We have developed what we believe to be the very first a priori prediction technique for the gasification reactivity of coal char. With this method the gasification reactivity of a coal char as function of temperature can be predicted from a single temperature programmed desorption (TPD) experiment following mild gasification at a single temperature (Calo et al., 1989; Hall and Calo, 1990a). This approach has been demonstrated for C0{sub 2} gasification of coal chars where the gasification reactivity is controlled by the thermal desorption of oxygen surface complexes formed during gasification. This approach may be extended to other oxidant species, such as steam, and carbon-hydrogen complexes for hydrogen gasification as well. In the current report, we present a summary of the work that has been conducted to date in constructing a new TGA/TPD-MS experimental system which provides us with the capability of simultaneous monitoring of transient sample mass data, as well as gas phase composition during thermal desorption experiments. In addition, we present some steam reactivity data obtained with another TGA (Cahn 113 system) which has been modified for steam gasification experiments.

A preliminary design basis for ammonia scrubbers in the DWPF has been issued. This design basis is based on a theoretical model of ammonia evolution from the SRAT, SME and RCT. It is desirable to acquire actual process data on ammonia evolution prior to performing detailed design of scrubbers for DWPF. The evolution of ammonia from the SRAT and SME in the Integrated DWPF Melter System (IDMS) was investigated during the HM4 run. In this run, Precipitate Hydrolysis Aqueous (PHA), which was made in the Precipitate Hydrolysis Experimental Facility (PHEF) using the HAN (hydroxylamine nitrate) process was used, thus resulting in PHA with a high concentration of ammonium ion.

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

This report covers the investigation on the field use of crosshole measurements in reservoir characterization. This investigation was planned for a four year effort. (Year 1) Preparation. (Year 2) Use of vertically polarized shear waves. (Year 3) Addition of horizontally polarized shear waves. (Year 4) Present static image of reservoir properties and observe the time varying phenomena in reservoir by reshooting high frequency compressional (P) survey. This report covers the first six months of the third year.

We have developed what we believe to be the very first a priori prediction technique for the gasification reactivity of coal char. With this method the gasification reactivity of a coal char as function of temperature can be predicted from a single temperature programmed desorption (TPD) experiment following mild gasification at a single temperature (Calo et al., 1989; Hall and Calo, 1990a). This approach has been demonstrated for C0{sub 2} gasification of coal chars where the gasification reactivity is controlled by the thermal desorption of oxygen surface complexes formed during gasification. This approach may be extended to other oxidant species, such as steam, and carbon-hydrogen complexes for hydrogen gasification as well. In the current report, we present a summary of the work that has been conducted to date in constructing a new TGA/TPD-MS experimental system which provides us with the capability of simultaneous monitoring of transient sample mass data, as well as gas phase composition during thermal desorption experiments. In addition, we present some steam reactivity data obtained with another TGA (Cahn 113 system) which has been modified for steam gasification experiments.

In this paper we describe a solution strategy to determine the natural frequencies of piezoelectric crystals subject to moderate changes in temperature and a variety of boundary constraints. The finite element equations governing piezoelectricity are derived based upon a Galerkin formulation of the problem. Suitable assumptions are made to linearize the steady-state (static) problem leading to an iteration scheme that can be used to refine the solution and include non-linear geometric effects caused by deformation. The eigenvalue problem is cast in this perturbed state to allow more accurate prediction of resonant frequencies.

The end'' design of the High Gradient Quad. was done with consideration to the integrated field harmonics, the iron contribution, and the maximum field at the conductor. Magnetic analysis was done on the return end only, however the physical dimension of the lead end were determined as well. Using the cross-section of the windings and Cook's program BEND, we generated the physical end windings around the return end. Placing a single wire at the center of each turn the integrated gradient was computed and iterating on the end block spacers the integrated harmonics minimized. The final geometry was then used for more, extensive calculations, such as the field at the conductor and the 3D field harmonics. For this detailed calculation we have placed a single line current at the center of each strand and included the iron contribution ({mu} = {infinity}), see Appendix C. With the termination of the iron serving as a reference, the maximum length of the inner and outer layers are 182 mm and 215 mm respectively. The magnetic length of the end was computed from the gradient function A{sub 2} and was found to be 142 mm. In reality we expect the physical length of the …

This report covers the investigation on the field use of crosshole measurements in reservoir characterization. This investigation was planned for a four year effort. (Year 1) Preparation. (Year 2) Use of vertically polarized shear waves. (Year 3) Addition of horizontally polarized shear waves. (Year 4) Present static image of reservoir properties and observe the time varying phenomena in reservoir by reshooting high frequency compressional (P) survey. This report covers the first six months of the third year.

