This health and safety guide was written to satisfy two objectives: to summarize the toxicity of metals and alloys used in superconductivity for the benefit of those who work with these materials, and to summarize and describes the basic principles of a highly technical field from a health and safety point-of-view for the benefit of health professionals. The guide begins with a profile of the superconductivity industry, including a list of current and potential applications, a literature review of the market potential, and summary of the current industry status. The body of the paper provides a toxicity and hazard summary for 50 metals, alloys and metal oxides used in superconductivity. The toxicity and hazard summary for all 50 compounds includes: occupational exposure limits, explosiveness and flammability potential, LD{sub 50}'s, chemical and physical properties, incompatibilities and reactivities, recommended personal protective equipment, symptoms of acute and chronic exposure, target organs and toxic effects, and steps for emergency first aid. Finally, a discussion of general occupational hygiene principles is provided, with emphasis on how these principles apply to the unique field of superconductivity. 41 refs.

Accelerator Physics issues, such as the dynamical aperture, the beam lifetime and the current--intensity limitation are carefully studied for the Relativistic Heavy Ion Collider at Brookhaven National Laboratory. The single layer superconducting magnets, of 8 cm coil inner diameter, satisfying the beam stability requirements have also been successfully tested. The proposal has generated wide spread interest in the particle and nuclear physics. 1 ref., 4 figs., 3 tabs.

This paper describes the validation, in accordance with ANSI/ANS-8.1-1983(R1988), of KENO V.a using the 27-group ENDF/B-IV cross section library for some neutronic systems containing highly-enriched uranium, carbon, and hydrogen. This constituent combination is present in many packaging applications for the safe transportation of fissile and fissionable materials. The validation has been performed for two separate computational platforms: an IBM 3090 mainframe and an HP 9000 Series 700 workstation, both using the Oak Ridge Y-12 Plant Nuclear Criticality Safety Software (NCSS) code package. Critical experiments performed at the Oak Ridge Critical Experiments Facility in support of the Rover reactor program were identified as having the constitutents desired for this validation as well as sufficient experimental detail to allow accurate construction of KENO V.a calculational models. Calculated values of k{sub eff} for the Rover experiments, which contain uranium, carbon, and hydrogen, are between 1.0012 {+-} 0.0026 and 1.0245 {+-} 0.0023. These experiments can now be added to KENO V.a and other computer code critical experiment data bases which are used for validation and to establish upper limits on calculated values of k{sub eff} for specific applications.

The technical work during this reporting term has principally involved the continued development, optimization and improvement of freezing drying techniques for solid ceramic oxide electrolyte powder preparation, preliminary optimization of the calcining of the ceramic electrolyte freeze dried powders to allow for optimum processing to the IGR composite, and determining (initial) electrochemical properties of the stabilized ceramic solid electrolyte at a variety of temperatures in air.

The interparticle repulsion, or space charge, limits the density of charged-particle beams that can be obtained in storage rings. In this report the authors study the effect of increasing the space charge, with an exact computation of the lattice parameters using SYNCH. Systematically increasing the ion density by decreasing the emittance with cooling techniques lowers the betatron tune, until the lower half-integral stopband resonance -- also induced by the beam -- is reached. In the simple model described in the report, the amount of ``cooling`` is limited by the encountered stopband of the lattice. Therefore, machines with a higher tune and larger periodicity are better suited to store beams with high space charge.

This report covers work completed during the sixth quarter for the project. The project consists of three tasks: the first relates to developing a database of waste volumes and disposal methods used by the industry; the second and third tasks are aimed at investigating technologies that could be used for the treatment of produced waters and developing cost estimates for those technologies. The remainder of this report describes progress related to the three tasks in the project. Overall, construction of the Production Environmental Database (PED) is ongoing. While much of the data has been collected and entered into the database, a few data categories are still missing, for example, soils and geology and geohydrology. Work is currently under way to collect these data. In addition, a detailed data analysis has begun in order to develop relationships between oil and gas activities and environmental characteristics. In terms of the treatment of produced water, much of the work in the past quarter was focused on analyzing the costs associated with the treatment and disposal of waste residuals such as sludges.

The Interactive, Computer-Enhanced, Remote Viewing System (ICERVS) is a system designed to provide a reliable geometric description of a robotic task space in a fashion that enables robotic remediation to be carried out more efficiently and economically that with present systems. The key elements are a faithful way to store empirical data and a friendly user interface that provides an operator with timely access to all that is known about a scene. ICERVS will help an operator to analyze a scene and generate additional geometric data for automating significant portions of the remediation activity. Features that enable this include the following: Storage and display of empirical sensor data; Ability to update segments of the geometric description of the task space; Side-by-side comparisons of a live TV scene and a computer generated view of the same scene; Ability to create and display computer models of perceived objects in the task space, together with textural comments; and Easy export of data to robotic world models for robot guidance.

