The design of internally cooled electrical coils for the production of high frequency intensity magnetic fields presents many new aspects and combinations of the familiar modes of heat transfer. However, the customary methodology appears to be sufficient for preliminary analysis and understanding of those problems. This methodology comprises the derivation of a qualitative, approximate equation expressing the relative performance of the various parts of a system, followed by an examination of this equation in order to locate the limiting features of the system. These features are then investigated by more powerful methods, which in turn provide guidance for development research in the laboratory.

Available knowledge of precision limits in S.S. accountability measurements and/or calculations by reactor and chemical processing groups is surveyed and summarizes. Experience in comparisons of reactor (production and research) calculations versus chemical plant accountability measurements is also reported. A general tentative conclusion is that available precisions (+/- 0.54 to +/- 0.78% ) in chemical plant measurements is also reported. A general tentative conclusion is that available precisions (+/- 1.0 to +/- 11.0%) possible by calculations (nuclear and/or engineering) of power reactor systems; however, with operation and empirical experience (e.g. less than +/-1.0%

Activity and ionic impurity specifications are presented for Thorex thorium nitrate products. Two sets of specifications are given, one set for direct handling during refabrication of production reactor thorium metal slugs and the second for refabrication of future power reactor thorium metal elements by semi-remote technics. Consideration was given to the health hazard problems associated with each process step between the Thorex process and final refabricated source material in order to arrive at these specifications.

From introduction: "54 tables are given of the Z coefficients."

Report containing a description of the Oak Ridge National Laboratory's High-Flux Isotope Reactor (HFIR) and its operation.

Bench scale studies have been made of the recovery of uranium from acid leach liquors (and slurries) by solvent extracting with di (2-ethylhexyl) phosphoric acid in an organic diluent. Uranium may be stripped from the organic solvent by either alkaline or acidic reagents, the former having been studied in greater detail. On the basis of these tests, a recovery process may be considered which shows promise both from the standpoint of operation and chemical costs. Under proper conditions, vanadium can also be extracted by the di (2-ethylhexyl) phosphoric acid and stripping again may be accomplished with either acidic or alkaline reagents. Preliminary studies have been made of these possibilities. In addition to di (2-ethylhexyl) phosphoric acid, some other organophosphorus acids, have been cursorily examined in respect to their extraction and/or stripping performance.

Results of four experiemental runs in the Fluorox fluidized bed reactor system are reported. The engineering feasibility of UF6 production from UF4 by use of dry air of O2, 2UF4 + O2 = UF6 + UO2F2, in an Inconel fluidized bed reactor at 800-850°C was demonstrated in two experimental tests in which greater than 90% of the theoretical amount of UF6 was collected or measured. Two runs made with crude UF4 (produced from unpurified mill concentrate) as the feed material, showed that UF6 could be produced at 700-725°C but corrosion on Inconel was prohibitive.

This quarterly progress discusses the ongoing work at the Oak Ridge National Laboratory for the quarter ending in March 10, 1952. Topics discussed include reactor theory and design, shielding research, materials research, and includes appendixes with supplemental information.

Report issued by the Oak Ridge National Laboratory discussing aqueous homogeneous reactors used in central-station power. As stated in the introduction, "it contains an evaluation of the potentiality of producing power only, as exhibited by aqueous homogeneous systems" (p. 6). This report includes tables, and illustrations.

Report documenting the process of decontaminating low-activity fuel waste water via the Scavenging-Precipitation Ion-Exchange process. This includes analyses of the costs of the process as well as a description of the operation of the pilot plant.

This report presents "Results of a critical literature review on pressure drop due to isothermal turbulent flow in noncircular geometries" (introduction).

New systems involving the exchange of boron between boron trifluoride and boron trifluoride addition compounds have been explored. These systems have large separation factors and potentially simple reflux mechanisms. A precise determination of this separation factor for the anisole-boron trifluoride system gave the value (see report). Boron exchange was found to occur between BF and BCl3. Several homogenous catalysts have been found which activate the hydrogen-water exchange, but none are adoptable to the production of deuterium because of the slow exchange rate. Platinum or platinum oxide may be usable as a heterogeneous catalyst with proper support or dispersion techniques. The high-pressure solubility of hydrogen in several amalgams was investigated in connection with a unique countercurrent exchange system. A proposed system involving isotopic exchange between lithium dipivaloylmethane in diethyl ether and lithium hydroxide in aqueous solution was shown to give little or no isotopic separation. Column studies of the carbonate system exchange reaction were concluded with a 40°C run. Slightly higher enrichment of N15 was obtained than at 30°C . The temperature dependence of all in this system was measured between 15 and 45°C. The factor increases with temperature, showing a tendency toward a maximum near 45°C. Isotopic exchange appears to …

After two batches (~ 340 kg) of fluoride salt from the ARE were reprocessed, pilot plant operations were terminated because of a leak through which an estimated 780 g of uranium (as UF6) escaped. Of the 21 kg of highly enriched uranium in the feed, 93.12% was collected as UF6 product, 0.13% represented measured losses, and 3.72% was unaccounted for (leak). An additional 3.03% was reclaimed from NaF beds and equipment washes. The product met both chemical purity and activity specifications for product level UF6. Decontamination from fission products was essentially complete. A gross gamma D.F. was apparently limited by the low activity of the feed salt.

