In early July, 1958, it appeared that Columbia River temperature at HAPO would be near 24.5ºC by the end of August. River temperature were averaging 4º to 5º above 1957 figures and were 3º to 4º above the ten year highs. It seemed desirable to examine the problem to determine if any corrective measure could be taken, since it was apparent that production losses were imminent.

Summary. At the time this project was initiated, all brazing had been confined to small retorts of ten cubic feet capacity or less. Larger assemblies were scheduled which required retorts of over 100 cubic feet capacity. Hydrogen atmospheres had given the best results, however, there was considerable reluctance to use hydrogen in these large retorts from a safety standpoint. It was thought that thru the use of PMC 2252, an argon - 2 1/2% hydrogen gas atmosphere which in non-explosive, sufficient cleaning action might be attoined without the inherent hazards encountered with hydrogen. An investigation of the argon - 2 1/2% hydrogen gas as a brazing atomosphoer

Technical report of an investigation to determine a suitable material for sintering and casting of braze rings. Braze rings afford an excellent means of preplacing braze alloy on tube to head joints of radiators, heat exchangers, and similar applications. A cast ring is especially desirable because of its increased strength. Previous efforts at casting had used welding grade carbon blocks with the desired ring cavities machined into their surface. Conclusion: Stackpole grade 331 electro-graphite provided the best results of the materials investigation. It is hard and more readily machinable with conventional tools than other grades. Carbon, in general, proved to be more satisfactory especially due its ease and speed of fabrication.

The design of internally cooled electrical coils for the production of high frequency intensity magnetic fields presents many new aspects and combinations of the familiar modes of heat transfer. However, the customary methodology appears to be sufficient for preliminary analysis and understanding of those problems. This methodology comprises the derivation of a qualitative, approximate equation expressing the relative performance of the various parts of a system, followed by an examination of this equation in order to locate the limiting features of the system. These features are then investigated by more powerful methods, which in turn provide guidance for development research in the laboratory.

Because of the excessive vertical fragility and high replacement costs of mice-window G-M tubes used in vertical and horizontal lead-pig shelf counters, it was requested that a simple system of conversions to reliable scintillation detection be accomplished.

The HAPO Critical Incident Alarm, Model I, is an instrument designed to give an audible and visual alarm signal in the event of a critical incident to which it is exposed. There will be thirty-one (31) of these instruments installed and several spares located in the various manufacturing buildings in the Chemical Processing Department where there exists any possibility of a critical incident occurring. The instrument is intended as a post or after-the-fact warning device. It will offer no protection prior or leading up to, nor prevent, a critical incident. They are intended to be operated from the 115 V. A.C., 60 C.P.S. emergency line power. The instrument is self-contained, including the radiation detector, and will be calibrated to alarm at 500 mr/hour in a gamma field.

In the use of a reactor as a device to measure neutron cross sections, the pile oscillator is often employed because of its much higher sensitivity compared to that available in static reactivity measurements. The factor limiting the available in static reactivity measurements. The factor limiting the available sensitivity is the generation of random noise, which originates in the statistical nature of the chain reaction. In other words, the nuclear reactions which maintain the chain reaction do not proceed uniformly, but rather at rates which fluctuate in time around some average values. These fluctuations limit the accuracy of measurements in the reactor.

During the period when the writer mixing fuel element was being evaluated, a small Litton glass lathe and a General Electric Fillerarc welder were used to weld the mixing spool to the fuel element. Due to the condition of these units and to the numerous difficulties encountered with them, it was deemed necessary to design and procure a semi automatic welding unit which could weld in excess of three hundred fuel elements per day.

The thickness of an oxide film on phosphor bronze helices was determined by first establishing the oxygen content of the helix "as received" and after cleansing with nitric acid. Based on the assumption that the difference between these two values was the oxygen in the film, and that the film consisted entirely of cupric oxide, the thickness of the film was calculated from the density of cupric oxide, weight of the film, and surface area of film. A value of 1080 A was calculated as the thickness by this method.

Results of four experiemental runs in the Fluorox fluidized bed reactor system are reported. The engineering feasibility of UF6 production from UF4 by use of dry air of O2, 2UF4 + O2 = UF6 + UO2F2, in an Inconel fluidized bed reactor at 800-850°C was demonstrated in two experimental tests in which greater than 90% of the theoretical amount of UF6 was collected or measured. Two runs made with crude UF4 (produced from unpurified mill concentrate) as the feed material, showed that UF6 could be produced at 700-725°C but corrosion on Inconel was prohibitive.

The major portion of transfers and inventory in the Chemical Processing Department are dependent on volume measurement. Good volume measurements are therefore essential to good SS material control. Considerable attention has been given to the volume problem especially on primary transfer points. Document HW-57888 discusses the biasing effect pf temperature on manometer oil. HW- 57866 given the procedure for vessel calibration. Other undocumented correspondence has discussed recent calibrations and certain aspects of temperature considerations in the volume determinations. However, there is a need to document for future reference the consideration given temperature and provide at the same time information which covers the temperature angle on all volume methods used in the Chemical Processing Department.