Assignment of the vibrational modes Of Os{sub 2}(CO){sub 8}(CHCH{sub 3}) and Os(CO){sub 4}(C{sub 2}H{sub 4)} has given fingerprint vibrational spectra for the following species when chemisorbed on metal catalyst surfaces: ethylidene and ethylene bound in a metallacyclopropane mode. The formation and fragmentation of diosmacyclobutanes have been shown to involve slippage of the outgoing olefin onto a single osmium, and associative exchange of the olefin from that site. The incorporation of vinylcyclopropane without rearrangement has confirmed the absence of a diradical intermediate. The anomalous stability of the diosmacyclobutane derived from trans-2-butene has proven due to greater destabilization (by the substituent methyls) of the slipped intermediate than of the ground state. Reaction of an osmacyclobutane with 1,3- or 1,2-dienes (allenes) gives 1,2 rather than 1,4 addition to the diosmium unit. Treatment of Os(CO){sub 4}(C{sub 2}H{sub 4}) with triflic acid results in the formation of Os(CO){sub 4}(C{sub 2}H{sub 5})OTf. The authors have found that the reaction of an aryl iodine(III) reagent with propargyl stannanes or silanes results in o-iodo propargyl arenes.

The Spent Nuclear Fuel (SNF) Project Engineering Support group cold-tested the Eductor System a 15 horsepower multi-stage centrifugal pump manufactured by the Grunfos Corporation with the housing manufactured and sold with the pump by the Tri-Nuclear Corporation and a 3-inch diameter water jet eductor manufactured by the Fox Valve Corporation. The Eductor System was tested to gather and document information to optimize sludge retrieval operations for use in the 105 K Basins. The cold-testing took place during February 12 through February 29, 1996 in the 305 Cold Test Facility basin located in the 300 area. The pump, utilized in conjunction with the eductor, makes up the core of the Eductor System. The pumping unit consists of a 15 hp stainless steel multi-stage centrifugal Grunfos pump which is seated in a stainless steel fabricated housing. Two baskets or filter elements make up part of the housing on the suction side of the pump. The pump can be used independent of the housing but the housing has two identified purposes. The first use is to stabilize the centrifugal pump and give the pneumatic valves and pump discharge piping a solid platform so the Eductor System can be more easily mobilized within the …

This is the final sample analysis report for tank 241-BX-104 (BX-104), cores 126 and 127. Two segments from each core yielded a total of 11 samples which were analyzed. The data quality objectives (DQOs) applicable to this sampling event were the Safety Screening DQO (Dukelow et al. 1995) and the Organic Safety DQO (Turner et al. 1995). The samples were received, extruded and analyzed at PNNL 325 Analytical Chemistry Laboratory (ACL). The analyses were performed in accordance with the Sample Analysis Plan (Gretsinger 1996) and indicated that the tank is safe with respect to the criteria in the Safety Screening and Organic DQO. Detailed analytical results were described in the analytical laboratory 45-day Report (Attachment 1, WHC-SD-WM-DP-171, REV. 0) and final report (Attachment 2, PNL-BX-104 REV.1) prepared by PNNL, 325 Laboratory. Corrections and/or exceptions to the PNNL final report are provided.

The technical work during this reporting term has principally involved the continued development, optimization and improvement of freezing drying techniques for solid ceramic oxide electrolyte powder preparation, preliminary optimization of the calcining of the ceramic electrolyte freeze dried powders to allow for optimum processing to the IGR composite, and determining (initial) electrochemical properties of the stabilized ceramic solid electrolyte at a variety of temperatures in air.

This document reviews some recent work on physics simulations for SSC/LHC. Included are reviews of some of the recent developments in physics simulations for the SSC/LHC and comments upon the requirements that are placed upon detectors by the need to extract specific physics signatures. The material in the various EOI/LOI documents submitted to the SCC Laboratory and the work done at the Aachen LHC workshop are discussed. In the following discussion 1 SSC (LHC) year corresponds to an integrated luminosity of 10 (100) fb{sup {minus}1}. 41 refs., 14 figs.

