Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipline Leak Detection Semi-Annual Report: October 2003 - April 2004 (open access)

Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipline Leak Detection Semi-Annual Report: October 2003 - April 2004

Ophir Corporation was awarded a contract by the U. S. Department of Energy, National Energy Technology Laboratory under the Project Title ''Airborne, Optical Remote Sensing of Methane and Ethane for Natural Gas Pipeline Leak Detection'' on October 14, 2002. The third six-month technical report contains a summary of the progress made towards finalizing the design and assembling the airborne, remote methane and ethane sensor. The vendor has been chosen and is on contract to develop the light source with the appropriate linewidth and spectral shape to best utilize the Ophir gas correlation software. Ophir has expanded upon the target reflectance testing begun in the previous performance period by replacing the experimental receiving optics with the proposed airborne large aperture telescope, which is theoretically capable of capturing many times more signal return. The data gathered from these tests has shown the importance of optimizing the fiber optic receiving fiber to the receiving optic and has helped Ophir to optimize the design of the gas cells and narrowband optical filters. Finally, Ophir will discuss remaining project issues that may impact the success of the project.
Date: May 12, 2004
Creator: Myers, Jerry
Object Type: Report
System: The UNT Digital Library
Borehole Data Package for Four CY 2003 RCRA Wells 299-E27-4, 299-E27-21, 299-E27-22, and 299-E27-23 at Single-Shell Tank, Waste Management Area C, Hanford Site, Washington (open access)

Borehole Data Package for Four CY 2003 RCRA Wells 299-E27-4, 299-E27-21, 299-E27-22, and 299-E27-23 at Single-Shell Tank, Waste Management Area C, Hanford Site, Washington

Four new Resource Conservation and Recovery Act (RCRA) groundwater monitoring wells were installed at the single-shell tank farm Waste Management Area (WMA) C in fiscal year 2003 to fulfill commitments for well installations proposed in the draft Hanford Federal Facility Agreement and Consent Order milestone M-24-00. Well 299-E27-22, installed upgradient, was drilled through the entire uppermost unconfined aquifer to the basalt and wells 299-E27-4, 299-E27-21 and 299-E27-23 were drilled approximately 40 feet into the uppermost unconfined aquifer and installed downgradient of the WMA. Specific objectives for these wells include monitoring the impact, if any, that potential releases from inside the WMA may have on current groundwater conditions (i.e., improved network coverage) and differentiating upgradient groundwater contamination from contaminants released at the WMA. This report supplies the information obtained during drilling, characterization, and installation of the four new groundwater monitoring wells. This document also provides a compilation of hydrogeologic and well construction information obtained during drilling, well development, aquifer testing, and sample collection/analysis activities.
Date: May 12, 2004
Creator: Williams, Bruce A. & Narbutovskih, Susan M.
Object Type: Report
System: The UNT Digital Library
Conceptual Design of a Simplified Skid-Mounted Caustic-Side Solvent Extraction Process for Removal of Cesium from Savannah Rive Site High-Level Waste (open access)

Conceptual Design of a Simplified Skid-Mounted Caustic-Side Solvent Extraction Process for Removal of Cesium from Savannah Rive Site High-Level Waste

This report presents the results of a conceptual design of a solvent extraction process for the selective removal of {sup 137}Cs from high-level radioactive waste currently stored in underground tanks at the U.S. Department of Energy's Savannah River Site (SRS). This study establishes the need for and feasibility of deploying a simplified version of the Caustic-Side Solvent Extraction (CSSX) process; cost/benefit ratios ranging from 33 to 55 strongly support the considered deployment. Based on projected compositions, 18 million gallons of dissolved salt cake waste has been identified as having {sup 137}Cs concentrations that are substantially lower than the worst-case design basis for the CSSX system that is to be deployed as part of the Salt Waste Processing Facility (SWPF) but that does not meet the waste acceptance criteria for immobilization as grout in the Saltstone Manufacturing and Disposal Facility at SRS. Absent deployment of an alternative cesium removal process, this material will require treatment in the SWPF CSSX system, even though the cesium decontamination factor required is far less than that provided by that system. A conceptual design of a CSSX processing system designed for rapid deployment and having reduced cesium decontamination factor capability has been performed. The proposed accelerated-deployment …
Date: May 12, 2004
Creator: Birdwell, JR.J.F.
Object Type: Report
System: The UNT Digital Library
Coupled Environmental Processes and Long-term Performance of Landfill Covers in the northern Mojave Desert (open access)

