Fission of Gold With 112-Mev C{sup 12} Ions: A Yield-Mass and Charge- Distribution Study (open access)

Fission of Gold With 112-Mev C{sup 12} Ions: A Yield-Mass and Charge- Distribution Study

Fission prcduct cross sections were measured radiochemically and mass- spectrometrically for gold bombsrded with 112-Mev C/sup 12/ ions. Cross sections for 43 nuclides were measured for elements from nickel to barium. Thirty-six yields are either primary fission product yields (independent yields) or were corrected (with less than 25% correction) so as to represent independent yields. The independent yields were empirically systematized and a yield-mass curve was constructed. The yield-mass curve is compared with the yield-mass curves obtained from the fission of Bi with 22 and 190-Mev deuterons. The yield systematics indicate that the sum of the mass numbers of complementary fission products is 13 plus or minus 1 amu less tban that of the compound nucleus, and the sum of the charges of complemertary fission products is two units less than that of the compound nucleus. It is postulated that 9 plus or minus 1 neutrons and an alpha particle must have been emitted. Evidence is presented that at least three and possibly more of the neutrons are emitted prior to fission. The most probable charge of the fission products as a function of mass number was determined empirically. It is shown that from mass number 80 to mass number …
Date: May 23, 1960
Creator: Blann, H. M.
Object Type: Thesis or Dissertation
System: The UNT Digital Library
THE OXIDATION OF CHROMIUM(III) TO CHROMIUM(VI) IN THE PRESENCE OF PLATINUM METALS (open access)

THE OXIDATION OF CHROMIUM(III) TO CHROMIUM(VI) IN THE PRESENCE OF PLATINUM METALS

BS>Ruthenium, either as soluble salts, powdered metal, or oxide, catalyzed the oxidation of Cr(III) to Cr(VI) in dilute oxygenated sulfuric acid solutions. Under the same conditions, in the absence of ruthenium, Cr(Vl) was not produced. In a 2 M Al(NO/sub 3/)/sub 3/-1 M HNO/sub 3/ solution at atmospheric boiling point, ruthenium and compounds of ruthenium, platinum, palladium, rhodium, and osmium very markedly increased the rate at which Cr(III) was oxidized to Cr(VI). Very low concentrations of ruthenium were capable of causing the oxidation to proceed at an appreciable rate. In boiling 65% nitric acid, Cr(HI) was oxidized to Cr(VI) if reduced oxides of nitrogen were removed from solution either m the presence or absence of ruthenium; without removal of the oxides of nitrogen, detectable quantities of Cr(VI) were not formed in either case. Cr(VI) was not produced in boiling and aerated uranyl sulfate solutions containing ruthenium. (auth)
Date: May 23, 1960
Creator: Wisdom, N E; Greeley, R S & Griess, J C
Object Type: Report
System: The UNT Digital Library