Tetraphenylborate (TPB) is used to precipitate radioactive 137Cs from high-level nuclear waste water at the Defense Waste Processing Facility (DWPF) operated by the US DOE at the Savannah River Plant (SRP). The process is part of the procedure for the glassification of high-level nuclear waste in preparation for its long-term geological disposal. The decontaminated waste water contains millimolar quantities of TPB that will be processed into salt concretions. The transporation and use of large amounts of TPB can potentially result in the release of TPB into soil or aquatic environments. Previous study has shown that TPB degrades in soils to initially form diphenylborinic acid (DPBA) and biphenyl. DPBA appears to degrade further into other unidentified compounds which subsequently degrade into inorganic boron. The factors which promote the abiotic degradation of TPB need to be investigated since this chemical is used in the processing of radioactive wastes. TPB and its intermediate product, DPBA, have been reported to be toxic to microorganisms and plants, dependent on soil or water environments for their survival and growth.

This report describes the progress and the plan of activities in the Feasibility Study of Health Effect in populations residing near the Pinellas Plant. The period covered by the work progress is September 1, 1992 through April 30, 1993 and the period covered by the plan of the project activities is May 1 through August 31, 1993.

This report contains discussions on the following topics: Experimental program at the Fermilab Tevatron Collider: FNAL E-740; Experimental program at the superconducting super collider: Solenoidal detector collaboration; Computation development program at Iowa State University: Batch after twilight running and parallel processing; Experimental program at the University of Hawaii: Deep underwater muon and neutrino detector; Global analysis of parton distributions; high energy direct photon production; photon fragmentation functions; single transverse-spin asymmetry; associated production of Higgs Boson at collider energies; Cronin effect in photoproduction and deeply inelastic scattering; and heavy meson production.

An attempt was made to pursue [sup 129]Xe NMR as a pore measurement technique. Samples studied were synthetic imogolite (tubular aluminosilicate with gibbsite structure), sodium Y-zeolite, and an aerogel and a xerogel. Gases used were normal Xe, [sup 13]CO[sub 2], and [sup 15]N[sub 2]. Although a completely general NMR technique for measuring pore size distributions may not be possible, information about molecular motion and interactions can be obtained, because NMR is sensitive to short range interactions (1 nm or less) and to molecular dynamics in the range 10[sup [minus]2] to 10[sup [minus]6]s.

An attempt was made to pursue {sup 129}Xe NMR as a pore measurement technique. Samples studied were synthetic imogolite (tubular aluminosilicate with gibbsite structure), sodium Y-zeolite, and an aerogel and a xerogel. Gases used were normal Xe, {sup 13}CO{sub 2}, and {sup 15}N{sub 2}. Although a completely general NMR technique for measuring pore size distributions may not be possible, information about molecular motion and interactions can be obtained, because NMR is sensitive to short range interactions (1 nm or less) and to molecular dynamics in the range 10{sup {minus}2} to 10{sup {minus}6}s.

Newsletter of the Texas Department of Health discussing the news, activities, and events of the organization and other information related to health in Texas.

The roadmapping process was initiated by the US Department of Energy`s office of Environmental Restoration and Waste Management (EM) to improve its Five-Year Plan and budget allocation process. Roadmap documents will provide the technical baseline for this planning process and help EM develop more effective strategies and program plans for achieving its long-term goals. This document is a composite of roadmap assumptions and issues developed for the Idaho National Engineering Laboratory (INEL) by US Department of Energy Idaho Field Office and subcontractor personnel. The installation roadmap discusses activities, issues, and installation commitments that affect waste management and environmental restoration activities at the INEL. The High-Level Waste, Land Disposal Restriction, and Environmental Restoration Roadmaps are also included.

Fully dense, nanocrystalline ceramic articles were prepared by the new nanofabrication process. The process consists of two steps: synthesis of ceramic nanoparticles and fabrication of dense, nanocrystalline ceramic parts. The synthesis step produced 10-nanometer-diameter crystallites, and is capable of being scaled up to kilogram/hour production rates. The fabrication step produced dense parts at significantly reduced sintering temperatures and times -- representing a factor of 10--100 reduction in process energy requirements. The process was demonstrated by producing ultrafine-grained yttria-stabilized ZrO[sub 2], an important material with a variety of energy-related applications (solid electrolytes, oxygen sensors, electrode materials, thermal barrier coatings, etc.). Results from this period clearly illustrate the capabilities of this energy-efficient and directly commercializable process for producing dense, nanocrystalline, multicomponent oxide ceramics.