Coupled Environmental Processes and Long-term Performance of Landfill Covers in the northern Mojave Desert

Evapotransiration (ET) covers have gained widespread acceptance as a closure feature for waste disposal sites, particularly in the arid and semi-arid regions of the southwestern U.S. But as landforms, ET covers are subject to change over time because of processes such as pedogenesis, hydrologic processes, vegetation establishment and change, and biological processes. To better understand the effects of coupled process changes to ET covers, a series of four primary analog sites in Yucca Flat on the Nevada Test Site, along with measurements and observations from other locations in the Mojave Desert, were selected to evaluate changes in ET covers over time. The analog sites, of varying ages, were selected to address changes in the early post-institutional control period, the 1,000-year compliance period for disposal of low-level and mixed low-level waste, and the 10,000-year compliance period for transuranic waste sites.
Date: May 12, 2004
Creator: Shafer, David; Young, Michael; Zitzer, Stephen; McDonald, Eric & Caldwell, Todd
Object Type: Report
System: The UNT Digital Library
CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES (open access)

CROSSCUTTING TECHNOLOGY DEVELOPMENT AT THE CENTER FOR ADVANCED SEPARATION TECHNOLOGIES

This Technical Progress Report describes progress made on the seventeen subprojects awarded in the first year of Cooperative Agreement DE-FC26-02NT41607: Crosscutting Technology Development at the Center for Advanced Separation Technologies. This work is summarized in the body of the main report: the individual sub-project Technical Progress Reports are attached as Appendices. Due to the time taken up by the solicitation/selection process, these cover the initial 6-month period of project activity only. The U.S. is the largest producer of mining products in the world. In 1999, U.S. mining operations produced $66.7 billion worth of raw materials that contributed a total of $533 billion to the nation's wealth. Despite these contributions, the mining industry has not been well supported with research and development funds as compared to mining industries in other countries. To overcome this problem, the Center for Advanced Separation Technologies (CAST) was established to develop technologies that can be used by the U.S. mining industry to create new products, reduce production costs, and meet environmental regulations. Originally set up by Virginia Tech and West Virginia University, this endeavor has been expanded into a seven-university consortium--Virginia Tech, West Virginia University, University of Kentucky, University of Utah, Montana Tech, New Mexico Tech …
Date: May 12, 2004
Creator: Rimmer, Hugh W.
Object Type: Report
System: The UNT Digital Library
Deflagration of HMX-Based Explosives at High Temperatures and Pressures (open access)

Deflagration of HMX-Based Explosives at High Temperatures and Pressures

We measure the deflagration behavior of energetic materials at extreme conditions (up to 520K and 1 GPa) in the LLNL High Pressure Strand Burner, thereby obtaining reaction rate data for prediction of violence of thermal explosions. The apparatus provides both temporal pressure history and flame time-of-arrival information during deflagration, allowing direct calculation of deflagration rate as a function of pressure. Samples may be heated before testing. Here we report the deflagration behavior of several HMX-based explosives at pressures of 10-600 MPa and temperatures of 300-460 K. We find that formulation details are very important to overall deflagration behavior. Formulations with high binder content (>15 wt%) deflagrate smoothly over the entire pressure range regardless of particle size, with a larger particle size distribution leading to a slower reaction. The deflagration follows a power law function with the pressure exponent being unity. Formulations with lower binder content ({le} 10% or less by weight) show physical deconsolidation at pressures over 100-200 MPA, with transition to a rapid erratic deflagration 10-100 times faster. High temperatures have a relatively minor effect on the deflagration rate until the HMX {beta} {yields} {delta} phase transition occurs, after which the deflagration rate increases by more than a factor …
Date: May 12, 2004
Creator: Maienschein, J. L.; Wardell, J. F.; DeHaven, M. R. & Black, C. K.
Object Type: Article
System: The UNT Digital Library
DESIGN, CONSTRUCTION, AND STATUS OF ALL NIOBIUM SUPERCONDUCTING PHOTOINJECTOR AT BNL. (open access)

