Numerical Simulation of the Performance Characteristics, Instability, and Effects of Band Gap Grading in Cadmium Telluride Based Photovoltaic Devices (open access)

Numerical Simulation of the Performance Characteristics, Instability, and Effects of Band Gap Grading in Cadmium Telluride Based Photovoltaic Devices

Using computer simulations, the performance of several CdTe based photovoltaic structures has been studied. The advantages and disadvantages of band gap grading, through the use of (Zn, Cd)Te, have also been investigated in these structures. Grading at the front interface between a CdS window layer and a CdTe absorber layer, can arise due to interdiffusion between the materials during growth or due to the intentional variation of the material composition. This grading has been shown to improve certain performance metrics, such as the open-circuit voltage, while degrading others, such as the fill factor, depending on the amount and distance of the grading. The presence of a Schottky barrier as the back contact has also been shown to degrade the photovoltaic performance of the device, resulting in a characteristic IV curve. However, with the appropriate band gap grading at the back interface, it has been shown that the performance can be enhanced through more efficient carrier collection. These results were then correlated with experimental observations of the performance degradation in devices subjected to light and heat stress.
Date: June 27, 2001
Creator: Petersen, Michael David
System: The UNT Digital Library
The VRFurnace: A Virtual Reality Application for Energy System Data Analysis (open access)

The VRFurnace: A Virtual Reality Application for Energy System Data Analysis

The VRFurnace is a unique VR application designed to analyze a complete coal-combustion CFD model of a power plant furnace. Although other applications have been created that analyze furnace performance, no other has included the added complications of particle tracking and the reactions associated with coal combustion. Currently the VRFurnace is a versatile analysis tool. Data translators have been written to allow data from most of the major commercial CFD software packages as well as standard data formats of hand-written code to be uploaded into the VR application. Because of this almost any type of CFD model of any power plant component can be analyzed immediately. The ease of use of the VRFurnace is another of its qualities. The menu system created for the application not only guides first time users through the various button combinations but it also helps the experienced user keep track of which tool is being used. Because the VRFurnace was designed for use in the C6 device at Iowa State University's Virtual Reality Applications Center it is naturally a collaborative project. The projection-based system allows many people to be involved in the analysis process. This type of environment opens the design process to not only …
Date: June 25, 2001
Creator: Johnson, Peter Eric
System: The UNT Digital Library
Thermodynamic Critical Field and Superconducting Fluctuation of Vortices for High Temperature Cuprate Superconductor: La-214 (open access)

Thermodynamic Critical Field and Superconducting Fluctuation of Vortices for High Temperature Cuprate Superconductor: La-214

Thermodynamics has been studied systematically for the high temperature cuprate superconductor La{sub 2-x}Sr{sub x}CuO{sub 4-{delta}}, La-214, in the entire superconductive region from strongly underdoped to strongly overdoped regimes. Magnetization studies with H {parallel} c have been made in order to investigate the changes in free energy of the system as the number of carriers is reduced. Above the superconducting transition temperature, the normal-state magnetization exhibits a two-dimensional Heisenberg antiferromagnetic behavior. Below T{sub c}, magnetization data are thermodynamically reversible over large portions of the H-T plane, so the free energy is well defined in these regions. As the Sr concentration is varied over the wide range from 0.060 (strongly underdoped) to 0.234 (strongly overdoped), the free energy change goes through a maximum at the optimum doped in a manner similar to the T{sub c0} vs. x curve. The density of states, N(0), remains nearly constant in the overdoped and optimum doped regimes, taking a broad maximum around x = 0.188, and then drops abruptly towards zero in the underdoped regime. The La{sub 2-x}Sr{sub x}CuO{sub 4} (La-214) system displays the fluctuating vortex behavior with the characteristic of either 2D or 3D fluctuations as indicated by clearly identifiable crossing points T* close to …
Date: June 25, 2001
Creator: Finnemore, Douglas K.
System: The UNT Digital Library
The Development of Layered Photonic Band Gap Structures Using a Micro-Transfer Molding Technique (open access)

The Development of Layered Photonic Band Gap Structures Using a Micro-Transfer Molding Technique

Over the last ten years, photonic band gap (PBG) theory and technology have become an important area of research because of the numerous possible applications ranging from high-efficiency laser diodes to optical circuitry. This research concentrates on reducing the length scale in the fabrication of layered photonic band gap structures and developing procedures to improve processing consistency. Various procedures and materials have been used in the fabrication of layered PBG structures. This research focused on an economical micro transfer molding approach to create the final PBG structure. A poly dimethylsiloxane (PDMS) rubber mold was created from a silicon substrate. It was filled with epoxy and built layer-by-layer to create a 3-D epoxy structure. This structure was infiltrated with nanoparticle titania or a titania sol-gel, then fired to remove the polymer mold, leaving a monolithic ceramic inverse of the epoxy structure. The final result was a lattice of titania rolds that resembles a face-centered tetragonal structure. The original intent of this research was to miniaturize this process to a bar size small enough to create a photonic band gap for wavelengths of visible electro-magnetic radiation. The factor limiting progress was the absence of a silicon master mold of small enough dimensions. …
Date: June 27, 2001
Creator: Sutherland, Kevin Jerome
System: The UNT Digital Library