The Umatilla Basin Anadromous Fish Habitat Enhancement Project is funded under the Northwest Power Planning Council's Columbia River Basin Fish and Wildlife Program, Section 7.6-7.8 and targets the improvement of water quality and restoration of riparian areas, holding, spawning and rearing habitats of steelhead, spring and fall chinook and coho salmon. The project focused on implementing cooperative instream and riparian habitat improvements on private lands on the Umatilla Indian Reservation (hereafter referred to as Reservation) from April 1, 1988 to March 31, 1992. These efforts resulted in enhancement of the lower l/4 mile of Boston Canyon Creek, the lower 4 river miles of Meacham Creek and 3.2 river miles of the Umatilla River in the vicinity of Gibbon, Oregon. In 1993, the project shifted emphasis to a comprehensive watershed approach, consistent with other basin efforts, and began to identify upland and riparian watershed-wide causative factors impacting fisheries habitat and natural fisheries production capabilities throughout the Umatilla River Watershed. During the 1994-95 project period, a one river mile demonstration project was implemented on two privately owned properties on Wildhorse Creek. This was the first watershed improvement project to be implemented by the Confederated Tribes of the Umatilla Indian Reservation (CTUIR) off …

A search for cosmological supernovae has discovered a number of a type la supernovae. In particular, one at z = 0.458 is the most distant supernova yet observed. There is strong evidence from measurements of nearby type Ia supernovae that they can be considered as 'standard candles'. We plan to use these supernovae to measure the deceleration in the general expansion of the universe. The aim of our experiment is to try and observe and measure about 30 such distant supernovae in order to obtain a measurement of the deceleration parameter q{sub 0} which is related to {Omega}. Here {Omega} is the ratio of the density of the universe to the critical density, and we expect a measurement with an accuracy of about 30%.

This paper presents work to develop benchmarked theoretical models of scrape-off-layer (SOL) characteristics in diverted tokamaks by comparing shot simulations using the UEDGE plasma fluid and DEGAS neutral transport codes to measurements of the DIII-D SOL plasma. The experimental data include the radial profiles of n{sub e} T{sub e}, and T{sub i}, the divertor exhaust power, the intensity of H{sub {alpha}} emission, and profiles of the radiated power. A very simple model of the anomalous perpendicular transport rates produces consistency between the calculated and measured radial profiles of the divertor power, and of the midplane densities and temperatures. Experimentally, the measured exhaust power is now 80--90% of the input power. The simulated peak power on the outer leg of the divertor floor is now within 20% of the measured power. Various sensitivities of these comparisons to model assumptions are described. Finally, these benchmarked models have been used to examine the effects of various baffle configurations for the Radiative Divertor Upgrade in DIII-D.

The authors present a simple closed-form expression for the reflectivity from a multilayer which includes the effects of absorption, refraction, surface and substrate reflections but neglects dynamical effects. This expression reproduces the exact dynamical calculation except for the regions near the critical angle and for intense Bragg reflections. The expression is generalized to include cumulative interface roughness which follows a t{sup 1/2} power-law growth.

This site-specific Work Plan/Health and Safety Checklist (WP/HSC) is a supplement to the general health and safety plan (HASP) for Waste Area Grouping (WAG) 2 remedial investigation and site investigation (WAG 2 RI&SI) activities [Health and Safety Plan for the Remedial Investigation and Site Investigation of Waste Area Grouping 2 at the Oak Ridge National Laboratory, Oak Ridge, Tennessee (ORNL/ER-169)] and provides specific details and requirements for the WAG 2 RI&SI Sediment Transport Modeling Task. This WP/HSC identifies specific site operations, site hazards, and any recommendations by Oak Ridge National Laboratory (ORNL) health and safety organizations [i.e., Industrial Hygiene (IH), Health Physics (HP), and/or Industrial Safety] that would contribute to the safe completion of the WAG 2 RI&SI. Together, the general HASP for the WAG 2 RI&SI (ORNL/ER-169) and the completed site-specific WP/HSC meet the health and safety planning requirements specified by 29 CFR 1910.120 and the ORNL Hazardous Waste Operations and Emergency Response (HAZWOPER) Program Manual. In addition to the health and safety information provided in the general HASP for the WAG 2 RI&SI, details concerning the site-specific task are elaborated in this site-specific WP/HSC, and both documents, as well as all pertinent procedures referenced therein, will be reviewed …