DESIGN, CONSTRUCTION, AND STATUS OF ALL NIOBIUM SUPERCONDUCTING PHOTOINJECTOR AT BNL.

We present here the design and construction of an all niobium superconducting RF injector to generate high average current, high brightness electron beam. A 1/2 cell superconducting cavity has been designed, built, and tested. A cryostat has been built to cool the cavity to {approx}2 K. The RF system can deliver up to 500 W at 1.3 GHz to the cavity. A mode-locked Nd:YVO{sub 4} laser, operating at 266 nm with 0.15 W average power, phase locked to the RF, will irradiate a laser cleaned Nb surface at the back wall of the cavity. Description of critical components and their status are presented in the paper. Based on DC measurements, QE of up to 10{sup 4} can be expected from such cavity.
Date: May 12, 2004
Creator: SRINIVASAN-RAO,T. BEN-ZVI,I. BURRILL,A. CITVER,G. ET AL.
Object Type: Article
System: The UNT Digital Library
DWPF Glass Air-Lift Pump Life Cycle Testing and Plant Implementation (open access)

DWPF Glass Air-Lift Pump Life Cycle Testing and Plant Implementation

Due to the accelerated cleanup at the Savannah River Site (SRS), efforts are underway to increase the glass melt rate and hence the high level waste processing throughput at the SRS Defense Waste Processing Plant Facility (DWPF). One of the proposed process/equipment improvements is a glass air-lift pump. The use of a glass air-lift pump to increase melt rate in the DWPF Melter has been investigated via several techniques including lab scale testing on various melters. The final test before implementation in DWPF was a long-term life cycle test (several months in duration) on a full size pump. The air-lift pump was successfully tested and no major problems were found. Based on this test a unit was designed and fabricated for DWPF and was installed in the DWPF Melter in February 2004.
Date: May 12, 2004
Creator: SMITH, MICHAEL
Object Type: Report
System: The UNT Digital Library
Elections: Electronic Voting Offers Opportunities and Presents Challenges (open access)

Elections: Electronic Voting Offers Opportunities and Presents Challenges

Testimony issued by the General Accounting Office with an abstract that begins "The technology used to cast and count votes is one aspect of the multifaceted U.S. election process. GAO examined voting technology, among other things, in a series of reports that it issued in 2001 following the problems encountered in the 2000 election. In October 2002, the Congress enacted the Help America Vote Act, which, among other things, established the Election Assistance Commission (EAC) to assist in the administration of federal elections. The act also established a program to provide funds to states to replace older punch card and lever machine voting equipment. As this older voting equipment has been replaced with newer electronic voting systems over the last 2 years, concerns have been raised about the vulnerabilities associated with certain electronic voting systems. Among other things, GAO's testimony focuses on attributes on which electronic voting systems can be assessed, as well as design and implementation factors affecting their performance. GAO also describes the immediate and longer term challenges confronting local jurisdictions in using any type of voting equipment, particularly electronic voting systems."
Date: May 12, 2004
Creator: United States. General Accounting Office.
Object Type: Text
System: The UNT Digital Library
Electroweak Supersymmetry with an Approximate U(1)_PQ (open access)