To better understand the solvent extraction process much effort has been and is being expended at ORNL and elsewhere to measure reaction kinetics of the extraction reactions. To date these efforts have been largely unsuccessful, due to the attempt to apply homogeneous reaction kinetics to two-phase systems. An optical method has been devised for analyzing the concentration profile in the vicinity of a quiescent interface during steady-state diffusion at rather large molecular fluxes. The system under study is the extraction of uranyl ion from water by a TBP solution. Considerable effort has been directed to eliminating leaks in the diffusion cell and testing the optical system/

In order to make rational predictions of the operating characteristics of uranium anion exchange contactors, an understanding of the mechanism and kinetics of the exchange is necessary. Toward this objective an effort is being made to determine the equilibrium sorption isotherms and rates of sorption of uranium on the anion exchange resin Dovex 21K.

In order to make rational predictions of the operating characteristics of uranium anion exchange contactors, an understanding of the mechanism and kinetics of the exchange is necessary. Toward this objective an effort is being made to determine the equilibrium sorption isotherms and rates of sorption of uranium on the anion exchange resin Dovex 21K.

Considerable delay has occurred in getting ratification of the Eurochemic charter by 80% of the participating nations. The French, who were not expected to ratify the charter until an elected government was again established , actually ratified under de Gaulle late in 1958.

A number of the questions which have been posed to us in the subject references are commented upon below. These have been reviewed by personanel of the Research and Engineering Operation and the Facilities Engineering Operation, Chemical Processing Department, and of the Chemical Research and Development Operation, Hanford Laboratories Operation. Particular acknowledment is given G. J Alkire, J. P. Duckworth, J. B. Fecht, R. G. Geier, E. R. Irish, H. M. Jones, G. C. Oberg, A. M. Platt, W. H. Reas, W. C. Schmidt, R. J. Sloat, W. H. Swift, M. T. Walling and L. L. Zahn of these organizations for assistance given assembling this information.

Abstract: "An experimental study was made to determine the effective shielding provided by a modern reinforced-concrete office building (AEC Headquarters building) from nuclear fallout. Pocket ionization chambers were used for measurement of the radiation-field strength. Fallout was simulated with distributed and point-source configurations of Co-60 and Ir-192 sources. Four typical sections were selected for study, and experiments were performed on each. These included an external wing with exposed basement walls and an external wing with a buried basement. Roof studies were made on an internal wing with a full basement and on the east end of wing A, which has a thin-roof construction. The thick-roof construction of 8 in. of concrete and 2 in. of rigid insulation covers all the building except the east end of wing A, which has 4 in. of concrete and 2 in. of insulation."

The final percentage of xenon created by fission in uranium and plutonium is a function of the neutron flux intensity. The flux dependence results because axenon 133 and 135 can be converted to a a stable xenon isotope by neutron capture instead of decaying into cesium.

A study was made of a method for the flame photometric determination of iron. In Part I of this report, the flame emission spectrum of iron, measured by means of a Beckman Model DU spectrophotometer with a flame attachment, is compated to that measured with an ORNL high-sensitivity, recording, single-beam instrument, in order to determine which instrument is best suited for this application. Although it was found that the Beckman product has the higher resolving power over the wavelength region of 360 to 400mu, it does no posses the sensitivity or ease of operation of the ORNL instrument. On this basis, the ORNL flame spectrophotometer is used in subsequent tests. After selecting the best-suited instrument for the flame photometric determination of iron, it was necessary to establish the optimum operating conditions for this particular method. These conditions are described in Part II.

Hastelloy F is a prime contender as a material of construction for plant dissolvers in the power fuel reprocessing program. Consequently, the fabrication and installation of dissolver was undertaken to delineate any unknown problems associated with the use of Hastelloy F; and, at the same time, to provide a vessel for development studies on the Niflex or the Sulfex processes. The purpose of this report is to describe the actual basis for design as well as to present the problems encountered during the fabrication of the vessels.

The technique of high-frequency titrimetry has been applied to the determination of thorium, uranium, sulfate, and free acid. In Part I of this report, the reproducibility of the method for the titration of standard solutions which contained 50mg of thorium in the absence of interferences is established. The coefficient of variation of the method, under these conditions, was found to be less than one per cent. In Part II, the effect of uranium on the high-frequency titration of thorium, as well as the application of the method to actual samples, is discussed. Uranium in a ratio of 5 to 1 to thorium can be tolerated. When the method is applied to the analysis of representative samples, the coefficient of variation is one per cent.

Nearly all nuclear reactors being designed and built today- whether for research, power, or productions of fissionable materials- use recirculating fluids for cooling. However, a number of production reactors are still operating with single-pass cooling by treated natural water. The Hanford Atomic Products Operation of the General Electric Company presently operates production reactors for the AEC at Richland, Washington. The first reactors were built during World War II, and utilized a standard water treatment which was designed to provide large quantities of settled, filtered Columbia River water for once-through cooling.

An empirical approach for the evaluation of shielding materials for macrochemical manipulations of spontaneously fissioning heavy elements (curium and californium) has revealed interesting comparisons. High-density metal halide solutions were compared with lead glass and with rare earth glass for use as shielding windows. Laminated shields of lead-paraffin and uranium-paraffin were compared with water and with paraffin for shielding walls.

This report provides an overview of the creation of the Liquid Metal Fuel Reactor Experiment program. It furthers the work by constructing a single loop to test all the components required for the 16 loop reactor. This utility loop was also constructed to provide a facility for testing various components such as valves and flow meters.