Fully dense, nanocrystalline ceramic articles were prepared by the new nanofabrication process. The process consists of two steps: synthesis of ceramic nanoparticles and fabrication of dense, nanocrystalline ceramic parts. The synthesis step produced 10-nanometer-diameter crystallites, and is capable of being scaled up to kilogram/hour production rates. The fabrication step produced dense parts at significantly reduced sintering temperatures and times -- representing a factor of 10--100 reduction in process energy requirements. The process was demonstrated by producing ultrafine-grained yttria-stabilized ZrO{sub 2}, an important material with a variety of energy-related applications (solid electrolytes, oxygen sensors, electrode materials, thermal barrier coatings, etc.). Results from this period clearly illustrate the capabilities of this energy-efficient and directly commercializable process for producing dense, nanocrystalline, multicomponent oxide ceramics.

The Pittsburgh Energy Technology Center of the US Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems'' Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: (1) NOx emissions not greater than one-third NSPS. (2) SOx emissions not greater than one-third NSPS. (3) Particulate emissions not greater than one-half NSPS. The specific secondary objectives are: (1) Improved ash disposability and reduced waste generation. (2) Reduced air toxics emissions. (3) Increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

The Pittsburgh Energy Technology Center of the US Department of Energy (DOE) has contracted with Combustion Engineering, Inc. (ABB CE) to perform work on the ``Engineering Development of Advanced Coal-Fired Low-Emission Boiler Systems`` Project and has authorized ABB CE to complete Phase I on a cost-reimbursable basis. The overall objective of the Project is the expedited commercialization of advanced coal-fired low-emission boiler systems. The specified primary objectives are: (1) NOx emissions not greater than one-third NSPS. (2) SOx emissions not greater than one-third NSPS. (3) Particulate emissions not greater than one-half NSPS. The specific secondary objectives are: (1) Improved ash disposability and reduced waste generation. (2) Reduced air toxics emissions. (3) Increased generating efficiency. The final deliverables are a design data base that will allow future coal-fired power plants to meet the stated objectives and a preliminary design of a commercial generation unit.

The objectives of this project are to study the effect of pretreatment methods on the two-stage liquefaction process. In particular the effects of dispersed catalysts and carbon monoxide atmospheres on a coal liquefaction process. The project is divided into three technical tasks. Task 1 and 2 deal with the analyses and liquefaction experiments, respectively, whereas Task 3 deals with the economic impact of utilizing the pretreatment methods. This quarter concentrated on Tasks 1 and 2. which are summarized below. The fractionated products from the coal liquefaction experiments conducted in Task 2 exhibited a very low H/C ratio, most likely due to the low H/C ratio of the Black Thunder recycle vehicle used in these liquefaction experiments. Wilsonville has reported the recycle vehicle as approximately 20% distillable material (1100{degree}F at one atmosphere), 20% insoluble material (CI) and 40% resid. We are now in the process of fractionating this material in order to determine its contribution to our liquefaction results. We also analyzed some of the sulfated iron catalysts for surface areas, finding that the calcined catalyst had surface areas of 76 m{sup 2}/g, compared to 6 m{sup 2}/g for the iron oxide used by Wilsonville. We also synthesized two more catalysts, …

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification; Whether article 6252-9b, section 7A(a), V.T.C.S., prohibits a former member of the Polygraph Examniers Board from appearing before the board in connection with sponsoring a polygraph intern (RQ-362)

Document issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification; Whether the Harris County Bail Bond Board is authorized to issue more than one bail bond license to a corporate surety, and related questions (RQ-463)

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

High power and radiance laser technologies developed at Lawrence Livermore National Laboratory such as copper-vapor and dye lasers show great promise for material processing tasks. Evaluation of models suggests significant increases in welding, cutting, and drilling capabilities, as well as applications in emerging technologies such as micromachining, surface treatment, and stereolithography. Copper lasers currently operate at 1.8 kW output at approximately three times the diffraction limit and achieve mean time between failures of more than 1,000 hours. Dye lasers have near diffraction limited beam quality at greater than 1.0 kW. Results from cutting and drilling studies in titanium and stainless steel alloys show that cuts and holes with extremely fine features can be made with dye and copper-vapor lasers. High radiance beams produce low distortion and small heat-affected zones. The authors have accomplished very high aspect ratios (> 60:1) and features with micron scale (5-50 {mu}m) sizes. The paper gives a description of the equipment; discusses cutting theory; and gives experimental results of cutting and drilling studies on Ti-6Al-4V and 304 stainless steel.

Letter opinion issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Dan Morales, regarding a legal question submitted for clarification: Whether the County of El Paso may use the county law library fund to maintain statutes and reporters located in the chambers of district and county courts (ID# 19317)

A short calculation was done to check the attachment method of the radiation shield to it's LN2 cooling tubes. The case considered was only for the obround chimney section. The proposed attachment method was to use 1/8-inch plug welds spaced every 5-inch along the length of the shield. The calculations were done conservatively for 6-inch spacing between plug welds. The criteria used was that the LN2 shield warmest temperature be less than 2 K above the temperature of the LN2 fluid. Using a very conservative heat transfer model. the calculations predict that the warmest temperature on the radiation shield will be < 1.4 K warmer than the LN2 fluid temperature.

