This workshop was requested by Dr. Robert Marianelli, Director of the DOE-BES Chemical Sciences Division, to update the findings of the Workshop on Molecular Environmental Sciences (MES) held at Airlie, VA, in July 1995. The Airlie Workshop Report defined the new interdisciplinary field referred to as Molecular Environmental Science (MES), reviewed the synchrotron radiation methods used in MES research, assessed the adequacy of synchrotron radiation facilities for research in this field, and summarized the beam time requirements of MES users based on a national MES user survey. The objectives of MES research are to provide information on the chemical and physical forms (speciation), spatial distribution, and reactivity of contaminants in natural materials and man-made waste forms, and to develop a fundamental understanding of the complex molecular-scale environmental processes, both chemical and biological, that affect the stability, transformations, mobility, and toxicity of contaminant species. These objectives require parallel studies of ''real'' environmental samples, which are complicated multi-phase mixtures with chemical and physical heterogeneities, and of simplified model systems in which variables can be controlled and fundamental processes can be examined. Only by this combination of approaches can a basic understanding of environmental processes at the molecular-scale be achieved.

We present an overview of the electroweak physics program of the SLD experiment at the Stanford Linear Accelerator Center (SLAC). A data sample of 550K Z{sup 0} decays has been collected. This experiment utilizes a highly polarized electron beam, a small interaction volume, and a very precise pixel vertex detector. It is the first experiment at a linear electron collider. We present a preliminary result for the weak mixing angle, sin{sup 2}({theta}{sub W}{sup eff}) = 0.23110 {+-} 0.00029. We also present a preliminary result for the parity violating parameter, A{sub b} = 0.898 {+-} 0.029. These measurements are used to test for physics beyond the Standard Model.

Vehicles powered by fuel cells operate more efficiently, more quietly, and more cleanly than internal combustion engines (ICEs). Furthermore, methanol-fueled fuel cell vehicles (FCVs) can utilize major elements of the existing fueling infrastructure of present-day liquid-fueled ICE vehicles (ICEVs). DOE has maintained an active program to stimulate the development and demonstration o fuel cell technologies in conjunction with rechargeable batteries in road vehicles. The purpose of this study is to identify and assess the availability of data on FCVs, and to develop a vehicle subsystem structure that can be used to compare both FCVs and ICEV, from a number of perspectives--environmental impacts, energy utilization, materials usage, and life cycle costs. This report focuses on methanol-fueled FCVs fueled by gasoline, methanol, and diesel fuel that are likely to be demonstratable by the year 2000. The comparative analysis presented covers four vehicles--two passenger vehicles and two urban transit buses. The passenger vehicles include an ICEV using either gasoline or methanol and an FCV using methanol. The FCV uses a Proton Exchange Membrane (PEM) fuel cell, an on-board methanol reformer, mid-term batteries, and an AC motor. The transit bus ICEV was evaluated for both diesel and methanol fuels. The transit bus FCV runs …

Environmental planning and management was an integral part of the ACWA Program planning process. To ensure that environmental protection issues could be addressed expeditiously and not delay the demonstrations, the PMACWA scaled the technology demonstrations such that simplified regulatory processes and existing research and development facilities could be used. The use of enclosed facilities for the demonstrations prevents any uncontrolled discharges to the environment and made it possible to conduct environmental assessments relatively quickly. The PMACWA also arranged for public briefings to ease any community concerns over the operations with chemical weapons. These steps precluded regulatory and community resistance to the ACWA activities. The cooperation of the regulators and stakeholders has been a key element in enabling the ACWA Program to move with the speed that it has to date. Technology demonstrations are currently underway and are scheduled to be completed in late May 1999. The data collected during these demonstrations will be used to prepare and submit a summary report to Congress by August 1999. The challenge continues for the ACWA management to guide the demonstrations to completion and to plan for possible pilot testing. As the scale of the ACWA facilities increase in size, the ease of reduced …

We have built monitors for use as beam diagnostics in the narrow gap of an undulator for an FEL experiment. They utilize an intercepting screen of doped YAG scintillating crystal to make light that is imaged through a periscope by conventional video equipment. The absolute position can be ascertained by comparing the electron beam position with the position of a He:Ne laser that is observed by this pop-in monitor. The optical properties of the periscope and the mechanical arrangement of the system mean that beam can be spatially determined to the resolution of the camera, in this case approximately 10 micrometers. Our experience with these monitors suggests improvements for successor designs, which we also describe.

