Discussion of Quadrupole Precession (open access)

Discussion of Quadrupole Precession

From abstract: "In this paper the motion of a nucleus with an intrinsic quadrupole moment in an external electrostatic field gradient is discussed from a classical point of view. It is shown that in the classical approximation the angular momentum may precess about the direction of strongest field gradient or about the direction of intermediate field gradient, but not about the direction of weakest field gradient. The classical precession frequencies are found to be related to the quantum mechanical dipole transition frequencies."
Date: May 31, 1962
Creator: Raich, J. C. & Good, R. H. (Roland Hamilton), 1923-
System: The UNT Digital Library
Electron Requirements of Bonds in Metal Borides (open access)

Electron Requirements of Bonds in Metal Borides

From abstract: "Electrical measurements have been made on CaB6, SrB6, BaB6, YB2, YB4, YB6, and YB12 for the purpose of testing models of the electronic structure of the boron atoms in the four boride types represented. The compounds CaB6, SrB6, and BaB6 were found to be semiconductors. The Hall coefficients of YB4 was also measured, but could not be interpreted because the free electron theory does not provide a theoretical value for comparison with experiment. The results are in agreement with the models proposed."
Date: May 28, 1962
Creator: Johnson, Robert W. & Daane, A. H. (Adrian Hill), 1919-
System: The UNT Digital Library
Molecular Spectra and Structure of the Compound, AlH3-2N(CH3)3 (open access)

Molecular Spectra and Structure of the Compound, AlH3-2N(CH3)3

This technical report discusses an infrared study of AlH3-2N(CH3)3 while the compound was in its gas phase. This investigation was then extended to include the Raman spectrum observed in liquid trimethylamine.
Date: May 25, 1962
Creator: Heitsch, C. W. & Kniseley, R. N.
System: The UNT Digital Library
Cation Exchange in Acetone-Water-Hydrochloric Acid (open access)

Cation Exchange in Acetone-Water-Hydrochloric Acid

Abstract: Distribution coefficients have been measured for the partition of metal ions between cation exchange resin and acetone-water-hydrochloric acid solutions. the differences in distribution coefficients of metal ions are greater in acetone-water media than in aqueous media of the same hydrochloric acid concentration. Using distribution coefficient data, conditions for column separations of mixtures can be selected. Column separations of metal ion mixtures can be effected by eluting with acetone-water-hydrochloric acid solutions of different compositions. Successful separations of a number of mixtures are reported.
Date: May 10, 1962
Creator: Fritz, James S. (James Sherwood), 1924- & Rettig, Thomas A.
System: The UNT Digital Library
Effect of Oxygen on Mechanical Properties of Niobium (open access)

Effect of Oxygen on Mechanical Properties of Niobium

From abstract: "The effects of oxygen on some mechanical properties of niobium were studied over the composition range of 20 ppm to 2400 ppm oxygen. The tensile properties of samples of these compositions were studied over the temperature range from room temperature to 500°C. Hardness values were obtained at room temperature only. The following observations and conclusions were made during these studies: 1. Oxygen additions to high purity niobium increase both the yield and tensile strengths of niobium at all temperatures investigated. As the temperature is increased above 250°C the effect of the first 200 ppm of oxygen has more influence than further additions on these strengths of niobium. 2. Strain aging behavior is observed. The peaks in the tensile strength versus temperature curves can be predicted with reliability by the relationship proposed by Cottrell, 3. A mechanism is proposed which, along with Cottrell's segregated atmosphere mechanism, can account for the serrated stress-strain curves obtained. This mechanism offers an explanation of the occurrence of serrations at room temperature, and the mechanism is composition dependent."
Date: May 1962
Creator: Neubauer, Edwin Paul & Wilhelm, H. A.
System: The UNT Digital Library