The results of the environmental surveillance program conducted at Site A/Plot M in the Palos Forest Preserve area for 1994 are presented. The surveillance program is the ongoing remedial action that resulted from the 1976-1978 radiological characterization of the site. That study determined that very low levels of hydrogen-3 (as tritiated water) had migrated from the burial ground and were present in two nearby hand-pumped picnic wells. The current program consists of sample collection and analysis of air, surface and subsurface water, and bottom sediment.

The reaction between tuffaceous groundwater and actinide-doped SRL 165 and PNL 76-68 type glasses in a gamma radiation field has been studied at 90 degrees C for periods up to 278 days. The primary effect of the radiation field was the acidification of the leachate through the production of nitrogen acids. Acidification of the leachate was limited by bicarbonate in the groundwater, for all exposures tested. Nonirradiated experiments were performed to represent the lowest limit of radiation exposure. Both irradiated and nonirradiated experiments were performed with and without a tuff monolith present in the reaction vessel. Neither irradiation nor the presence of tuff had a major effect on the extent of glass reaction as measured by the leachate concentrations of various glass species or analysis of the reacted glass surfaces. This report discusses the results of leaching experiments performed in a gamma radiation field and in the absence of a radiation field.

Two-phase flow patterns and frictional pressure gradients in flow in small, rectangular channels are being studies as part of a larger research program addressing phase-change heat transfer of pure refrigerants and refrigerant mixtures in plate-fin heat exchangers. Small rectangular flow channels were selected as representative of plain fin geometries. The particular channel reported herein has dimensions of 19.05 {times} 3.18 mm. Adiabatic flows of air/water mixtures, with the flow channel horizontal and the channel exit at near-atmospheric conditions, were utilized in the experiments. Analysis and interpretation of the pressure data relative to observed flow pattern transitions led to an objective method for determining the plug/bubble-to-slug flow transition. This method, together with visual observations, supplemented with photographic data, was used to develop a flow pattern man. A comparison of existing flow pattern maps for circular pipes, capillary tubes, and larger rectangular channels led to the conclusion that, while qualitative agreement exists, these maps are not generally applicable on a quantitative basis to the subject small rectangular channel. Two state-of-the-art correlations for frictional pressure gradient were evaluated, with particular emphasis on the practically important ranges of total mass quality and mass flux, from the standpoint of plate-fin heat exchangers designed as evaporators. …

Highlights of the Chemical Technology Division's activities during 1990, including electrochemical technology and advanced batteries and fuel cells, technology for coal-fired magnetohydrodynamics and fluidized-bed combustion, methods for recovery of energy from municipal waste, and techniques for treatment of hazardous organic waste, the reaction of nuclear waste glass and spent fuel under conditions expected for a high-level waste repository.

This report reviews the activities and operations of the Advanced Computing Research Facility (ACRF) from February 1990 through April 1991. The ACRF is operated by the Mathematics and Computer Science Division at Argonne National Laboratory. The facility's principal objective is to foster research in parallel computing. Toward this objective, the ACRF operates experimental advanced computers, supports investigations in parallel computing, and sponsors technology transfer efforts to industry and academia.

An outline is presented for an experimental program to develop and evaluate nondestructive assay techniques applicable to holdup measurement in plutonium-containing fuel fabrication facilities. The current state-of-the-art in holdup measurements is reviewed. Various aspects of the fuel fabrication process and the fabrication facility are considered for their potential impact on holdup measurements. The measurement techniques considered are those using gamma-ray counting, neutron counting, and temperature measurement. The advantages and disadvantages of each technique are discussed. Potential difficulties in applying the techniques to holdup measurement are identified. Experiments are proposed to determine the effects of such problems as variation in sample thickness, in sample distribution, and in background radiation. These experiments are also directed toward identification of techniques most appropriate to various applications. Also proposed are experiments to quantify the uncertainties expected for each measurement.

The COMMIX-M computer code, which describes steady-state and transient single- and multi-component flows in engineering systems, has been implemented to simulate suspension flows in laminar regimes and turbulent and bubbly particulate flows. This report presents a synopsis of the present code's capabilities, with particular emphasis on the recent development of turbulence models, and explains in detail the modifications necessary to simulate particulate flows and bubbly flows. First results of computations of turbulent bubbly and particulate flows are then given and compared with results of computations reported in the literature and with preliminary experimental results obtained at the Kernforschungszentrum Karlsruhe (Germany).

