This final technical report covers the work performed between September 1, 1980 and November 30, 1981 relating to Chem Systems' Liquid Phase Methanation/Shift Process. A total of 44 runs were completed covering testing of five commercially available catalysts at 900/sup 0/F, 1000 psig and 10,000 h/sup -1/ VHSV. The shifted methanation feed gas consisted of 63% H/sub 2/, 19% CO, 2% CO/sub 2/ and 16% CH/sub 4/. To determine the effects of steam, twenty of the scans had 15% steam injected into the feed gas. Each test ran for 100, 300, 600 or 1200 hours with continuous effluent sampling and temperature profile monitoring. At each of the termination points, a catalyst sample was taken from the hot spot section of the bed for analysis. Carbon was deposited on the catalyst under the methanation conditions studied. The rate of carbon deposition was primarily a function of catalyst properties and not of the thermodynamics of the methanation reaction system. In spite of heavy carbon deposition, the catalytic behavior for these systems generally remains unaffected. Physical plugging of the catalyst bed is the limiting condition of the process and not catalyst deactivation. In this respect, a controlled oxidation of the carbon deposits is …

A numerical model designed for the study of mesoscale weather phenomena is presented. It is a three-dimensional, time-dependent model based upon a mesoscale primitive-equation system, and it includes parameterizations of cloud and precipitation processes, boundary-layer transfers, and ground surface energy and moisture budgets. This model was used to simulate the lake-effect convergence over and in the lee of Lake Michigan in late fall and early winter. The lake-effect convergence is created in advected cold air as it moves first from cold land to the warm constant-temperature lake surface, and then on to cold land. A numerical experiment with a prevailing northwesterly wind is conducted for a period of twelve hours. Two local maxima of the total precipitation are observed along the eastern shore of Lake Michigan. The results in this hypothetical case correspond quite well to the observed precipitation produced by a real event in which the hypothetical conditions are approximately fulfilled.

The essentially unlimited rep-rate capability of non-linear magnetic systems has imposed strict requirements on the drive system which initiates the pulse compression. An order of magnitude increase in the rep-rates achieved by the Advanced Test Accelerator (ATA) gas blown system is not difficult to achieve in the magnetic compressor. The added requirement of having a high degree of regulation at the higher rep-rates places strict requirements on the triggerable switch for charging and de-Queing. A novel feedback technique which applies the proper bias to a magnetic core by comparing a reference voltage to the charging voltage eases considerably the regulation required to achieve low jitter in magnetic compression. The performance of the high rep-rate charging and regulation systems will be described in the following pages.

Impurities in the Tandem Mirror Experiment (TMX) have been studied using extreme ultraviolet spectroscopy. Three time-resolving absolutely-calibrated normal-incidence monochromators, one on each section of TMX, were used to study the impurity emissions in the wavelength range of 300 A to 1600 A. The instruments on the east end cell and central cell were each capable of obtaining spatially-resolved profiles from 22 chords of the plasma simultaneously while the instrument on the west end cell monitored the central chord. The impurities identified in TMX were carbon, nitrogen, oxygen, and titanium. Emphasis was placed upon determining the impurity densities and radiated power losses of the central cell; results indicate that the impurity concentrations were low - less than 0.4% for each species - and that less than 10% of the total net trapped neutral beam power was lost to radiation. The use of titanium gettering on the central cell walls was observed to decrease the brightnesses of singly- and doubly-ionized carbon and oxygen in the central cell plasma. In the end cells, oxygen was the main impurity with a concentration of about 1.5% and was injected by the neutral beams; the other impurities had concentrations of about 0.5%. Radiation losses from the …