Electroweak Supersymmetry with an Approximate U(1)_PQ

A predictive framework for supersymmetry at the TeV scale is presented, which incorporates the Ciafaloni-Pomarol mechanism for the dynamical determination of the \mu parameter of the MSSM. It is replaced by (\lambda S), where S is a singlet field, and the axion becomes a heavy pseudoscalar, G, by adding a mass, m_G, by hand. The explicit breaking of Peccei-Quinn (PQ) symmetry is assumed to be sufficiently weak at the TeV scale that the only observable consequence is the mass m_G. Three models for the explicit PQ breaking are given; but the utility of this framework is that the predictions for all physics at the electroweak scale are independent of the particular model for PQ breaking. Our framework leads to a theory similar to the MSSM, except that \mu is predicted by the Ciafaloni-Pomarol relation, and there are light, weakly-coupled states in the spectrum. The production and cascade decay of superpartners at colliders occurs as in the MSSM, except that there is one extra stage of the cascade chain, with the next-to-LSP decaying to its"superpartner" and \tilde{s}, dramatically altering the collider signatures for supersymmetry. The framework is compatible with terrestrial experiments and astrophysical observations for a wide range of m_G and<s>. …
Date: May 12, 2004
Creator: Hall, L.J. & Watari, T.
Object Type: Article
System: The UNT Digital Library
Environment Assessment, Resource Evaluation, and Underground Science in Southeastern California and Southwestern Nevada (open access)

Environment Assessment, Resource Evaluation, and Underground Science in Southeastern California and Southwestern Nevada

The geologically unique region of southeastern California and southwestern Nevada has both very high peaks and the lowest point, Death Valley, in the U.S. These features have significant effects on research in nuclear waste disposal, climate change, and evaluation of the potential for underground science in that region. These areas of scientific research can be further coordinated and expanded: (1) For nuclear waste, the studies of the Yucca Mountain site northeast of Death Valley contribute to the understanding of unsaturated and saturated flow and transport in an arid environment, with sensitivity to infiltration, under present-day and future climate conditions. (2) For climate research, water resources in hydrographic basins are being evaluated, in light of the prediction that there will be large decreases in snow accumulations (by 50%) in the 21st century. Further coupling of general circulation models with subsurface processes can increase understanding of hydrological responses to climate changes, with findings potentially applicable to other climate-stressed regions. (3) The combination of earth science testing and physics experimentation in underground laboratories signifies a promising research opportunity for the Death Valley region. Telescope Peak (along the western border of Death Valley), Boundary Peak (along the California-Nevada border), Mount Charleston (outside Las Vegas), …
Date: May 12, 2004
Creator: Wang, J.
Object Type: Article
System: The UNT Digital Library
Federal Individual Income Tax Thresholds for 2004 (open access)

Federal Individual Income Tax Thresholds for 2004

This report presents the tax thresholds for various families for tax year 2004.
Date: May 12, 2004
Creator: Esenwein, Gregg
Object Type: Report
System: The UNT Digital Library
Federal Reserve Banks: Areas for Improvement in Computer Controls (open access)

Federal Reserve Banks: Areas for Improvement in Computer Controls

Correspondence issued by the General Accounting Office with an abstract that begins "In connection with fulfilling our requirement to audit the financial statements of the U.S. government, we audited and reported on the Schedules of Federal Debt Managed by the Bureau of the Public Debt (BPD) for the fiscal years ended September 30, 2003 and 2002. As part of these audits, we performed a review of the general and application computer controls over key financial systems maintained and operated by the Federal Reserve Banks (FRB) on behalf of the Department of the Treasury's BPD. Many of the FRBs perform fiscal agent services on behalf of the U.S. government, including BPD. The debt-related services primarily consist of issuing, servicing, and redeeming Treasury securities and processing secondary market securities transfers. In fiscal year 2003, the FRBs issued about $4.1 trillion in federal debt securities to the public, redeemed about $3.8 trillion of debt held by the public, and processed about $125 billion in interest payments on debt held by the public. FRBs maintain and operate key financial applications on behalf of BPD and an array of financial and information systems to process and reconcile monies disbursed and collected on behalf of BPD."
Date: May 12, 2004
Creator: United States. General Accounting Office.
Object Type: Text
System: The UNT Digital Library
Fermilab drift tube Linac revisited (open access)