This report discusses the results of the environmental protection program at Argonne National Laboratory-East (ANL) for 1991. To evaluate the effects of ANL operations on the environment, samples of environmental media collected on the site, at the site boundary, and off the ANL site were analyzed and compared to applicable guidelines and standards. A variety of radionuclides was measured in air, surface water, groundwater, soil, grass, and bottom sediment samples.

This report discusses the results of the environmental protection program at Argonne National Laboratory-East (ANL) for 1992. To evaluate the effects of ANL operations .on the environment, samples of environmental media collected on the site, at the site boundary, and off the ANL site were analyzed and compared to applicable guidelines and standards. A variety of radionuclides was measured in air, surface water, groundwater, soil, grass, and bottom sediment samples.

This annual report on the ANL environmental protection program provides the DOE, environmental agencies, and the public with information on the levels of radioactive and chemical pollutants in the vicinity of ANL and on the amounts, if any, added to the environment by ANL operations. It also summarizes compliance of ANL operations with applicable environmental laws and regulations and highlights significant accomplishments and problems related to environmental protection. The report follows the guidelines given in DOE Order 5400.1.

This report discusses the results of the environmental protection program at Argonne National Laboratory-East (ANL) for 1994. To evaluate the effects of ANL operations on the environment, samples of environmental media collected on the site, at the site boundary, and off the ANL site were analyzed and compared to applicable guidelines and standards. A variety of radionuclides was measured in air, surface water, groundwater, soil, grass, and bottom sediment samples. In addition, chemical constituents in surface water, groundwater, and ANL effluent water were analyzed.

In this dissertation the author reports on his efforts to develop a parallel genetic algorithm and apply it to the solution of set partitioning problem -- a difficult combinatorial optimization problem used by many airlines as a mathematical model for flight crew scheduling. He developed a distributed steady-state genetic algorithm in conjunction with a specialized local search heuristic for solving the set partitioning problem. The genetic algorithm is based on an island model where multiple independent subpopulations each run a steady-state genetic algorithm on their subpopulation and occasionally fit strings migrate between the subpopulations. Tests on forty real-world set partitioning problems were carried out on up to 128 nodes of an IBM SP1 parallel computer. The authors found that performance, as measured by the quality of the solution found and the iteration on which it was found, improved as additional subpopulation found and the iteration on which it was found, improved as additional subpopulations were added to the computation. With larger numbers of subpopulations the genetic algorithm was regularly able to find the optimal solution to problems having up to a few thousand integer variables. In two cases, high-quality integer feasible solutions were found for problems with 36,699 and 43,749 …

Interim report describing progress to develop glassy slag waste forms that support environmental restoration efforts.

Between 1953 and 1970, studies on the long-term effects of external x-ray and {gamma} irradiation on inbred and hybrid mouse stocks were carried out at the Biological and Medical Research Division, Argonne National Laboratory. The results of these studies, plus the mating, litter, and pre-experimental stock records, were routinely coded on IBM cards for statistical analysis and record maintenance.

The DOE is building a new generation 6-7 GeV Synchrotron Radiation Source known as the Advanced Photon Source (APS) at Argonne National Laboratory. This facility, to be completed in FY 1996, can provide 70 x-ray sources of unprecedented brightness to meet the research needs of virtually all scientific disciplines and numerous technologies. The technological research capability of the APS in the areas of energy, communications and health will enable a new partnership between the DOE and US industry. Current funding for the APS will complete the current phase of construction so that scientists can begin their applications in FY 1996. Comprehensive utilization of the unique properties of APS beams will enable cutting-edge research not currently possible. It is now appropriate to plan to construct additional radiation sources and beamline standard components to meet the excess demands of the APS users. In this APS Beamline Initiative, 2.5-m-long insertion-device x-ray sources will be built on four straight sections of the APS storage ring, and an additional four bending-magnet sources will also be put in use. The front ends for these eight x-ray sources will be built to contain and safeguard access to these bright x-ray beams. In addition, funds will be provided …