This engineering note documents the calculations done to determine the chimney heat loads. These heat load numbers were reported in the D0 solenoid upgrade design report. The heat loads to the LN2 circuit were done by Andrew Stefanik, RDIMechanical Systems group. They were part of his LN2 shield calculations dated 2/23/93. Pages 1 thru 3 of his calculations that apply to the chimney are attached. The heat loads to the LHe circuit were done originally on 12/16/92 and then revised on 12/23/92 to be more conservative. The raw calculations are attached. I include both the original 12/16 version and the 12/23 revised version to document the amount of conservativeness added.

This engineering note contains miscellaneous information about the rectangular liquid helium supply tube for the D-Zero solenoid. The information is fairly superficial, but could be used as a starting point for a future engineer who is going to specify and puchase the tubing. The chimney contains 4 conductors attached to an aluminum liquid helium supply tube. Because good thermal contact is desired, the tube will have flat sides. Aluminum is chosen to match the thermal contraction coefficient of the superconductor's aluminum stabilizer. The type of aluminum is chosen as 6061-T6 because it's allowable stress in ANSI/ASME B31.3 is higher than for other alloys. A different alloy could be chosen for extrusion reasons. The highest pressures this tubing should see will be during a quench. Current calculations predict the peak pressure during a quench to be 520 psi a for one-way relieving and 250 psia for two way relieving. Whatever the final alloy selection, the tubing needs to have a high enough allowable working pressure. There is very little room in the obround section of the chimney. In that portion the shape is rectangular, 12.7 mm (0.50-inch) x 31.8 mm (1.25-inch). A drawing shows the flow path cross section. This also …

This engineering note documents the calculations done to determine the relief capacity of the solenoid vacuum pumping line. The calculations were done by David Bell, a co-op student from the University of Wisconsin. The calculations are attached. The conclusion is that the vacuum pumping line has a venting capacity of 129 g/s warm helium or 298 g/s warm nitrogen. Both of these capacities are much larger than the expected operating mass flow rates of the liquid helium (5 to 15 g/s) or liquid nitrogen (2 or 3 g/s) circuits. The calculations assume the solenoid vacuum vessel is at 3 psig and the relief plate is set at 1.5 psig. Additional calculations were done to prove that the venting capacity of the vacuum pumping line exceeded flowrates due to a failure mode. These calculations are attached. Since the system is not finalized, (pipe sizes not determined, components sized...) the calculations were done by first picking reasonable line sizes based on known allowed pressure drops in the system and then doing a maximum delivery rate calculation if a line was completely severed in the vacuum space of the solenoid/control dewar. The numbers from these calculations say that failure mode flow rates are …

A plasma coating system has been developed for induction melting zirconium at 1900 C using a graphite crucible. This laminated coating system consists of plasma spraying the following materials onto the graphite: (1) molybdenum or tungsten, (2) a 50% blend by weight of the metal powder and calcia-stabilized zirconium oxide, and (3) calcia-stabilized zirconia followed by painting a final coating of nonstabilized zirconia on top of the plasma-sprayed coating system. Zirconium was melted in argon using both laminating systems without any degradation of the graphite crucible and with only a minimal amount of carbon absorption. This novel approach that is being proposed as an alternative method of melting zirconium alloys offers substantial cost savings over the standard practice of electric arc melting using a consumable electrode.

The majority of this research has been in developing a model to describe the magnetostrictive properties of Terfenol-D, Tb{sub 1{minus}x}Dy{sub x}Fe{sub y} (x = 0.7-0.75 and y = 1.8--2.0), a rare earth-iron alloy which displays much promise for use in device applications. In the first chapter an introduction is given to the phenomena of magnetization and magnetostriction. The magnetic processes responsible for the observed magnetic properties of materials are explained. An overview is presented of the magnetic properties of rare earths, and more specifically the magnetic properties of Terfenol-D. In the second chapter, experimental results are presented on three composition of Tb{sub 1{minus}x}Dy{sub x}Fe{sub y} with x = 0.7, y= 1.9, 1.95, and x= 0.73, y= 1.95. The data were taken for various levels of prestress to show the effects of composition and microstructure on the magnetic and magnetostrictive properties of Terfenol-D. In the third chapter, a theoretical model is developed based on the rotation of magnetic domains. The model is used to explain the magnetic and magnetostrictive properties of Terfenol-D, including the observed negative strictions and large change in strain. The fourth chapter goes on to examine the magnetic properties of Terfenol-D along different crystallographic orientations. In the fifth …