During the accelerator studies period of 12/90-1/91 efforts were made to improve the efficiency of crossing transition in the Accumulator. E760 wishes to measure the product of the branching ratios for {bar p}p {yields} {eta}{sub c} {yields} {gamma}{gamma} and the mass and width of the {eta}{sub c}. Since resonance production of the {eta}{sub c} requires a beam momentum of 3.67 Gev/c which is below the Accumulator design transition momentum, and since the above process is rare, it is required to cross transition efficiently (> 90%) with 30 mA of beam. In the past, transition crossing efficiency has been intensity-dependent, with never more than 10 mA getting through transition. At 8 mA or less, transition crossing efficiency was typically 100%. The beam loss is due to a large longitudinal beam blow-up which has been observed many times during transition crossing.

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All models of lasing action require knowledge of the physical parameters involved, of which many can be measured or estimated. The value of the terminal level lifetime is an important parameter in modeling many high power laser systems since the terminal level lifetime can have a substantial impact on the extraction efficiency of the system. However, the values of the terminal level lifetimes for a number of important laser materials such as ND:YAG and ND:YLF are not well known. The terminal level lifetime, a measure of the time it takes for the population to drain out of the terminal (lower) lasing level, has values that can range from picoseconds to microseconds depending on the host medium, thus making it difficult to construct one definitive experiment for all materials. Until recently, many of the direct measurements of the terminal level lifetime employed complex energy extraction or gain recovery methods coupled with a numerical model which often resulted in large uncertainties in the measured lifetimes. In this report we demonstrate a novel and more accurate approach which employs a pump-probe technique to measure the terminal level lifetime of 16 neodymium-doped materials. An alternative yet indirect method, which is based on the ``Energy …

Research is presently being conducted to develop a criteria for selecting weld overlay coatings for erosion mitigation in Circulated Fluidized Beds. During the last two quarters tensile tests were performed at 400{degrees}C for the Ultimet, Inconel-625, 316L SS, C-22, and Stellite-6 wrought alloys. Also, the erosion tests for these materials at 400{degrees}C were completed. The results of mechanical and erosion tests are used to correlate mechanical properties of selected wrought alloys such as tensile toughness, ductility, strain hardening coefficient and yield strength to their erosion resistance at 400{degrees}C. Preliminary results of correlations between erosion resistance of wrought alloys at 400{degrees}C and their mechanical properties are presented in this progress report.

The purpose of this document is to provide the general strategy for resolution of the flammable gas safety issue; it is not a detailed description of program activities. budgets and schedules. Details of the program activities have been issued (Johnson and Sherwood, 1994) and the information pertaining to budgets is provided in the FY 1995-1997 Multi-Year Work Plan for Tank Waste Remediation System (TWRS) (Program Element 1.1.1.2.02.). The key element in this strategy is to provide an understanding of the behavior of each of the Flammable Gas Watch List tanks. While a review of historical information does provide some insight, it is necessary to gather current information about the gases, behavior and nature of the waste,. and about the control systems that maintain and monitor the waste. Analysis of this information will enable TWRS to determine the best approach to place any tank in a safe condition, if it is found to be in an unsafe state.

OAK-B135 Annual report Rockwell International Hot Laboratory decommissioning GFY 1993

Magnesium-aluminate spinel (MAS) and yttria-stabilized zirconia (YSZ) are being considered for use as ceramic matrices in proliferation resistant fuels and radioactive storage systems, and may be used either as individual entities or as constituents in multicomponent ceramic systems. It is worthwhile, therefore, to compare radiation damage in these two potentially important materials when subjected to similar irradiation conditions, e.g., ion beam irradiation. To compare radiation damage properties of these two materials, single crystals of spinel and zirconia were irradiated with 340 keV Xe{sup ++} ions at 120 K, and subsequently investigated by Rutherford backscattering and ion channeling (RBS/C), and optical absorption spectroscopy. Results indicate that damage accumulation in both spinel and zirconia follow a three stage process: (1) very slow damage accumulation over a wide range of dose; (2) rapid changes in damage over a range of doses from about 0.25 to 25 displacements per atom (DPA); (3) slower damage accumulation at very high doses and possibly saturation. Optical absorption results indicate that F-centers form in Xe ion-irradiated spinel and that the concentration of these centers saturates at high dose. Absorption bands are also formed in both spinel and zirconia that are due to point defect complexes formed upon irradiation. …