This report details the evaluation of two methods of spatially characterizing the chemical composition of tank core samples using Raman spectroscopy. One method involves a spatially-scanned fiber optic probe. The fiber optic probe must be in contact with a sample to interrogate its chemical composition. The second method utilizes a line-of-sight technique involving a remote imaging spectrometer that can perform characterization over an entire surface. Measurements using the imaging technique are done remotely, requiring no contact with the sample surface. The scope of this document studies the effects of laser power, distance from each type of probe to the sample surface, and interferences unique to the two methods. This report also documents the results of comparative studies of sensitivity to ferrocyanide, a key contaminant of concern in the underground storage tanks at DOE`s Hanford site. The effect of other factors on signal intensity such as moisture content is explored. The results from the two methods are compared, and a recommendation for a Raman hot cell core scanning system is presented based on the test results. This work is part of a joint effort involving several DOE laboratories for the design and development of Raman spectroscopy systems for tank waste characterization …

This report documents the design of a 80 MW Pressurized Circulating Fluidized Bed (PCFB) boiler for the repowering of Unit 1 at the Des Moines Energy Center. Objective is to demonstrate that PCFB combined-cycle technology is cost effective and environmentally superior compared to traditional pulverized coal burning facilities.

We give an algorithm for triangulating n-vertex polygonal regions (with holes) so that no angle in the final triangulation measures more than {pi}/2. The number of triangles in the triangulation is only 0(n), improving a previous bound of 0(n{sup 2}), and the worst-case running time is 0(n log{sup 2} n). The basic technique used in the algorithm, recursive subdivision by disks, is new and may have wider application in mesh generation. We also report on an implementation of our algorithm.

A Multipurpose Canister (MPC) is analyzed for critical stresses that occur during normal handling conditions and accidental scenarios. Linear and Non-linear Finite Element Analysis is performed and the stresses at various critical locations in the MPC and its weldments are studied extensively. Progressive failure analysis of the MPC`s groove and fillet welds, is presented. The structural response of the MPC to dynamic lifting loads, to loads resulting from an accidental slippage of a crane cable carrying the MPC, and from the impact between two canisters, is evaluated. Nonlinear structural analysis is used in the evaluation of the local buckling and the ultimate failure phenomena in the shell when the steel is in the strain hardening state during impact. Results make a case for increasing the thickness of the shell and all the welds.

In work prior to the inception of this project, the authors observed that mixtures of phenolic materials and polyalkoxyaromatic molecules were appreciably more effective in catalyzing the decompositions of di-2-naphthyl ether and of di-1-naphthyl sulfide in tetralin solutions at 450{degrees}C than were the phenols by themselves, even though the polyalkoxyaromatic molecules, in the absence of phenolic co- catalysts, show essentially no catalytic activity. This was of appreciable interest in coal research because dinapthyl ether and dinapthyl sulfide have been employed as model compounds for coals in studies aimed at cleaving ether and sulfide bonds similar to those in coals. The authors proposed (R. K. Sharma, K. P. Raman, and B. Miller) that the mixed catalysts used in these studies catalyze cleavages of ether and sulfide bonds by means of a mechanism involving electron transfer from the polyalkoxyaromatics to the substrates, which are activated as electron acceptors by hydrogen bonding to phenols. Since phenols themselves are electron donors, they also proposed that the well known effects of phenols in catalyzing the conversion of coals are due to similar electron transfer mechanisms.

Pressurized, entrained gasification is a promising new technology for the clean and efficient combustion of coal. Its principle is to operate a coal gasifier at a high inlet gas velocity to increase the inflow of reactants, and at an elevated pressure to raise the overall efficiency of the process. Unfortunately, because of the extraordinary difficulties involved in performing measurements in hot, pressurized, high-velocity pilot plants, its fluid dynamics are largely unknown. Thus the designer cannot predict with certainty crucial phenomena like erosion, heat transfer and solid capture. In this context, we are conducting a study of the fluid dynamics of Pressurized Entrained Coal Gasifiers (PECGs). The idea is to simulate the flows in generic industrial PECGs using dimensional similitude. To this end, we employ a unique entrained gas-solid flow facility with the flexibility to recycle -- rather than discard -- gases other than air. By matching five dimensionless parameters, suspensions in mixtures of helium, carbon dioxide and sulfur hexafluoride simulate the effects of pressure and scale-up on the fluid dynamics of PECGs. Because it operates under cold, atmospheric conditions, the laboratory facility is ideal for detailed measurements. In the second quarter of this project, we have continued our comparisons of …

The objectives of this project are to develop a new catalyst; the kinetics for this catalyst; reactor models for trickle bed, slurry and fixed bed reactors; and to simulate the performance of fixed bed trickle flow reactors, slurry flow reactors, and fixed bed gas phase reactors for conversion of a hydrogen lean synthesis gas to isobutylene. A hydrogen-lean synthesis gas with a ratio of H{sub 2}/CO of 0.5 to 1.0 is produced from the gasification of coal, lignite, or biomass. Isobutylene is a key reactant in the synthesis of methyl tertiary butyl ether (MTBE) and of isooctanes. MTBE and isooctanes are high octane fuels used to blend with low octane gasolines to raise the octane number required for modern automobiles. The production of these two key octane boosters is limited by the supply of isobutylene. MTBE, when used as an octane enhancer, also decreases the amount of pollutants emitted from the exhaust of an automobile engine.