We describe a Fourier analysis of the diffusion-synthetic acceleration (DSA) and transport-synthetic acceleration (TSA) iteration schemes for a spatially periodic, but otherwise arbitrarily heterogeneous, medium. Both DSA and TSA converge more slowly in a heterogeneous medium than in a homogeneous medium composed of the volume-averaged scattering ratio. In the limit of a homogeneous medium, our heterogeneous analysis contains eigenvalues of multiplicity two at ''resonant'' wave numbers. In the presence of material heterogeneities, error modes corresponding to these resonant wave numbers are ''excited'' more than other error modes. For DSA and TSA, the iteration spectral radius may occur at these resonant wave numbers, in which case the material heterogeneities most strongly affect iterative performance.

The DOE's Atmospheric Radiation Measurement (ARM) Program employs both upward- and downward-looking remote-sensing instruments to measure the horizontal and vertical distributions of clouds across its Southern Great Plains (SGP) site. No single instrument is capable of completely determining these distributions over the scales of interest to ARM's Single Column Modeling (SCM) and Instantaneous Radiative Flux (IRF) groups; these groups embody the primary strategies through which ARM expects to achieve its objectives of developing and testing cloud formation parameterizations (USDOE, 1996). Collectively, however, the data from ARM's cloud-detecting instruments offer the potential for such a three-dimensional characterization. Data intercomparisons, like the ones illustrated in this paper, are steps in this direction. Examples of some initial comparisons, involving satellite, millimeter cloud radar, whole sky imager and ceilometer data, are provided herein. that many of the lessons learned can later be adapted to cloud data at the Boundary and Extended Facilities. Principally, we are concerned about: (1) the accuracy of various estimates of cloud properties at a single point, or within a thin vertical column, above the CF over time, and (2) the accuracy of various estimates of cloud properties over the Cloud and Radiation Testbed (CART) site, which can then be reduced …

Effectiveness and efficiency of software development can be greatly increased by writing modularized code using informal (styles) and formal (standards) work approaches. Software development is about connecting pieces into a coherent whole. Thus consistent work approaches provide a structure that allows individuals and teams to minimize the time and thought put into making these connections. These investments in structure return even more benefits in the maintenance phase when old code has to be examined by new programmers, or after time has passed. We present some examples of coding style for Avenue: a simplified form of Hungarian notation (notationHungarian, stringCustomerName, etc.), script naming prefixes and suffixes, and options in script headers. We demonstrate several modular, object-like utility scripts that can be used alone or combined into other utilities. These include developer tools such as a System.Echo substitute for Windows, a Window inspector, and a script for detecting and dealing with multiple display resolutions.

Diagnostics have been developed and fielded at the Nova laser facility that image scattered light in the vicinity of the final laser focusing lens. The absolute calibration of optical components exposed to the target debris have been achieved by a combination of routine in situ calibration and maintenance. The scattering observed from plasmas relevant to ignition experiments indicates that light scattered just outside the lens can be larger than that collected by the lens, and is a significant factor in the energy balance when the f number is high.

There are several goals for the neutron source strength monitor system for the International Thermonuclear Experimental Reactor (ITER). Desired is a stable, reliable, time-dependent neutron detection system which exhibits a wide dynamic range and broad energy response to incident neutrons while being insensitive to gamma rays and having low noise characteristics in a harsh reactor environment. This system should be able to absolutely calibrated in-situ using various neutron sources. An array of proportional counters of varying sensitivities is proposed along with the most promising possible locations. One proposed location is in the pre-shields of the neutron camera collimators which would allow an integrated design of neutron systems with good detector access. As part of an ongoing conceptual design for this system, the detector-specific issues of dynamic range, performance monitoring, and sensitivity will be presented. The location options of the array will be discussed and most importantly, the calibration issues associated with a heavily shielded vessel will be presented.

This report discusses the uses of programming by object-orientation. Included in this report are the following: overview of concepts; software development; user interfaces; and databases.

This document presents the radiological dose and toxicological exposure calculations for an accident scenario involved with the ventilation system used to support salt well pumping single-shell tank 241-A-101. This tank has been listed on the Hydrogen Watch List.