Sintering studies of CeO{sub 2} and CeO{sub 2} + 2 wt. % Ga{sub 2}O{sub 3} were completed. Firing temperatures studied were 1250-1650 C with 2 to 4 hour firing soak times in air. Powders fabricated by three methods (as-received, attrition-mill and nitrite-derived) were studied. Attrition-milled CeO{sub 2} improved densities as compared with as-received CeO{sub 2}. Attrition-milled CeO{sub 2} with 2 wt.% Ga{sub 2}O{sub 3} showed decreased densities with increasing temperatures. As-received CeO{sub 2} with 2 wt.% Ga{sub 2}O{sub 3} showed a opposite trend, increasing in density with increased firing temperature. Two pellet preparation methods were studied, a one-step-press method and a two-step-press method. The two-step-press method showed greater densities at lower firing temperatures and times as compared with the one-step-press method, however for CeO{sub 2} + 2 wt.% Ga{sub 2}O{sub 3}, the two methods gave equivalent results at 1650 C, 6 hr. firing conditions.

Metaphorically, a teleoperator with master controllers projects the user's arms and hands into a re- mote area, Therefore, human users interact with teleoperators at a more fundamental level than they do with most human-machine systems. Instead of inputting decisions about how the system should func- tion, teleoperator users input the movements they might make if they were truly in the remote area and the remote machine must recreate their trajectories and impedance. This intense human-machine inter- action requires displays and controls more carefully attuned to human motor capabilities than is neces- sary with most systems. It is important for teleoperated manipulators to be able to recreate human trajectories and impedance in real time. One method for assessing manipulator performance is to observe how well a system be- haves while a human user completes human dexterity tasks with it. Fitts' tapping task has been, used many times in the past for this purpose. This report describes such a performance assessment. The International Submarine Engineering (ISE) Autonomous/Teleoperated Operations Manipulator (ATOM) servomanipulator system was evalu- ated using a generic positioning accuracy task. The task is a simple one but has the merits of (1) pro- ducing a performance function estimate rather than a …

The Automated Bar Coding of Air Samples at Hanford (ABCASH) system provides an integrated data collection, sample tracking, and data reporting system for radioactive particulate air filter samples. The ABCASH plotting program provides a graphical trend report for ABCASH of the performance of air sample results. This document provides an operational guide for using the program. Based on sample location identifier and date range, a trend chart of the available data is generated. The trend chart shows radiological activity versus time. General indications of directional trend of the concentrations in air over time may be discerned. Comparison limit set point values are also shown as derived from the ABCASH data base.

Oak Ridge National Laboratory (ORNL) is developing a core DNA sequencing facility to support biological research endeavors at ORNL and to conduct basic sequencing automation research. This facility is novel because its development is based on existing standard biology laboratory equipment; thus, the development process is of interest to the many small laboratories trying to use automation to control costs and increase throughput. Before automation, biology Laboratory personnel purified DNA, completed cycle sequencing, and prepared 96-well sample plates with commercially available hardware designed specifically for each step in the process. Following purification and thermal cycling, an automated sequencing machine was used for the sequencing. A technician handled all movement of the 96-well sample plates between machines. To automate the process, ORNL is adding a CRS Robotics A- 465 arm, ABI 377 sequencing machine, automated centrifuge, automated refrigerator, and possibly an automated SpeedVac. The entire system will be integrated with one central controller that will direct each machine and the robot. The goal of this system is to completely automate the sequencing procedure from bacterial cell samples through ready-to-be-sequenced DNA and ultimately to completed sequence. The system will be flexible and will accommodate different chemistries than existing automated sequencing lines. The …

Lifetime studies in four-point flexure were performed on a Hi-Nicalon^TM fiber-reinforced SiC matrix composite over a temperature range of 700 degrees to 1150 degrees C in air. The composite consisted of ~40 vol. % Hi-Nicalon^TM fiber (8-harness weave) with a 0.5 Mu-m BN fiber coating and a melt-infiltration SiC matrix wand was tested with as-machined surfaces. Lifetime results indicated that the composite exhibited a stress-dependent lifetime at stress levels above an apparent fatigue limit, similar to the trend observed in CG-Nicalon^TM fiber reinforced CVI SiC matrix composites. At less than or equal to 950 degrees C, the lifetimes of Hi-Nicalon/MI SiC composites decreased with increasing applied stress level and test temperature. However, the lifetimes were extended as test temperature increased from 950 degees to 1150 degrees C as a result of surface crack sealing due to glass formation by the oxidation of Mi SiC matrix. The lifetime governing processes were, in general, attributed to the progressive oxidation of BN fiber coating and formation of glassy phase, which formed a strong bond between fiber and matrix, resulting in embrittlement of the composite with time.