Fermilab drift tube Linac revisited

Using the PARMILA code running under PC-WINDOWS, the present performance of the Fermilab Drift Tube Linac has been analyzed in the light of new demands on the Linac/Booster complex (the Proton Source). The Fermilab Drift Tube Linac (DTL) was designed in the sixties as a proton linac with a final energy of 200 MeV and a peak current of 100mA. In the seventies, in order to enable multi-turn charge exchange injection into the Booster, the ion source was replaced by an H- source with a peak beam current of 25mA. Since then the peak beam current was steadily increased up to 55mA. In the early nineties, part of the drift tube structure was replaced with a side-coupled cavity structure in order to increase the final energy to 400 MeV. The original and still primary purpose of the linac is to serve as the injector for the Booster. As an added benefit, the Neutron Therapy Facility (NTF) was built in the middle seventies. It uses 66MeV protons from the Linac to produce neutrons for medical purposes. The Linac/Booster complex was designed to run at a fundamental cycling rate of 15Hz, but beam is accelerated on every cycle only when NTF is …
Date: May 12, 2004
Creator: Popovic, Milorad
Object Type: Report
System: The UNT Digital Library
Filtration of a Hanford AW-101 Waste Sample (open access)

Filtration of a Hanford AW-101 Waste Sample

The objectives of this test were: determine the optimum filter operating parameters to maximize filter flux; determine whether the mean filter flux across the dewatering cycle matches or exceeds the plant design throughput; dewater the feed sample to 20 wt percentage insoluble solids; wash the sample to determine which species are removed during the washing process; provide filtrate to the ion exchange test program; the project flowsheet for the separation of LAW entrained solids assumes the entrained solids slurry from ultrafiltration contains 20 wt percentage insoluble solids by weight. These tests must therefore confirm that the slurry rheology is compatible with this requirement. No solids must pass into the ultrafiltration permeate; and after the filtration stage is complete, the rig will be chemically cleaned to determine if the clean water flux can be returned to pre-operation (clean) levels.
Date: May 12, 2004
Creator: POIRIER, M.R.
Object Type: Report
System: The UNT Digital Library
A lattice with larger momentum compaction for the NLC main damping rings (open access)

A lattice with larger momentum compaction for the NLC main damping rings

Previous lattice designs for the Next Linear Collider Main Damping Rings [1] have met the specifications for equilibrium emittance, damping rate and dynamic aperture. Concerns about the effects of the damping wiggler on the beam dynamics [2] led to the aim of reducing the total length of the wiggler to a minimum consistent with the required damping rate, so high-field dipoles were used to provide a significant energy loss in the arcs. However, recent work has shown that the wiggler effects may not be as bad as previously feared. Furthermore, other studies have suggested the need for an increased momentum compaction (by roughly a factor of four) to raise the thresholds of various collective effects. We have therefore developed a new lattice design in which we increase the momentum compaction by reducing the field strength in the arc dipoles, compensating the loss in damping rate by increasing the length of the wiggler. The new lattice again meets the specifications for emittance, damping rate and dynamic aperture, while having the benefit of significantly higher thresholds for a number of instabilities.
Date: May 12, 2004
Creator: Wolski, Andrzej; Raubenheimer, Tor O.; Woodley, Mark & Wu, Juhao
Object Type: Article
System: The UNT Digital Library
Modeling radiation loads to detectors in a SNAP mission (open access)

