The research reported here in summary form was conducted under the auspices of Weapons-Supporting Research (WSR) and Institutional Research and Development (IR D). The period covered is the first half of FY90. The results reported here are for work in progress; thus, they may be preliminary, fragmentary, or incomplete. Research in the following areas are briefly described: energetic materials, tritium, high-Tc superconductors, interfaces, adhesion, bonding, fundamental aspects of metal processing, plutonium, synchrotron-radiation-based materials science, photocatalysis on doped aerogels, laser-induced chemistry, laser-produced molecular plasmas, chemistry of defects, dta equipment development, electronic structure study of the thermodynamic and mechanical properties of Al-Li Alloys, and the structure-property link in sub-nanometer materials.

Florida State University is investigating the concept of pulsed electron beams for fly ash precipitation. This report describes the results and data on three of the subtasks of this project and preliminary work only on the remaining five subtasks. Described are the modification of precharger for pulsed and DC energization of anode; installation of the Q/A measurement system; and modification and installation of pulsed power supply to provide both pulsed and DC energization of the anode. The other tasks include: measurement of the removal efficiency for monodisperse simulated fly ash particles; measurement of particle charge; optimization of pulse energization schedule for maximum removal efficiency; practical assessment of results; and measurement of the removal efficiency for polydisperse test particles. 15 figs., 1 tab. (CK)

1,1'-Diruthenocenylnaphthalene has been prepared and its molecular structure has been determined by x-ray diffraction, in order to compare its structure with that of its iron analog. The molecular structure of the half oxidized form of 1,1'-diferocenylnaphthalene has also be determined. Comparison of these structures has made it possible to assign the origins of observed deformations in these substances. Polymeric, face-to-face metallocenes related to the 1,8-dimetallocenylnaphthalenes (M=Fe, Ru) have also been prepared by coupling of 1,1'-bis(chlorozinc)metallocenes with 1,8- diiodonaphthalene. A more general approach to the synthesis of polymeric face-to-face metallocenes incorporating other transition metals has been developed. This involves the sequential replacement of iodo groups in 1,8-diiodonaphthalene with cyclopentadiene and the complexation of these rings with metals. A short synthesis of 4-n-butyl-1,8-diiodonaphthalene has been achieved. The molecular structure of a 2,3-oligomeric face-to-face ferrocene has been determined and shown to have the unexpected cis arrangement of naphthalene rings. 6 refs.

The Physics Section vacuum deposition system is available for several types of thin film techniques. This vacuum evaporation system operates in the high vacuum range. The evaporation source is a resistive heating element, either a boat or a filament design. Coating is then line of sight from the source. Substrates to be coated can have a maximum diameter of 17 inches. At this time the variations in the thickness of the coatings can be controlled, by monitor, to within about 100 angstroms. The system diagrams follow the Operation Procedures and the Sample Coating Procedures provided in this document. 3 figs.

The amplitude attenuation and the phase shift of the correction magnet field inside the APS storage ring vacuum chamber due to the eddy current effect were measured. A circuit to compensate for this effect was then inserted between the signal source and the magnet power supply. The amplitude was restored with an error of less than 20% of the source signal amplitude and the phase shift was reduced from 80{degrees} to 12{degrees} at 10 Hz.

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This report describes the basic features and operating principles of the Electron Beam Ion Trap. The differences between EBIT and other sources of highly charged ions are outlined. Its features and operating parameters are discussed. The report also explains why certain design choices were necessary and the constraints involved in building an electron beam ion trap. EBIT's evaporation cooling system is described in detail. 13 refs., 8 figs.

We recently examined Argonne supplied Wyodak coal under both thermal (no added water, under N{sub 2}) and hydrothermal (liquid water present, under N{sub 2}) conditions at 350{degrees}C for periods of 30 min. and 5 hr. We found that the coal produces a tar that is deposited on the reactor insert walls solely at hydrothermal conditions. The shift from 30 min. to 5 hr. yields a tar that is more volatile and has a slightly increased molecular weight. The coals recovered from thermal and hydrothermal treatments are different by pyrolysis-field ionization mass spectrometry (py-FIMS). Specifically, the hydrothermal condition yields py-FIMS volatiles with a higher weight average molecular weight and greater volatility. They are thus less polar, a conclusion consistent with other py-FIMS data showing that the volatiles from the hydrothermally treated coal are lower in phenolics. Our results show that the phenols and catechols in the coal behave very differently. Our data are consistent with a scheme in which the catechol units in the coal engage in condensation at thermal conditions, probably through a catalyzed process related to acidic sites on the mineral matter. The phenols in contrast are unreactive. At hydrothermal conditions, on the other hand, both are released hydrolytically. …

