CHEMISTRY OF +1 IODINE IN ALKALINE SOLUTION (open access)

CHEMISTRY OF +1 IODINE IN ALKALINE SOLUTION

The iodine species formed either by adding hypochlorite to a basic iodide solution or by adding triiodide to sodium hydroxide, was identified as hypoiodite ion. The absorption spectrum of IO{sup -} was investigated in the wavelength range from 450 m{micro} to 280 m{micro}. The kinetics of the reaction I{sup -} + ClO{sup -} = IO{sup -} + Cl{sup -} was studied spectrophotometrically in alkaline solution. The forward rate law was found to be d(IO{sup -})/dt = k(I{sup -})(ClO{sup -})/OH{sup -}. At 25 C and an ionic strength of 1.00 M, k is 61 {+-} 3 sec{sup -1}. It was found spectrophotometrically that for certain ratios of the initial iodide to hydroxide concentrations, there was evidence of the presence of I{sub 3}{sup -}, I{sub 2}OH{sup -}, and I{sub 2}O{sup 2-} along with IO{sup -}. The equilibrium constants between IO{sup -} and these three species were evaluated by a graphical method. The formal potential of the cell: Pt:H{sub 2}:1 M NaOH : 1M NaOH, KI, NaIO : Au was found to be 1.297 v at 25 C. The equilibrium constant, K{sub 2} = (I{sub 3}{sup -})(OH{sup -}){sup 2}/(IO{sup -})(I{sup -}){sup 2}, of the reaction IO{sup -} + 2I{sup -} + H{sub 2}O …
Date: June 2, 1958
Creator: Chia, Yuan-tsan.
System: The UNT Digital Library
Study of B-Meson Decays to Final States with a Single Charm Baryon (open access)

Study of B-Meson Decays to Final States with a Single Charm Baryon

A study of B-meson decays to final states with a single charm baryon is presented based on data recorded by the BABAR detector at the Stanford Linear Accelerator Center. Although the B meson is the lightest bottom-flavored meson, it is heavy enough to decay to a baryon made of three quarks and an antibaryon made of three antiquarks. By studying the baryonic weak decays of the B meson, we can investigate baryon production mechanisms in heavy meson decays. In particular, we measure the rates of the decays B{sup -} {yields} {Lambda}{sub c}{sup +}{bar p}{pi}{sup -} and {bar B}{sup 0} {yields} {Lambda}{sub c}{sup +}{bar p}. Comparing these rates, we confirm an observed trend in baryonic B decays that the decay with the lower energy release, B{sup -} {yields} {Lambda}{sub c}{sup +}{bar p}{pi}{sup -}, is favored over {bar B}{sup 0} {yields} {Lambda}{sub c}{sup +}{bar p}. The dynamics of the baryon-antibaryon ({Lambda}{sub c}{sup +}{bar p}) system in the three-body decay also provide insight into baryon-antibaryon production mechanisms. The B{sup -} {yields} {Lambda}{sub c}{sup +}{bar p}{pi}{sup -} system is a laboratory for searches for excited {Sigma}{sub c} baryon states; we observe the resonant decays B{sup -} {yields} {Sigma}{sub c}(2455){sup 0}{bar p} and B{sup -} …
Date: June 2, 2009
Creator: Majewski, Stephanie A.
System: The UNT Digital Library