In particle methods, each particle represents a finite region over which there is a distribution of the field quantity of interest. The field value at any point is calculated by summing the distribution functions for all the particles. This summation procedure does not require the use of any connectivities to generate continuous fields. Various AVS modules and networks have been developed that enable us to visualize the results from particle methods. This will be demonstrated by visualizing a numerical simulation of a rising, chaotic bubble. In this fluid dynamics simulation, each particle represents a region with a specified vorticity distribution.

When a weak magnetic field is applied to a superconducting strip or disk of thickness d (of the order of the penetration depth {lambda}) much less than its width or radius, induced super-currents flow so as to prevent magnetic flux from penetrating the superconductor (except within {lambda} of the edge). A stronger field causes vortices to enter, and the profiles of the macroscopic flux density B are determined by critical-state equations describing bulk pinning. Near the sample edge, where the vortices are, the magnitude of the current density J is J{sub c}. In vortex-free regions of the sample, the magnitude of J is less than J{sub c} but is not zero. The profiles of B can be calculated analytically by assuming that J, averaged over the film thickness, is given by the difference between the values of the tangential component of B at the top and bottom surfaces of the film. This paper examines the basis for this assumption, which is equivalent to assuming that the current density is determined solely by the curvature of H, rather than by the gradient of its magnitude. It is shown that this is a good approximation for thin-film strips and disks.

This report contains results of a technical review of software, identified as LGCALC, that processes data collected by a high-resolution gamma-ray borehole logging system. The software presently operates within Westinghouse Hanford Company, Department of Geosciences, to process data collected by the Radionuclide Logging System. The software has been reviewed for its suitability for processing data to be collected by new high-resolution gamma-ray logging trucks scheduled to begin operational tests within Westinghouse Tank Waste Remediation Systems during 1994. Examination of the program code and hands-on operational tests have shown that this software is suitable for its intended use of processing high-resolution gamma-ray data obtained from borehole logging. Most of the code requires no changes, but in a few limited cases, suggestions have been made to correct errors or improve operation. Section 4 describes these changes. The technical review has confirmed the appropriateness, correctness, completeness, and coding accuracy of algorithms used to process spectral gamma-ray data, leading to a calculation of subsurface radionuclide contaminants. Running the program with test data from calibration models has confirmed that the program operates correctly. Comparisons with hand calculations have shown the correctness of the output from the program, based on known input data. Section 3 describes …

Procedures exist for waste characterization, but waste minimization and pollution prevention have not usually played a role in development of these procedures. The US Department of Energy (DOE) expects to require several million characterizations over a 30-year period to accomplish the Department`s goals in environmental restoration and waste management. The waste generated by the analytical procedures used for characterizations is a significant source of new DOE waste. We have begun investigating ways to reduce these secondary wastes, focusing on three areas: microanalysis using flow injection; reduction of solvent volume required for dissolution of waste samples for radiochemical analysis; and alternative samples preparation for analysis of organic constituents in waste samples. Preliminary results are reported.

Because dynamic instabilities are not acceptable in any commercial maglev system, it is important to consider dynamic instability in the development of all maglev systems. This study considers the stability of maglev systems based on experimental data, scoping calculations, and simple mathematical models. Divergence and flutter are obtained for coupled vibration of a three-degree-of-freedom maglev vehicle on a guideway consisting of double L-shaped aluminum segments. The theory and analysis developed in this study provides basic stability characteristics and identifies future research needs for maglev systems.

The major results of our research effort include the determination of the S-Receptor Kinase (SRK) gene structure, the demonstration of S-haplotype-associated SRK polymorphisms and possible co-evolution of SRK and SLG, the characterization of the temporal and spatial expression patterns of SRK, and the demonstration that SRK has intrinsic serine/threonine kinase activity. Our results have indicated that SLG originated from an SRK-like gene by a gene duplication event and suggested a possible molecular basis for leaky S haplotypes. The data have allowed us to develop a model of self-incompatibility based on the interaction of SRK and SLG and the activation of SRK in response to self-pollination. More generally, the information that we have obtained is potentially relevant to understanding mechanisms of signalling inplants. Thus, the interaction of membrane-based receptor protein kinases with secreted forms of their extracellular domains may represent a generalized mechanism by which receptors signal across the plant cell wall.