Modeling radiation loads to detectors in a SNAP mission

In order to investigate degradation of optical detectors of the Supernova Acceleration Project (SNAP) space mission due to irradiation, a three-dimensional model of the satellite has been developed. Realistic radiation environment at the satellite orbit, including both galactic and trapped in radiation belts cosmic rays, has been taken into account. The modeling has been performed with the MARS14 Monte Carlo code. In a current design, the main contribution to dose accumulated in the photodetectors is shown to be due to trapped protons. A contribution of primary {alpha}-particles is estimated. Predicted performance degradation for the photo-detector for a 4-year space mission is 40% and can be reduced further by means of shielding optimization.
Date: May 12, 2004
Creator: al., Nikolai V. Mokhov et
Object Type: Article
System: The UNT Digital Library
Nuclear Physics Laboratory, University of Colorado, Final Progress Report (open access)

Nuclear Physics Laboratory, University of Colorado, Final Progress Report

OAK-B135 The results and progress of research funded by DOE grant number DOE-FG03-95ER40913 at the University of Colorado at Boulder is described. Includes work performed at the HERMES experiment at DESY to study the quark structure of the nucleon and the hadronization process in nuclei, as well as hadronic reactions studied at LAMPF, KEK, and Fermilab.
Date: May 12, 2004
Creator: Kinney, E.R., ed.
Object Type: Report
System: The UNT Digital Library
On the theory and simulation of multiple Coulomb scattering of heavy charged particles (open access)

On the theory and simulation of multiple Coulomb scattering of heavy charged particles

The Moliere theory of multiple Coulomb scattering is modified to take into account difference between scattering off atomic nuclei and electron. A simple analytical expression for angular distribution of charged particles passing through a thick absorber is found. It does not assume any special form for a differential scattering cross section and has wider range of applicability than a Gaussian approximation. A well-known method to simulate multiple Coulomb scattering is based on the different treatment of ''soft'' and ''hard'' collisions. An angular deflection in a large number of ''soft'' collisions is sampled using the proposed distribution function, a small number of ''hard'' collision are simulated directly. A boundary between ''hard'' and ''soft'' collisions is defined providing a precise sampling of a scattering angle (1% level) and a small number of ''hard'' collisions. A corresponding simulating module takes into account projectile and nucleus charged distributions and exact kinematics of a projectile-electron interactions.
Date: May 12, 2004
Creator: Striganov, Sergei I.
Object Type: Article
System: The UNT Digital Library
Parallelizing the MARS15 Code with MPI for shielding applications (open access)

Parallelizing the MARS15 Code with MPI for shielding applications

The MARS15 Monte Carlo code capabilities to deal with time-consuming deep penetration shielding problems and other computationally tough tasks in accelerator, detector and shielding applications, have been enhanced by a parallel processing option. It has been developed, implemented and tested on the Fermilab Accelerator Division Linux cluster and network of Sun workstations. The code uses MPI. It is scalable and demonstrates good performance. The general architecture of the code, specific uses of message passing, and effects of a scheduling on the performance and fault tolerance are described.
Date: May 12, 2004
Creator: Mokhov, Mikhail A. Kostin and Nikolai V.
Object Type: Article
System: The UNT Digital Library
Real-space formulation of the electrostatic potential and total energy of solids (open access)

Real-space formulation of the electrostatic potential and total energy of solids

We develop expressions for the electrostatic potential and total energy of crystalline solids which are amenable to direct evaluation in real space. Unlike conventional reciprocal space formulations, no Fourier transforms or reciprocal lattice summations are required, and the formulation is well suited for large-scale, parallel computations. The need for reciprocal space expressions is eliminated by replacing long-range potentials by equivalent localized charge distributions and incorporating long-range interactions into boundary conditions on the unit cell. In so doing, a simplification of the conventional reciprocal space formalism is obtained. The equivalence of the real- and reciprocal space formalisms is demonstrated by direct comparison in self-consistent density-functional calculations.
Date: May 12, 2004
Creator: Pask, J E & Sterne, P A
Object Type: Article
System: The UNT Digital Library
Recent enhancements to the MARS15 code (open access)