Rising interest in the nuclear physics community in a GeV C.W. electron accelerator reflects the growing importance of high-resolution short-range nuclear physics to future advances in the field. In this report major current problems are reviewed and the details of prospective measurements which could be made with a GeV C.W. electron facility are discussed, together with their impact on an understanding of nuclear forces and the structure of nuclear matter. The microtron accelerator has been chosen as the technology to generate the electron beams required for the research discussed because of the advantages of superior beam quality, low capital and operating cost and capability of furnishing beams of several energies and intensities simultaneously. A complete technical description of the conceptual design for a 2 GeV double-sided C.W. electron microtron is presented. The accelerator can furnish three beams with independently controlled energy and intensity. The maximum current per beam is 100 mircoamps. Although the precise objective for maximum beam energy is still a subject of debate, the design developed in this study provides the base technology for microtron accelerators at higher energies (2 to 6 GeV) using multi-sided geometries.

An automated accountability system for special nuclear materials (SNM) is under development at Argonne National Laboratory-West. Phase I of the development effort has established the following basic features of the system: a unique file organization allows rapid updating or retrieval of the status of various SNM, based on "batch numbers," storage location, serial number, or other attributes. Access to the program is controlled by an interactive user interface that can be easily understood by operators who have had no prior background in electronic data processing. Extensive use of structured programming techniques make the software package easy to understand and to modify for specific applications. All routines are written in FORTRAN.

This report proposes six extensions to ANS PL/I, which is being revised by the American National Standards Committee X3J1. The new features include environmental enquiry functions, generalization of restricted expressions (compile-time expressions), liberalization of the contexts of restricted expressions, a named-literal declaration type, explicit precision specification for constants, and a pragmatic statement for expressing conditions that an implementation must satisfy for acceptable compilation. Used together, these features will give numerical analysts access to properties of an implementation's floating-point arithmetic in exactly the ways required to ease the burden of tailoring a program's precision specifications to new environments. In many cases it will be possible to write PL/I programs that are completely self-adapting to their host environment. Effective definition of the environmental enquiry functions will require the incorporation of an explicitly parameterized model of floating-point arithmetic. If such a model is integrated into the Standard, numerical analysts will be able to state and prove theorems about their programs' error bounds by appealing directly to the Standard.

The design, development, and use of the software package called LINPACK, a collection of subroutines to solve various systems of simultaneous linear algebraic equations are described. The package has been designed to be machine-independent and fully portable and to run efficiently in many operating environments.

The goal of this study was to develop an iron-based alloy, similar to Type 316 stainless steel in mechanical and corrosion properties but with a reduced chromium content or, ideally, no chromium. A total of twenty-six 225-g ingots and ten 2.5 to 12 kg ingots of various compositions in the Fe-Si-Mn-Ni-C system were prepared. All ingots contained from 5 to 11 w/o silicon and drew their corrosion resistance primarily from this component. The composition ranges of the remaining major alloying elements were (in w/o) 0-24 Mn, 0-35 Ni, and 0.08 to 0.95 C. Most of the alloys were reduced to sheet, demonstrating the hot fabricability of these high-silicon alloys. The mechanical and corrosion properties of these alloys are attractive. Tensile tests showed yield strengths of 303 to 379 Mpa (44 to 55 ksi), ultimate tensile strengths of 731 to 882 MPa (106 to 128 ksi), and elongations of 34 to 77%. Air oxidation rates were lower than those of 300-series stainless steels at 1000 C. Salt water corrosion rates for these alloys fall between those of stainless steels and plain carbon steels and are 5 to 10 times lower than the rates for plain carbon steels.

Quarterly report discussing fuel cell research and development work at Argonne National Laboratory (ANL). This report describes efforts directed toward understanding and improving components of molten carbonate fuel cells and have included operation of 10-cm square cells.

Biaxial creep-fatigue data for Incoloy 800 and Type 316H stainless steel at elevated temperatures are presented. Tubular specimens were subjected to constant internal pressure and strain-controlled axial cycling with and without hold times in tension as well as in compression.

Compilation of abstracts for lectures that were presented at the NATO Advanced Study Institute on "Nonequilibrium Superconductivity, Phonons and Kapitza Boundaries." The topics primarily discuss work in the area of superconductivity, low-temperature phenomena, and energy-related problems in this field.

Procedures are given for the chemical analysis of a variety of materials of interest in battery development and research. These materials include LiCl-KCl eutectic, Li-Al alloys, lithium sulfide, lithium aluminum chloride, calcium sulfide, titanium sulfide, and various sulfides of iron, nickel, copper, and cobalt.