In situ inspections were performed on tarp-covered 55-gallon drums of transuranic (TRU) waste stored underground at the Hanford Site. These inspections were part of a task to characterize TRU drums for extent of corrosion degradation and uncertainty in TRU designation (inaccuracy in earlier assay determinations may have led to drums that actually were low-level waste to be termed TRU), and to attempt to correlate accuracy of existing records with actual drum contents. Two separate storage trench sites were investigated; a total of 90 drums were inspected with ultrasonic techniques and 104 additional drums were visually inspected. A high-humidity environment in the underground storage trenches had been reported in earlier investigations and was expected to result in substantial corrosion degradation. However, corrosion was much less than expected. Only a small percentage of drums had significant corrosion (with one breach) and the maximum rate was estimated at 0.051 mm/yr (2 mils/yr). The corrosion time of underground exposure was 14 to 15 years. These inspection results should be applicable to other similar environments (this applicability should be restricted to arid climates such as the Hanford Site) where drums are stored underground but shielded from direct soil contact by a tarp or other means. …

There has been some feeling that a PEP upgrade might reduce the need for a 6-GeV synchrotron source. In this note we compare the two sources from a user viewpoint. Specifications for each are laid out and in conclusion, it appears that the PEP ring, at best, will be a useful source for carrying out 6-GeV R&D work (related to accelerator physics and beamline optics) rather than a replacement for a 6-GeV source.

The Tower Shielding Facility (TSF) is the only reactor facility in the US that was designed and built for radiation-shielding studies in which both the reactor source and shield samples could be raised into the air to allow measurements to be made without interference from ground scattering or other spurious effects. The TSF proved its usefulness as many different programs were successfully completed. It became active in work for the Defense Atomic Support Agency (DASA) Space Nuclear Auxiliary Power, Defense Nuclear Agency, Liquid Metal Fast Breeder Reactor Program, the Gas-Cooled and High-Temperature Gas-Cooled Reactor programs, and the Japanese-American Shielding Program of Experimental Research, just to mention a few of the more extensive ones. The history of the TSF as presented in this report describes the various experiments that were performed using the different reactors. The experiments are categorized as to the programs which they supported and placed in corresponding chapters. The experiments are described in modest detail, along with their purpose when appropriate. Discussion of the results is minimal, but references are given to more extensive topical reports.

The National Ignition Facility, currently under design and construction at Lawrence Livermore National Laboratory, will be the world`s largest laser when complete. The NIF will use about 8,000 large optics of 26 different types to focus up to 192 laser beams on a dime-size target. Given the constraints of the NIF operating environment, the tasks associated with optics transport and handling require a novel, versatile transport system. The system will consist of a computer system containing guidance, traffic management and order entry functions, and four or more automated laser-guided vehicles. This transport system will transport optics enclosures that are essentially portable clean rooms and will lift, align, and position them as needed to contact and engage mating points on the laser support structure.

In May 1994, the Defense Nuclear Facilities Safety Board (DNFSB) issued DNFSB Recommendation 94-1 (Conway 1994), which identified concerns related to US Department of Energy (DOE) management of legacy fissile materials remaining from past defense production activities. The DNFSB expressed concern about the existing storage conditions for these materials and the slow pace at which the conditions were being remediated. The DNFSB also expressed its belief that additional delays in stabilizing these fissile materials would be accompanied by further deterioration of safety and unnecessary increased risks to workers and the public. In February 1995, DOE issued the DNFSB Recommendation 94-1 Implementation Plan (O`Leary 1995) to address the concerns identified in DNFSB Recommendation 94-1. The Implementation Plan (IP) identifies several DOE commitments to achieve safe interim storage for the legacy fissile materials, and constitutes DOE`s baseline DNFSB Recommendation 94-1 Integrated Program Plan (IPP). The IPP describes the actions DOE plans to implement within the DOE complex to convert its excess fissile materials to forms or conditions suitable for safe interim storage. The IPP was subsequently supplemented with an Integrated Facilities Plan and a Research and Development Plan, which further develop complex-wide research and development and long-range facility requirements and plans. The …

The Department and its contractors are responsible for ensuring that a safe and healthy work environment is provided to Department and contractor employees at its operating facilities. Contractors are responsible for establishing a comprehensive occupational safety and health program, which includes reporting of significant work-related employee injuries. The Department is responsible for monitoring the implementation of the contractor`s programs. Two performance indicators used by the Department to measure a contractor`s safety performance are the number and severity of work-related employee injuries and of lost workdays rates. The objective of the audit was to determine whether Department of Energy contractors accurately reported occupational injuries and illnesses in accordance with Departmental requirements.

Laboratory centrifugal dewatering tests were conducted to study the effects of anionic and cationic flocculants on filtration of PMCC compliance (low sulfur) and non-compliance (high sulfur) ultrafine coal slurry. The results obtained with compliance coal indicated that use of 30 g/t anionic flocculant reduced filter cake moisture from 32. 3 to 29.0 percent and increased solids recovery by two absolute percentage points. Use of cationic flocculant had no effects on solids recovery but lowered cake moisture to 27 percent at a dosage of 15 g/t. With the non-compliance coal slurry addition of 15 g/t anionic flocculant lowered cake moisture from 30 to 28.5 percent with marginal effects on solids recovery; addition of cationic flocculant reduced cake moisture by one absolute percentage point. Both flocculants showed marginal effects on solids recovery. Laboratory vacuum filter leaf filtration studies showed that use of flocculants considerably increased filtration kinetics. For example, addition of 15 g/t anionic flocculant to the compliance coal slurry increased filtration kinetics by 10 times and addition of 15 g/t.

Two programming models for parallelizing the Angular Domain Decomposition (ADD) of the discrete ordinates (S{sub n}) approximation of the neutron transport equation are examined. These are the shared memory model based on the POSIX threads (Pthreads) standard, and the message passing model based on the Message Passing Interface (MPI) standard. These standard libraries are available on most multiprocessor platforms thus making the resulting parallel codes widely portable. The question is: on a fixed platform, and for a particular code solving a given test problem, which of the two programming models delivers better parallel performance? Such comparison is possible on Symmetric Multi-Processors (SMP) architectures in which several CPUs physically share a common memory, and in addition are capable of emulating message passing functionality. Implementation of the two-dimensional,(S{sub n}), Arbitrarily High Order Transport (AHOT) code for solving neutron transport problems using these two parallelization models is described. Measured parallel performance of each model on the COMPAQ AlphaServer 8400 and the SGI Origin 2000 platforms is described, and comparison of the observed speedup for the two programming models is reported. For the case presented in this paper it appears that the MPI implementation scales better than the Pthreads implementation on both platforms.

MCNP is a general-purpose Monte Carlo code that can be used for neutron, photon, or coupled neutron/photon transport, including the capability to calculate eigenvalues for critical systems. The code treats an arbitrary three-dimensional configuration of materials in geometric cells bounded by first- and second-degree surfaces, and some special fourth-degree surfaces (elliptical tori).

This document describes the procedure to be used for the prioritization for natural phenomena hazards evaluations of existing DOE facilities in conformance with DOE Order 5480.28, `Natural Phenomena Hazards Mitigation.`

The solution-mediated syntheses and single crystal structures of (CH₃NH₃)₃·Zn₄0(AsO₄)₃ and (CH₃NH₃)₃·Zn₄O(P0₄)₃ are reported. These compounds are built up from vertex-sharing three-dimensional Zn0₄ + AsO₄/P0₄ tetrahedral frameworks encapsulating methylammonium cations in three-dimensional channel systems. These phases are closely related to the zeolite- like M₃Zn₄O(XO₄)₃·nH₂O family of phases. Crystal data for (CH₃NH₃)₃·Zn₄0(AsO₄)₃, M, = 790.47, monoclinic, space group P2₁ (No. 4), a = 7.814 (3)Å, b = 15.498 (6)Å, c = 7.815 (3) Å, {beta} = 92.91 (2)0, V = 945.1 (9) ų, Z = 2, R(F) = 3.01%, R_W(F) = 3.98% (2301 reflections, 236 parameters). Crystal data for (CH₃NH₃)₃·Zn₄0(P0₄)₃: M, = 658.63, monoclinic, space group P2₁ (No. 4), a = 7.6569 (5) Å, b = 15.241 (1)Å, c= 7.6589 (5) Å, {beta} = 92.740 (1)0, V= 892.7 (5) ų, Z = 2, R(F)= 8.07%, R_W(F)= 9.60% (2694 reflections, 106 parameters).

Due to the vast diversity of chemical media in which metal separations are executed, a wide range of ion separation materials are employed. This results in an ongoing effort to discover new phases with novel ion exchange properties. We present here the synthesis of a novel class of thermally and chemically stable microporous, niobate-based materials. Ion exchange studies show these new phases are highly selective for Sr²⁺ and other bivalent metals.