Any detectable leakage emanating from the argon storage dewar is undesirable; not only from a safety standpoint (eg, cryogenic burns, asphyxiation, etc.), but also small amounts of air back diffusing through leaks can render the argon unsuitable for the future physics experiments to take place within the cryostats. Whereas leakage through some of the control and manually operated valves on the dewar does not necessarily infroduce any of the above hazards directly, it could be high enough to be an economical, and perhaps an operational nuisance. Contained in the following is a compilation of the final leakage rates associated with the dewar during the period of January through May of 1990 and the raw data from which they were derived from. Also contained is a calculation of the total maximum allowable leakage rate int%ut of the dewar. The general strategy employed while leak checking the dewar was to eliminate all leaks found which could be relatively easily stopped and to reduce the more difficult ones to an acceptable level. Leakage past the seats/plugs of control and main relief valves in addition to leakage past the ball seals in the diverter valve fell into the latter category. Helium mass spectrometer leak …

Letter opinion issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether the half sister of a school board member may be hired as school cafeteria manager.

The Nevada Operations Office (NV) is responsible for supporting the nuclear test programs of the Los Alamos and Lawrence Livermore National Laboratories. This support includes the drilling of test holes for nuclear device testing a the Nevada Test Site (NTS). The purpose of this audit was to assess the effectiveness of the Department of Energy's management of test hole inventories at the NTS. Our audit disclosed that NV accumulated a large inventory of unused test holes and approved drilling additional holes for which neither laboratory (Los Alamos nor Livermore) had identified a need. The overdrilling of test holes occurred because NV did not comply with good inventory practices that would have had NV's approving official question the need for, and the timing of, the laboratories' drilling requests. Instead, NV gave perfunctory approval to the laboratories' work orders for drilling test holes, and emphasized keeping two drill rig crews busy and satisfying the laboratories' demands for dedicated drilling personnel. Although NV did not agree that overdrilling had occurred, it has cut back its drilling activities and estimated that this will save abut $7.6 million annually. NV agreed with the recommendations in the report and has taken corrective actions.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

The EMPACT experiment utilizes a broad approach to maximize its discovery potential for new phenomena accessible at the SSC. The high resolution detector has a balances emphasis on, and large acceptance for, electrons, muons, jets, and noninteracting particles, and is capable of utilizing the ultimate luminosity of the SSC. The detector emphasizes excellent calorimetry augmented by TRD tracking, and employs an innovative system of superconducting air core toroids for muon measurements. Significant engineering effort has established the feasibility of a baseline detector concept and has addressed the related issues of support facilities, assembly, and detector integration. The design has been tested against the challenges of predicted phenomena, with the expectation that this will optimize the capacity for observing the unexpected. EMPACT's international collaboration has unprecedented support from major aerospace industries who are providing tools and expertise for project design and integration, which will assure that a detector optimized for performance and cost will be available for the first collisions at the new laboratory.

The concept of a Super Fixed Target Beauty Facility (SFT) which uses a relatively low intensity 20 TeV proton beam as a generator of very high momenta B's is an exciting prospect which is very competitive with other B factory ideas. The yields of B's in such a facility are quite high (3 {times} 10{sup 10} {yields} 10{sup 11} B's per year). At this level of statistics, CP violation measurements will be possible in many modes. In addition, the fixed target configuration, because of the high momenta of the produced B's and the resulting long decay lengths, facilitates the detection and reconstruction of B's and offers unique opportunities for observation of the B decays. The limited solid angle coverage required for the fixed target spectrometer makes the cost of the facility much cheaper than other e{sup +}e{sup {minus}} or hadron collider options under consideration. The relatively low intensity 20 TeV beam (1 {yields} 2 {times} 10{sup 8} protons/second) needed for the SFT makes it possible to consider an extraction system which operates concurrently and in a non-interfering manner with the other collider experiments. One possible method for generating such a beam, crystal channeling, is discussed.

