Two auger samples from tank 241-C-201 (C-201) were received by the 222-S Laboratories and underwent safety screening analysis, consisting of differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and total alpha activity. Analytical results for the DSC analyses of both samples exceeded the notification limit of 481 J/g (dry weight basis). As well, the TGA analyses for both samples were less than the safety screening notification limit (notification is made if the sample is analyzed at less than 17 percent water). Notification of both of these occurrences was made on May,15, 1995, and secondary analysis of total organic carbon (TOC) was initiated. These TOC analysis results are also included in this report.

The 1990 Clean Air Act Amendments provided the Environmental Protection Agency (EPA) and the states with new tool to address the problem of interstate transport of air pollutants. This report discusses the actions undertaken as a direct result of this act, additional pollution reduction enforcement measures pursued by the EPA, and actions undertaken by states to reduce offending emissions not in compliance with these measures.

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE's Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce air pollution and petroleum consumption due to the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, and project management on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of January 1, 1993 through March 31, 1993. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Project Management; 2.0 Sodium/Metal Chloride R D; 3.0 Microreference Electrodes for Lithium/Polymer Batteries.

The Electrochemical Technology Program at Argonne National Laboratory (ANL) provides technical and programmatic support to DOE`s Electric and Hybrid Propulsion Division (DOE-EHP). The goal of DOE-EHP is to advance promising electric-vehicle (EV) propulsion technologies to levels where industry will continue their commercial development and thereby significantly reduce air pollution and petroleum consumption due to the transportation sector of the economy. In support of this goal, ANL provides research, development, testing/evaluation, post-test analysis, modeling, and project management on advanced battery technologies for DOE-EHP. This report summarizes the battery-related activities undertaken during the period of January 1, 1993 through March 31, 1993. In this report, the objective, background, technical progress, and status are described for each task. The work is organized into the following task areas: 1.0 Project Management; 2.0 Sodium/Metal Chloride R&D; 3.0 Microreference Electrodes for Lithium/Polymer Batteries.

A major question that arises in Congress during its considerations of what policies promote and what inhibit the restoration of a healthy economy is the influence that interest rates exert. In particular, are high interest rates a threat to sustained economic recovery?

Atomic transport of oxygen in nonstoichiometric oxides is an extremely important topic which overlaps science and technology. In many cases the diffusion of oxygen controls sintering, grain growth, and creep. High oxygen diffusivity is critical for efficient operation of many fuel cells. Additionally, oxygen diffusivities are an essential ingredient in any point defect model. Secondary Ion Mass Spectrometry (SIMS) is the most accurate modern technique to measure oxygen tracer diffusion. This paper briefly reviews the principles and applications of SIMS for the measurement of oxygen transport. Case studies are taken from recent work on ZnO and some high-temperature superconductors.

The baseline risk assessment [WSRC91] has demonstrated that the hazard at PAR Pond is solely from external exposure to Cs-137, a gamma emitting radionuclide. Between 1954 and 1964, approximately 222 curies of radioactive cesium (Cs-134 and Cs-137) were released to the Lower Three Runs Creek system from R Reactor [Ma9l]. These releases were associated with leaking fuel and target slugs in the reactor disassembly basin. Independent studies show that approximately 45 curies of Cs-137 (half-life of 30 years) still resides in the sediments of PAR Pond [Wh9l; Wi9l]; Cs-134 has a relatively short half-life (2 years) and has decayed to insignificant quantities since it was released.

The baseline risk assessment [WSRC91] has demonstrated that the hazard at PAR Pond is solely from external exposure to Cs-137, a gamma emitting radionuclide. Between 1954 and 1964, approximately 222 curies of radioactive cesium (Cs-134 and Cs-137) were released to the Lower Three Runs Creek system from R Reactor [Ma9l]. These releases were associated with leaking fuel and target slugs in the reactor disassembly basin. Independent studies show that approximately 45 curies of Cs-137 (half-life of 30 years) still resides in the sediments of PAR Pond [Wh9l; Wi9l]; Cs-134 has a relatively short half-life (2 years) and has decayed to insignificant quantities since it was released.

We examine magnetic field penetration in the Plasma Opening Switch, exploring, in particular, advective field penetration arising in conjunction with radial density gradients across the cathode anode gap. Our calculations have been completed with the implicit multi-fluid, ANTHEM code. We show favored penetration along a radial density jump, unstable plain wave penetration for a 1/(y {minus} y{sub {alpha}+{epsilon}}) density dependence (with y measured from cathode to anode at Y{sub {alpha}}) in planar switches, and the penetration of finger-like magnetic field perturbations, when the fill plasmas bears initial sinusoidal disturbances on its generator interface. 7 refs., 4 figs.

Correspondence issued by the General Accounting Office with an abstract that begins "Pursuant to a congressional request, GAO reviewed the proposed legislation entitled the Government Waste Correction Act of 1999."