Recent enhancements to the MARS15 code

The MARS code is under continuous development and has recently undergone substantial improvements that further increase its reliability and predictive power in numerous shielding, accelerator, detector and space applications. The major developments and new features of the MARS15 (2004) version described in this paper concern an extended list of elementary particles and arbitrary heavy ions and their interaction cross-sections, inclusive and exclusive nuclear event generators, module for modeling particle electromagnetic interactions, enhanced geometry and histograming options, improved MAD-MARS Beam Line Builder, enhanced Graphical-User Interface, and an MPI-based parallelization of the code.
Date: May 12, 2004
Creator: al., Nikolai V. Mokhov et
Object Type: Article
System: The UNT Digital Library
Recommended Amendment Mixture for in Situ Treatment of Water Management Unit Groundwater, Ashtabula Closure Project (open access)

Recommended Amendment Mixture for in Situ Treatment of Water Management Unit Groundwater, Ashtabula Closure Project

This document provides recommendations for the composition of a mixture of peat, hydroxyapatite, and sand to treat dissolved TCE, uranium, and technetium-99 in groundwater.One option for treatment was to remove the most contaminated soil and fill the engineered excavation with amendments for in situ clean up of the groundwater. A mixture of peat and hydroxyapatite will produce conditions necessary for stabilization of uranium and technetium-99, as well as anaerobic degradation of TCE. There is an ample body of literature supporting the use of peat to maintain the methanogenic conditions required for reductive dechlorination of TCE. Likewise, peat has been used to remediate uranium in groundwater. Furthermore, reducing conditions that stabilize uranium will also stabilize technetium-99. Addition of hydroxyapatite, a natural phosphate mineral, will enhance stabilization of uranium by precipitation of low solubility phosphate phases. Hydroxyapatite will also provide phosphate, a critical nutrient, to promote microbial degradation of the peat required to maintain methanogenic conditions. This is based on the composition of WMU groundwater, the groundwater flow rate, and an assumed 30-year lifetime for the outermost meter of the treatment zone. The lifetime of the treatment system as a whole depends on the size of the treatment zone. It is recommended …
Date: May 12, 2004
Creator: DENHAM, MILES
Object Type: Report
System: The UNT Digital Library
Small-Column Ion-Exchange Alternative to Remove 137Cs from Low-Curie Salt Waste: Summary of Phase 1 (open access)

Small-Column Ion-Exchange Alternative to Remove 137Cs from Low-Curie Salt Waste: Summary of Phase 1

A Small-Column Ion-Exchange (SCIX) system is being evaluated for removing cesium from the Type 2 and/or Type 3 dissolved saltcake wastes at the Savannah River Site (SRS) to ensure that the dissolved saltcake meets the waste acceptance criteria at the Saltstone Facility. Both crystalline silicotitanate (CST) and IONSIV{trademark} IE-96 zeolite were evaluated as the ion-exchange media. The accelerated alternative, using CST in the SCIX, could save as much as $3 billion in operating and storage costs and {approx}20 years in processing time compared to the current baseline. With its proven high cesium-loading capacity for the expected dissolved saltcake compositions and temperatures, CST is the preferred sorbent for SCIX. The low-cost alternative sorbent, zeolite, greatly increases the volume of sorbent required because of its much lower cesium-loading capacity. Thus, zeolite greatly increases the cost for the alternative, mainly because of the increased number of Defense Waste Processing Facility canisters required to dispose of the loaded sorbent (potentially over 7000 for zeolite, compared with <500 for CST). The models previously developed for predicting cesium loading on CST compared favorably with laboratory measurements of equilibrium distribution ratios and column loading performance using dissolved saltcake simulants. These models predict that a column of 432 …
Date: May 12, 2004
Creator: Walker, J. F. Jr.
Object Type: Report
System: The UNT Digital Library