Chemical Processing Department Monthly Report: May 1963 (open access)

Chemical Processing Department Monthly Report: May 1963

This report, from the Chemical Processing Department at HAPO for May 1963, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations, facilities engineering; research; employee relations; weapons manufacturing operation; and power and crafts operation.
Date: June 21, 1963
Creator: Hanford Atomic Products Operation. Chemical Processing Department.
Object Type: Report
System: The UNT Digital Library
Variation of the Half-Wave Potential of Organic Compounds With pH. Report No. 78 (open access)

Variation of the Half-Wave Potential of Organic Compounds With pH. Report No. 78

From 19th International Union of Pure and Applied Chemistry Congress, London. A systematic introduction is presented to the subject of the variation with pH of the polarographic half-wave potential, which is probably the most readily measured electrochemical energetic parameter of organic compounds. Emphasis is placed on (a) the types of relationships observed for both reversible and irreversible electrode processes, (b) the mathematical formulation of these relationships, (c) the structural, mechanistic, kinetic, and environmental factors influencing such relationships, and (d) the presumptive physical causes for such relationships, e.g., the effect of pH on the electrochemical kinetics. Although the discussion is primarily concerned with behavior in aqueous solution, the conclusions drawn are equally valid for nonaqueous media in which hydrogen ion or some other Lewis acid can play a significant role. The half-wave potential for an organic electrode process may be independent of pH, or may vary lineanly or sigmoidally; other types of relationships observed are likely to be combinations of such effects. These variations may be due (a) to direct participation of hydrogen ion in the transition state involving the electroactive site in the organic molecule and the electron source, e.g., polarization of the bond to be broken, (b) to control …
Date: June 21, 1963
Creator: Elving, P. J.
Object Type: Article
System: The UNT Digital Library
POWER-BURST FACILITY (PBF) CONCEPTUAL DESIGN (open access)

POWER-BURST FACILITY (PBF) CONCEPTUAL DESIGN

A description is presented of the conceptual design of a high- performance, pulsed reactor called the Power Burst Facility (PBF). This reactor is designed to generate power bursts with initial asymptotic periods as short as 1 msec, producing energy releases large enough to destroy entire fuel subassemblies placed in a capsule or flow loop mounted in the reactor, all without damage to the reactor itself. It will be used primarily to evaluate the consequences and hazards of very rapid destructive accidents in reactors representing the entire range of current nuclear technology as applied to power generation, propulsion, and testing. It will also be used to carry out detailed studies of nondestructive reactivity feedback mechanisms in the shortperiod domain. The facility was designed to be sufficiently flexible to accommodate future cores of even more advanced design. The design for the first reactor core is based upon proven technology; hence, completion of the final design of this core will involve no significant development delays. Construction of the PBF is proposed to begin in September 1984, and is expected to take approximately 20 months to complete. (auth)
Date: June 21, 1963
Creator: Wasserman, A. A.; Johnson, S. O.; Heffner, R. E.; Kern, R. S. & Spano, A. H.
Object Type: Report
System: The UNT Digital Library
THERMOLUMINESCENCE SPECTRA AND ACTIVATION ENERGIES FOR AROMATIC AMINO ACIDS, TRYPSIN, AND SPORES OF BACILLUS MEGATERIUM (open access)

THERMOLUMINESCENCE SPECTRA AND ACTIVATION ENERGIES FOR AROMATIC AMINO ACIDS, TRYPSIN, AND SPORES OF BACILLUS MEGATERIUM

The theory of thermoluminescence is reviewed. The spectral distribution of thermoluminescence and the activation energies associated with peaks of the glow curves were determined for samples of aromatic amino acids, trypsin, and spores of Bacillus megaterium irradiated by a Co/sup 60/ gamma source. All of the substances, except phenylalanine, exhibited a readily observable long-lived glow that persisted up to at least 2 hr following irradiation. Possible reaction mechanisms in the production of thermoluminescence in biological materials are discussed. (C.H.)
Date: June 21, 1963
Creator: Weinberg, C. J.; Carter, J. G.; Nelson, D. R. & Birkhoff, R. D.
Object Type: Thesis or Dissertation
System: The UNT Digital Library