The Solenoidal Tracker At RHIC (STAR) will search for signatures of quark-gluon plasma (QGP) formation and investigate the behavior of strongly interacting matter at high energy density. The emphasis win be the correlation of many observables on an event-by-event basis. In the absence of definitive signatures for the QGP, it is imperative that such correlations be used to identify special events and possible signatures. This requires a flexible detection system that can simultaneously measure many experimental observables. The physics goals dictate the design of star and it's experiment. To meet the design criteria, tracking, momentum analysis, and particle identification of most of the charged particles at midrapidity are necessary. The tracking must operate in conditions at higher than the expected maximum charged particle multiplicities for central Au + Au collisions. Particle identification of pions/kaons for p < 0.7 GeV/c and kaons/protons for p < 1 GeV/c, as well as measurement of decay particles and reconstruction of secondary vertices will be possible. A two-track resolution of 2 cm at 2 m radial distance from, the interaction is expected. Momentum resolution of {Delta}p/p {approximately} 0.02 at p = 0.1 GeV/c is required to accomplish the physics, and,{Delta}p/p of several percent at p …

The Solenoidal Tracker At RHIC (STAR) will search for signatures of quark-gluon plasma (QGP) formation and investigate the behavior of strongly interacting matter at high energy density. The emphasis win be the correlation of many observables on an event-by-event basis. In the absence of definitive signatures for the QGP, it is imperative that such correlations be used to identify special events and possible signatures. This requires a flexible detection system that can simultaneously measure many experimental observables. The physics goals dictate the design of star and it`s experiment. To meet the design criteria, tracking, momentum analysis, and particle identification of most of the charged particles at midrapidity are necessary. The tracking must operate in conditions at higher than the expected maximum charged particle multiplicities for central Au + Au collisions. Particle identification of pions/kaons for p < 0.7 GeV/c and kaons/protons for p < 1 GeV/c, as well as measurement of decay particles and reconstruction of secondary vertices will be possible. A two-track resolution of 2 cm at 2 m radial distance from, the interaction is expected. Momentum resolution of {Delta}p/p {approximately} 0.02 at p = 0.1 GeV/c is required to accomplish the physics, and,{Delta}p/p of several percent at p …

A letter report issued by the General Accounting Office with an abstract that begins "Pursuant to a congressional request, GAO reviewed the Bureau of Labor Statistics' (BLS) decisions to substitute one product for another in its computation of the Consumer Price Index (CPI), focusing on: (1) how commodity analysts decide whether to make adjustments to the CPI; (2) the adjustment methods they use; and (3) how supervisors of commodity analysts review the analysts' decisions."

This report discusses the following topics; establishment and growth of the laboratories and the struggle for Livermore; technology and weapons development; and challenges to unbridled technological development--the laboratories and arms control.

A letter report issued by the General Accounting Office with an abstract that begins "Pursuant to a legislative requirement, GAO reviewed the Navy's F/A-18E/F developmental and operational test program, focusing on the: (1) extent to which the aircraft is meeting performance requirements; (2) risks associated with proceeding into operational test and evaluation (OPEVAL) with unresolved deficiencies; and (3) potential cost increases and risks associated with approving the Navy's request for multiyear funding for the program."

Detection of weak patterns in radar ocean RCS images is complicated by the fact that signals and noise are interactive rather than additive and the ambient noise background is non Gaussian or even strongly non Gaussian at low grazing angles. This paper addresses this difficult problem with the aid of two simplifying assumptions: (1) the signal modulation is weak, and (2) departure from Gaussianity is small. In situations where this departure is large, an approach is suggested for reducing this non Gaussianity. The relevant weak signal detection theory, based on the Likelihood ratio, is reviewed and adapted for use in the analysis. The approach to this problem, similar to that previously used for complex images, is facilitated by approximating the multivariate probability distributions as a composite integral involving underlying processes which are assumed to be Gaussian. This formulation, subject to the approximations in the analysis, permits derivation of an ideal detection statistic (which determines the form of optimum receiver) and a signal/noise ratio which characterizes detection performance in the weak signal limit. Implications for image processing are discussed and directions for future analysis are suggested.

This project investigated a suitable catalyst system for the direct NO decomposition for post-combustion NO{sub x} control. The studied process does not use a reductant, such as ammonia in the case of Selective Catalytic Reduction (SCR) process for catalytic reduction of NO{sub x} to nitrogen. This is a simplified process basically involving passing the flue gas through a catalytic converter, thus avoiding problems generally associated with the commercial SCR process, namely high operating cost, ammonia slip, and potential N{sub 2}O emissions. The main results from this research project are summarized in the following: Cu-ZSM-5 and M/Cu-ZSM-5 were synthesized by incorporating metal cations into ZSM-5 zeolite supports by optimized ion exchange procedures. It was found that (1) the catalytic activity of Cu-ZSM-5 only increased with copper loading when the Cu-ZSM-5 was prepared in an aqueous copper acetate solution with pH lower than 5.74; (2) high pH of the solution led not only to ion-exchanged Cu{sup 2+}, but also copper deposition on the zeolite surface forming inactive CuO particles as identified by STEM/EDX and XRD; (3) the sequence of metal ion exchange first, followed by copper ion exchange to synthesize M/Cu-ZSM-5, where M represents any metal ion but copper, was important for …