A preliminary design basis for ammonia scrubbers in the DWPF has been issued. This design basis is based on a theoretical model of ammonia evolution from the SRAT, SME and RCT. It is desirable to acquire actual process data on ammonia evolution prior to performing detailed design of scrubbers for DWPF. The evolution of ammonia from the SRAT and SME in the Integrated DWPF Melter System (IDMS) was investigated during the HM4 run. In this run, Precipitate Hydrolysis Aqueous (PHA), which was made in the Precipitate Hydrolysis Experimental Facility (PHEF) using the HAN (hydroxylamine nitrate) process was used, thus resulting in PHA with a high concentration of ammonium ion.

The objective of this project is to investigate three possible routes to the formation of ethers, in particular methyl tert-butyl ether (MTBE), during slurry phase Fischer-Tropsch reaction. The three reaction schemes to be investigated are: Addition of isobutylene during the formation of methanol and/or higher alcohols directly from CO and H{sub 2} during slurry-phase Fischer-Tropsch. Addition of isobutylene to FT liquid products including alcohols in a slurry-phase reactor containing an MTBE or other acid catalyst. Addition of methanol to slurry phase FT synthesis making iso-olefins.

The ``end`` design of the High Gradient Quad. was done with consideration to the integrated field harmonics, the iron contribution, and the maximum field at the conductor. Magnetic analysis was done on the return end only, however the physical dimension of the lead end were determined as well. Using the cross-section of the windings and Cook`s program BEND, we generated the physical end windings around the return end. Placing a single wire at the center of each turn the integrated gradient was computed and iterating on the end block spacers the integrated harmonics minimized. The final geometry was then used for more, extensive calculations, such as the field at the conductor and the 3D field harmonics. For this detailed calculation we have placed a single line current at the center of each strand and included the iron contribution ({mu} = {infinity}), see Appendix C. With the termination of the iron serving as a reference, the maximum length of the inner and outer layers are 182 mm and 215 mm respectively. The magnetic length of the end was computed from the gradient function A{sub 2} and was found to be 142 mm. In reality we expect the physical length of the …

The meeting began with presentations by the facilitator and the representative from DOE. The facilitator introduced those on the podium. He then described the general structure of the meeting and its purpose: to hear the issues and concerns of those present regarding the proposed Hawaiian Geothermal Project. He described his role as assuring the impartiality and fairness of the meeting. Dr. Lewis of DOE further defined the scope of the project, introduced those of the EIS team present and briefly described the EIS process. A number of process issues were covered, including the current State dependence on imported petroleum (>90%), the public nature of the DOE EIS process, DOE's responsibility to consider general impacts to the global situation, and database availability. Dr. Lewis assured those present that the EIS would examine transmission system/cable-related impacts and alternatives to the proposed action, within geothermal and outside it (including coal), including different mixes of supply- or demand-side options on each island using an integrated resource planning approach. With respect to prior and on-going geothermal developments in Puna, Dr. Lewis explained that although DOE will not conduct new environmental reviews of the HGP(A) and other federal geothermal development in Puna, these and the present …

The meeting began with presentations by the facilitator, Mr. Spiegel, and Dr. Lewis, the representative from DOE. The facilitator introduced those on the podium. He then described the general structure of the meeting and its purpose: to hear the issues and concerns of those present regarding the proposed Hawaiian Geothermal Project. He described his role as assuring the impartiality and fairness of the meeting. Dr. Lewis of DOE further defined the scope of the project, introduced members of the EIS team, and briefly described the EIS process. Ninety percent of those presenting expressed concern about the potential impacts of the HGP to the environment. They asked that the EIS investigate the impacts of 1.he HGP on quality of air, water and soils, flora and fauna, land, socioeconomics, religion and culture. Seventy percent of the commenters want the EIS to investigate the impacts of all components of the HGP (eg. generation facilities, pipes, roads, drill pads, transmission corridors, and cable) on terrestrial ecosystems (e.g. the rainforest), threatened and endangered species, species diversity, species used for ritual or medicinal purposes, and climate stability. The EIS should address the effects of segmentation of habitat, introduction of exotic species, acid rain, herbicides, and enhanced …

This report is about the historical facts of Georgia.

In this paper we describe a solution strategy to determine the natural frequencies of piezoelectric crystals subject to moderate changes in temperature and a variety of boundary constraints. The finite element equations governing piezoelectricity are derived based upon a Galerkin formulation of the problem. Suitable assumptions are made to linearize the steady-state (static) problem leading to an iteration scheme that can be used to refine the solution and include non-linear geometric effects caused by deformation. The eigenvalue problem is cast in this perturbed state to allow more accurate prediction of resonant frequencies.