gamma}- Al{sub 2}O{sub 3}, a new series of K-doped Rh-Mo/{gamma}-Al{sub 2}O{sub 3} catalysts was synthesized. Work on synthesis of bimetallic Rh-Mo clusters is reported.
Date:
June 4, 1992
Creator:
Foley, H. C. & Mills, G. A.
System:
The UNT Digital Library