Workers in indoor environments often complain of symptoms, such as eye and nose irritation, headache, and fatigue, which improve away from work. Exposures causing such complaints, sometimes referred to as sick building syndrome, generally have not been identified. Evidence suggests these worker symptoms are related to chemical, microbiological, physical, and psychosocial exposures not well characterized by current methods. Most research in this area has involved cross-sectional studies, which are limited in their abilities to show causal connections. Experimental studies have also been conducted which, by changing one factor at a time to isolate its effects, can demonstrate benefits of an environmental intervention even before exposures or mechanisms are understood. This study was prompted by evidence that particulate contaminants may be related to acute occupant symptoms and discomfort. The objective was to assess, with a double-blind, double crossover intervention design, whether improved removal of small airborne particles by enhanced central filtration would reduce symptoms and discomfort.

Many hydroxylated aromatic compounds (HACs), particularly small molecules such as substituted phenols, are common contaminants of surface and subsurface systems. The high environmental mobility of these contaminants, due to their relatively high water solubilities, is of particular concern. Abiotic and enzymatic oxidative coupling of this class of contaminants by natural sorbents may be significant in controlling the mobility of HACs and facilitate remediation efforts. The principal objectives of this study are to investigate: (1) the role of abiotic/enzymatic coupling reactions on the sequestration of HACs by natural sorbents; (2) the effects of sorbent structure and chemical composition on such sequestration; and (3) optimal conditions for the induction of these abiotic/enzymatic coupling reactions by addition of suitable catalysts and sorbents. Information gathered from the study will be useful in quantifying the behavior of this class of organic compounds in various subsurface contamination scenarios relevant to DOE facilities, and in specifying strategies for the selection and design of remediation technologies.

Under this FY-96 NLUF program, the authors began their search for satellite lines to forbidden transitions for localized laser-induced electric field measurements by preparing in their laboratory a flat-field grazing incidence spectrograph for use on the OMEGA-Upgrade facility. This involved wavelength calibration using a (small) laser-produced plasma, as well as designing and constructing a mounting table compatible with the large 60-beam target chamber at LLE. Beginning in April 1996 they installed and aligned the spectrograph at LLE. Following final alignment on Monday, April 29, they obtained the following day their first time-integrated spectral data in the 30--250 {angstrom} range. A total of 28 successful shots were obtained. For most shots, two beams of the OMEGA-Upgrade laser were used at nominal uv-pulse widths of 1.1 ns and energies ranging from 76--470 J/beam, with focal spots of 80--450 {micro}m and irradiances covering approximately 10{sup 14}--10{sup 16} Watt/cm{sup 2}. Planar targets used consisted of Mg and NaF, as well as boron mounted on a plastic film, with some of the former two overcoated with 5 {micro}m of CH on each side for containing the plasma, at least during the early portion of the pulse. Preliminary analyses indicate that they do indeed observe the …

Electroweak baryogenesis is addressed within the context of the standard model of particle physics. Although the minimal standard model has the means of fulfilling the three Sakharov`s conditions, it falls short to explaining the making of the baryon asymmetry of the universe. In particular, it is demonstrated that the phase of the CKM mixing matrix is an, insufficient source of CP violation. The shortcomings of the standard model could be bypassed by enlarging the symmetry breaking sector and adding a new source of CP violation.

As enterprises become increasingly information based, making improvements in their information activities is a top priority to assure their continuing competitiveness. A key to achieving these improvements is developing an Enterprise Information Architecture (EIA). An EIA can be viewed as a structured set of multidimensional interrelated elements that support all information processes. The current ad hoc EIAs in place within many enterprises can not meet their future needs because of a lack of a coherent framework, incompatibilities, missing elements, few and poorly understood standards, uneven quality and unnecessary duplications. This paper discusses the EIA developed at Lawrence Livermore National Laboratory as a case study, for other information based enterprises, particularly those with decentralized and autonomous organization structures and cultures. While the architecture is important, the process by which it is developed and sustained over time is equally important. This paper outlines the motivation for an EIA and discusses each of the interacting elements identified. It also presents an organizational structure and processes for building a sustainable EIA activity.

The program ESME for modeling the longitudinal degree of freedom of beam dynamics in proton synchrotrons is described in the ``User`s Guide to ESME v. 8.0`` released 8 March 1993. This note updates the User`s Guide to the state of the code at 15 June 1993. To simplify moving the code to the various UNIX machines at Fermilab and sharing it with other laboratories, it has been decided to promote the HIGZ graphics version. A few new graphics parameters are described which have been introduced in consequence. This note also corrects minor errors and omissions in the User`s Guide and reports minor program enhancements. No errors producing wrong results have been found.

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