Report issued by the Oak Ridge National Laboratory discussing a Health Physics Instrument Manual. Descriptions, characteristics, and applications of different instruments are presented. This report includes tables, illustrations, and photographs.

In the use of a reactor as a device to measure neutron cross sections, the pile oscillator is often employed because of its much higher sensitivity compared to that available in static reactivity measurements. The factor limiting the available in static reactivity measurements. The factor limiting the available sensitivity is the generation of random noise, which originates in the statistical nature of the chain reaction. In other words, the nuclear reactions which maintain the chain reaction do not proceed uniformly, but rather at rates which fluctuate in time around some average values. These fluctuations limit the accuracy of measurements in the reactor.

The objectives of this study have been to examine the problems of the pebble-bed reactor concept and to conceive a design of a facility for investigating the feasibility of this type of reactor. The design must provide for adequate leaktightness of the contaminated-gas system and adequate maintenance of contaminated components, the most vital feasibility questions of the concept.

Sanderson & Porter have carried out a series of studies over the last four years which indicate that the pebble-bed reactor way be an attractive way to obtain low-cost power. At the request of the Atomic Energy Commission, two design studies have been carried out on this concept at the Oak Ridge National Laboratory. The first of these a preliminary design of a 10-Mw(t) reactor experiment, the PRRE, was initiated September 10, and a report on the study was issued November 1960. The second phase of the work, a conceptual design study of a 330-Mw (e) central station, was initiated November 1, and is the subject of this report.

Report issued by the Oak Ridge National Laboratory discussing a review of the Radioisotopes Program during 1964. Research and experimental projects conducted during 1964 is presented. This report includes tables, illustrations, and photographs.

A study of the thermodynamic properties of dilute aqueous hydrochloric acid solutions at elevated temperatures by an electromotive force method was undertaken for several reasons. First, a great need for fundamental information at elevated temperatures was evident from the growing number of industries making use of aqueous solutions at elevated temperatures. Second, the use of the hydrogen electrode against the silver-silver chloride electrode in dilute hydrochloric acid solutions promised to give fundamental thermodynamic information on an important electrode system as well as on hydrochloric acid over a wide temperature range.

A new gas-liquid countercurrent system (the ANCO system from Anisole-Complex) for the enrichment of boron isotopes has been developed. It is believed that use of this systems will result in a considerably lower unit cost for enriched boron-10 than was previously possible. The system utilizes the exchange reaction between BF3 (gas) and BF3·anisole (liquid) to concentrate boron-10 in the liquid phase. The single stage isotopic separation factor for this system has been found to vary from 1.039 at 0°C to 1.029 at 30°C. The isotopic exchange reaction has been shown to be rapid. Vapor pressures of the complex as a function of temperature have been measured and the heat of formation of the complex determined. Laboratory experiments show that quantitative removal of the BF3 from the complex can be accomplished by heating. A complete miniature ANCO plant was constructed and operated in the laboratory to test the feasibility of the system. The system was found to operate efficiently with a minimum of attention, and to enrich the isotopes of boron as expected. Based upon the experience obtained with the laboratory ANCO unit, a pilot plant large enough to utilize a 6-inch diameter exchange column was designed. The design calculations of …

Technical report on the activities of the Oak Ridge National Laboratory Biology Division for the report period including a list of 346 publication and lectures and 205 short articles by members of the division on their research and activities.

Study of the effects on Zircaloy-2 radiation corrosion of a high concentration of excess H2SO4 in a uranyl sulfate test solution using an in-pile loop experiment.

One of a series of experiments to test the radiation corrosion of Zircaloy-2 and other possible reactor construction materials in UO2SO4 solutions under various radiation intensities, temperatures, solution compositions, and velocities of flow past specimens.

Thorium, a fertile material, is of interest to the Reactor Program in the production of U233. Thorium can be extracted and processed to a very pure bulk metal for fabrication into solid fertile elements. There are advantages, technical and economic, for using fabricated bulk thorium dioxide rather than the metal in some applications. It is the purpose of this paper to point out these advantages and to present briefly the technology related to fabrication, radiation damage and chemical processing of ThO2.