Laboratory Tests of the Use of Victorian Brown Coal for Removing Traces of Radioactivity from Water (open access)

Laboratory Tests of the Use of Victorian Brown Coal for Removing Traces of Radioactivity from Water

Measurements were made of the capacity of pre-treated Victorian brown coal for removing trace quantities of Sr2+ and Cs+ at pH 8.0 and 9.5 in the presence of various concentrations of Ca2+. At 20 p.p.m. Ca2+ breakthrough was immediate.
Date: May 1962
Creator: O'Keffe, J.
System: The UNT Digital Library
Preliminary Experiments on the Dissolution of Beryllium Based Fuels in Ammonium Fluoride Solutions (open access)

Preliminary Experiments on the Dissolution of Beryllium Based Fuels in Ammonium Fluoride Solutions

Some preliminary measurements have been made of the rate of dissolution of beryllium when refluxed with ammonium fluoride solution. The rate of dissolution exhibits pseudo first order dependence on the "free" fluoride concentration defined as the concentration of total fluoride less that assumed to be present as BeF4. The solubility of uranium metal in ammonium fluoride - beryllium fluoride solutions increases with free fluoride concentration, where the uranium is present in solutions as U(1V). Thorium metal is attacked only slightly under similar conditions. Beryllium may be selectively leached from UBe13 by ammonium fluoride solutions if the fine A-/Be mole ratio is greater than 4:1. The solubility of uranium under these conditions suggests that this is not a satisfactory solvent for mixtures of these alloys with Be when the U/Be ratio is small, but that it could be used successfully as a decladding agent for an oxide fuel clad in beryllium meta.
Date: May 1962
Creator: Whitfield, H. J.
System: The UNT Digital Library