For several years, the Pacific Northwest Laboratory (PNL) has been investigating methods to pretreat Hanford neutralized cladding removal waste (NCRW) sludge. In the past, Zircaloy-clad metallic U fuel was chemically decladded using the Zirflex process; NCRW sludge was formed when the decladding solution was neutralized for storage in carbon-steel tanks. This sludge, which is currently stored in Tanks 103-AW and 105-AW on the Hanford Site, primarily consists of insoluble Zr hydroxides and/or oxides and NaF. Significant quantities of Al, La, U, as well as other insoluble minor constituents are present in the sludge, along with sodium and potassium nitrates, nitrites, and hydroxides in the interstitial liquid. The sludge contains about 2,000 nCi of transuranic (TRU) material per gram of dry sludge, and mixed fission products. Therefore, the sludge must be handled as high-level waste (HLW). The NCRW sludge must be pretreated before treatment (e.g., vitrification) and disposal, so that the overall cost of disposal can be minimized. The NCRW pretreatment flowsheet was designed to achieve the following objectives: (a) to separate Am and Pu from the major sludge constituents (Na, Zr). (b) to separate Am and Pu from U. (c) to concentrate Am and Pu in a small volume for …

Alkali metal catalyzed reactions between CO{sub 2}-containing brines and portland cement-based well cements can result in rapid strength reductions, increased permeability and casing corrosion, reduced well life, increased costs, and environmental concerns. Materials formed by acid-base reactions between calcium aluminate compounds and phosphate-containing solutions yield high strength, low permeability and CO{sub 2}-resistant cements when cured in hydrothermal environments. The cementing formulations are pumpable for several hours at temperatures up to 150C, thereby making their use for well completions technically feasible. When this cementing matrix was exposed in an autoclave containing Na{sub 2}CO{sub 3}-saturated brine for 120 days, < 0.4 wt% CaCO{sub 3} was produced. A conventional portland cement-based well completion material will form {approx} 10 wt% CaCO{sub 3} after only 7 days exposure. Addition of hollow aluminosilicate microspheres to the uncured matrix constituents yields slurries with densities as low as {approx} 1.2 g/cc which cure to produce materials with properties meeting the criteria for well cementing. Laboratory characterization is nearing completion, engineering scale-up is underway, and plans for field testing in a variety of geothermal fluids are being made.

Local measurements of n{sub e} and T{sub e} in the divertor region are necessary for a more complete understanding of divertor physics. We have designed an extension to the existing multipulse Thomson scattering system to measure n{sub e} in the range 5 {times} 10{sup 18} to 5 {times} 10{sup 20} m{sup {minus}3} and T{sub e} 5--500 eV, with 1 cm resolution from 1--21 cm above the floor of the DIII-D vessel, in the region of the X-point for lower single-null diverted plasmas. One of the existing 8, 20 Hz, ND:YAG lasers will be redirected to a separate vertical port, and viewed radially with a specially designed, f/6.8 lens. Fiber optics carry the light to additional polychromators whose interference filters have been optimized for low T{sub e} measurements. Other aspect of the system, including the beam path to the vessel, polychromator design, real time data acquisition, laser control, calibration facility, and DIII-D timing and data acquisition interface will be shared with the existing multipulse Thomson system. An in-situ laser alignment monitor will provide alignment information for each laser pulse.

For central p+A and Si+A collisions, the average projectile baryon stopping has been determined. The average rapidity loss of the projectile baryons is 0.85{+-}0.1, 1.35{+-}0.1, 1.50{+-}0.28, 1.66{+-}0.21, 1.88{+-}0.17 and 2.11{+-}0.13 for Si+Al, Si+Au, p+Be, p+Al, p+Cu and p+Au, respectively. For central Si+Au collisions, significant deviations from exponential M{sub {perpendicular}} dependence of the differential cross-sections are found. Protons are suppressed at low P{sub {perpendicular}} and pions are enhanced relative to a simple exponential in M{sub {perpendicular}}. This is ascribed to Fermi/Bose effects, and for pions the full (Y,pt) distributions can be well fit by a single source thermal distribution. Within errors both the temperature and chemical potential are equal to the pion mass. Pion densities of approximately 0.1 fm{sup {minus}3} for each species, or {approximately}0.3 fm{sup {minus}3} overall, are found if thermalization of the pions is assumed. This density corresponds to a hard sphere radius of 4.0 to 4.5 fm, in good agreement with pion and proton interferometry measurements.

This monthly report describes activities performed in support of Cassini fueled-clad production and studies related to the use of {sup 238}PuO{sub 2} in radioisotope power systems carried out for the Office of Special applications of the US Department of Energy (DOE) by Los Alamos National Laboratory (LANL). Most of the activities described are ongoing; the results and conclusions described may change as the work progresses.

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special 9 surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of U.S. Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, U.S. Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks.