Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy (open access)

Atomic resolution mapping of the excited-state electronic structure of Cu2O with time-resolved x-ray absorption spectroscopy

We have used time-resolved soft x-ray spectroscopy to investigate the electronic structure of optically excited cuprous oxide at the O K-edge and the Cu L3-edge. The 400 nm optical excitation shifts the Cu and O absorptions to lower energy, but does not change the integrated x-ray absorption significantly for either edge. The constant integrated x-ray absorption cross-section indicates that the conduction-band and valence-band edges have very similar Cu 3d and O 2p orbital contributions. The 2.1 eV optical band gap of Cu2O significantly exceeds the one eV shift in the Cu L3- and O K-edges absorption edges induced by optical excitation, demonstrating the importance of core-hole excitonic effects and valence electron screening in the x-ray absorption process.
Date: May 2, 2010
Creator: Hillyard, P. W.; Kuchibhatla, S. V. N. T.; Glover, T. E.; Hertlein, M. P.; Huse, Nils; Nachimuthu, P. et al.
System: The UNT Digital Library
Beam-energy and laser beam-profile monitor at the BNL LINAC (open access)

Beam-energy and laser beam-profile monitor at the BNL LINAC

We are developing a non-interceptive beam profile and energy monitor for H{sup -} beams in the high energy beam transport (HEBT) line at the Brookhaven National Lab linac. Electrons that are removed from the beam ions either by laser photodetachment or stripping by background gas are deflected into a Faraday cup. The beam profile is measured by stepping a narrow laser beam across the ion beam and measuring the electron charge vs. transverse laser position. There is a grid in front of the collector that can be biased up to 125kV. The beam energy spectrum is determined by measuring the electron charge vs. grid voltage. Beam electrons have the same velocity as the beam and so have an energy of 1/1836 of the beam protons. A 200MeV H{sup -} beam yields 109keV electrons. Energy measurements can be made with either laser-stripped or gas-stripped electrons.
Date: May 2, 2010
Creator: Connolly, R.; Briscoe, B.; Degen, C.; DeSanto, L.; Meng, W.; Minty, M. et al.
System: The UNT Digital Library
Dynamically tuned high-Q AC-dipole implementation (open access)

Dynamically tuned high-Q AC-dipole implementation

AC-dipole magnets are typically implemented as a parallel LC resonant circuit. To maximize efficiency, it's beneficial to operate at a high Q. This, however, limits the magnet to a narrow frequency range. Current designs therefore operate at a low Q to provide a wider bandwidth at the cost of efficiency. Dynamically tuning a high Q resonant circuit tries to maintain a high efficiency while providing a wide frequency range. The results of ongoing efforts at BNL to implement dynamically tuned high-Q AC dipoles will be presented.
Date: May 2, 2010
Creator: Oddo, P.; Bai, M.; Dawson, W.C.; Meng, W.; Mernick, K.; Pai, C. et al.
System: The UNT Digital Library
HIGHER MODE FREQUENCY EFFECTS ON RESONANCE IN MACHINERY, STRUCTURES, AND PIPE SYSTEMS (open access)

HIGHER MODE FREQUENCY EFFECTS ON RESONANCE IN MACHINERY, STRUCTURES, AND PIPE SYSTEMS

The complexities of resonance in multi-degree of freedom systems (multi-DOF) may be clarified using graphic presentations. Multi-DOF systems represent actual systems, such as beams or springs, where multiple, higher order, natural frequencies occur. Resonance occurs when a cyclic load is applied to a structure, and the frequency of the applied load equals one of the natural frequencies. Both equations and graphic presentations are available in the literature for single degree of freedom (SDOF) systems, which describe the response of spring-mass-damper systems to harmonically applied, or cyclic, loads. Loads may be forces, moments, or forced displacements applied to one end of a structure. Multi-DOF systems are typically described only by equations in the literature, and while equations certainly permit a case by case analysis for specific conditions, graphs provide an overall comprehension not gleaned from single equations. In fact, this collection of graphed equations provides novel results, which describe the interactions between multiple natural frequencies, as well as a comprehensive description of increased vibrations near resonance.
Date: May 2, 2010
Creator: Leishear, R.
System: The UNT Digital Library
HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPE SYSTEMS (open access)

HYDROGEN IGNITION MECHANISM FOR EXPLOSIONS IN NUCLEAR FACILITY PIPE SYSTEMS

Hydrogen and oxygen generation due to the radiolysis of water is a recognized hazard in pipe systems used in the nuclear industry, where the accumulation of hydrogen and oxygen at high points in the pipe system is expected, and explosive conditions exist. Pipe ruptures at nuclear facilities were attributed to hydrogen explosions inside pipelines, in nuclear facilities, i.e., Hamaoka, Nuclear Power Station in Japan, and Brunsbuettel in Germany. Prior to these accidents an ignition source for hydrogen was questionable, but these accidents, demonstrated that a mechanism was, in fact, available to initiate combustion and explosion. Hydrogen explosions may occur simultaneously with water hammer accidents in nuclear facilities, and a theoretical mechanism to relate water hammer to hydrogen deflagrations and explosions is presented herein.
Date: May 2, 2010
Creator: Leishear, R
System: The UNT Digital Library
Improvements for operational baseband tune and coupling measurements and feedback at RHIC (open access)

Improvements for operational baseband tune and coupling measurements and feedback at RHIC

Throughout RHIC Run-9 (polarized protons) and Run-10 (gold), numerous modifications to the Baseband Tune (BBQ) system were made. Hardware and software improvements resulted in improved resolution and control, allowing the system to overcome challenges from competing 60Hz mains harmonics, other spectral content, and other beam issues. Test points from the Analog Front End (AFE) were added and connected to diagnostics that allow us to view signals, such as frequency spectra on a Sr785 dynamic signal analyser (DSA), in real time. Also, additional data can now be logged using a National Instruments DAQ (NI-DAQ). Development time using tune feedback to obtain full-energy beams at RHIC has been significantly reduced from many ramps over a few weeks, to just a few ramps over several hours. For many years BBQ was an expert-only system, but the many improvements allowed BBQ to finally be handed over to the Operations Staff for routine control.
Date: May 2, 2010
Creator: Wilinski, M.; Dawson, C.; Degen, C.; Marusic, A.; Mernick, K.; Minty, M. et al.
System: The UNT Digital Library
Microwave link phase compensation for longitudinal stochastic cooling in RHIC (open access)

Microwave link phase compensation for longitudinal stochastic cooling in RHIC

A new microwave link has been developed for the longitudinal stochastic cooling system, replacing the fiberoptic link used for the transmission of the beam signal from the pickup to the kicker. This new link reduces the pickup to kicker delay from 2/3 of a turn to 1/6 of a turn, which greatly improves the phase margin of the system and allows operation at higher frequencies. The microwave link also introduces phase modulation on the transmitted signal due to variations in the local oscillators and time of flight. A phase locked loop tracks a pilot tone generated at a frequency outside the bandwidth of the cooling system. Information from the PLL is used to calculate real-time corrections to the cooling system at a 10 kHz rate. The design of the pilot tone system is discussed and results from commissioning are described.
Date: May 2, 2010
Creator: Mernick, K.; Blaskiewicz, M.; Brennan, J. M.; Johnson, B. & Severino, F.
System: The UNT Digital Library
Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy (open access)

Probing Reaction Dynamics of Transition-Metal Complexes in Solution via Time-Resolved Soft X-ray Spectroscopy

We report the first time-resolved soft x-ray measurements of solvated transition-metal complexes. L-edge spectroscopy directly probes dynamic changes in ligand-field splitting of 3d orbitals associated with the spin transition, and mediated by changes in ligand-bonding.
Date: May 2, 2010
Creator: Huse, Nils; Kim, Tae Kyu; Khalil, Munira; Jamula, Lindsey; McCusker, James K. & Schoenlein, Robert W.
System: The UNT Digital Library
Residual-gas-ionization beam profile monitors in RHIC (open access)

Residual-gas-ionization beam profile monitors in RHIC

Four ionization profile monitors (IPMs) are in RHIC to measure vertical and horizontal beam profiles in the two rings. These work by measuring the distribution of electrons produced by beam ionization of residual gas. During the last two years both the collection accuracy and signal/noise ratio have been improved. An electron source is mounted across the beam pipe from the collector to monitor microchannel plate (MCP) aging and the signal electrons are gated to reduce MCP aging and to allow charge replenishment between single-turn measurements. Software changes permit simultaneous measurements of any number of individual bunches in the ring. This has been used to measure emittance growth rates on six bunches of varying intensities in a single store. Also the software supports FFT analysis of turn-by-turn profiles of a single bunch at injection to detect dipole and quadrupole oscillations.
Date: May 2, 2010
Creator: Connolly, R.; Fite, J.; Jao, S. & Trabocchi, C.
System: The UNT Digital Library