The amount of data generated by CT scanners is enormous, making the reconstruction operation slow, especially for 3-D and limited-data scans requiring iterative algorithms. The Radon transform and its inverse, commonly used for CT image reconstruction from projections, are computationally burdensome for today's single-processor computer architectures. If the processing times for the forward and inverse Radon transforms were comparatively small, a large set of new CT algorithms would become feasible, especially those for 3-D and iterative tomographic image reconstructions. In addition to image reconstruction, a fast Radon Transform Computer'' could be naturally applied in other areas of multidimensional signal processing including 2-D power spectrum estimation, modeling of human perception, Hough transforms, image representation, synthetic aperture radar processing, and others. A high speed processor for this operation is likely to motivate new algorithms for general multidimensional signal processing using the Radon transform. In the proposed workshop paper, we will first describe interpolation schemes useful in computation of the discrete Radon transform and backprojection and compare their errors and hardware complexities. We then will evaluate through statistical means the fixed-point number system required to accept and generate 12-bit input and output data with acceptable error using the linear interpolation scheme selected. These …

Letter opinion issued by the Office of the Attorney General of Texas in Austin, Texas, providing an interpretation of Texas law. It provides the opinion of the Texas Attorney General, Jim Mattox, regarding a legal question submitted for clarification; Whether the parties to a collective bargaining agreement entered into pursuant to the Fire and Police Employee Relations Act, article 5154c-1, V.T.C.S. (hereinafter, the act), may agree to the following provision: Each party for the term of this Agreement specifically waives the right to demand or petition for charges herein, whether or not the subjects were known to the parties at the time of execution hereof as proper subjects for Collective Bargaining.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

This report presents the closing talk of the workshop on AGS heavy ion program held at BNL March 5--7, 1990. The emphasis is on new questions posed by the new data presented at this meeting with emphasis on the pion-proton puzzle. 10 refs., 1 fig., 1 tab.

Research on this grant is devoted to the calculation of heavy particle collision cross sections needed for diagnostic studies of magnetic fusion plasmas. This work requires the development and testing of new theoretical methods, with the implementation of benchmarked techniques to collisions pertinent to fusion reactors. Within the last context, we have provided charge-exchange-recombination cross sections to specific n,1-levels for diagnostic studies on TFTR and for a major compilation for IAEA. We have also completed a cross section study related to the planned neutral beam current drive for ITER. In addition, calculations were completed to assess the use of He neutral atom angular scattering measurements for JT-60. Also, new theoretical methods have been developed to more accurately calculate cross sections involving either He or H{sub 2} targets and partially stripped multiply-charged ions.

Table A shows the steady state situation. One ofthe two dewars would be supplying purge gas at (a maximum of) 20 scfm, which would leak: into the room through the welding orifice. Instantaneous uniform diffusion and exhaust are assumed. Note the probability is 1 for the 20 scfm leak since it is a planned occurrence. Table B is the same situation in the event of a power failure, estimated for twice a year (2.29 x 10{sup -4} fails/hour). This assumes that the exhaust is shut down, and the dewars are not turned off. This would require the minimum exhaust to be the same as the leak: (as an approximation). These results, however, would only be valid for an infinite supply of the purge gas, and for an exceedingly long power failure. Since the supply of LAr would only last a day at most, and the power failure would not last for weeks, this result has no real significance. In fact, the time constant for the ODH equation in this case is 5717 minutes, which means it would take 20 days for all the oxygen to be displaced. A worst case scenario would be a full dewar completely emptying into the …

It was decided to use a hydraulic cylinder resting on the floor of the argon spill trough in the EC carriage to drive the EC's motion on the center beam. Space was limited due to the spill bellows and their required support and containment system. The 0.0. of the cylinder had to be limited to 3 to 3-1/2 inches, maximum. The weight of a wet EC and carriage is estimated to be 320 tons. The rolling coefficient of friction of the Tychoway rollers chosen to guide the EC and carriage along the hardened centerbeam ways is claimed to be less than 0.0025. The driver will also need to overcome the forces produced by moving (rotating) the numerous bayonets located at the top of the cryostats in the many piping systems. These forces were conservatively estimated at 1000 lbs. The drive force required to overcome these forces was then calculated to be: 320(2,000) x 0.0025 + 1,000 = 2.600 lbs. (min. required). Due to the uncertainty in the actual roller coefficient of friction and the various unknowns in estimating the resistive forces contained in the piping and cabling systems attached to the cryostat, a conservative design factor of 5 was chosen. …

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A preliminary measurement of the properties of W and Z production along with accompanying jets has been made in {anti p}p collisions at 1.8 TeV using the CDF detector at Fermilab. Distributions of jet multiplicity, and boson E{sub T}, with and without selection on jet multiplicity, were obtained. Agreement was found with perturbative QCD predictions.

A proposal for continuation of research on net ecosystem carbon dioxide and methane flux and sampling and analysis of soil samples from arctic tundra regions is presented.