In summary, significant bond cleavage was found only for thiophenol under the supercritical conditions studied. Less than 5% yield was found for the observed reaction products for all the other organosulfur compounds. The hydrogen sulfur bond in thiophenol is clearly the weakest of those studied and therefore it is the easiest to rupture. Also a general trend was observed the solvolysis reaction products such as ethylthiobenzene were the products initially formed at lower temperatures. But with higher temperatures the reaction product were those typically produced from the bimolecular association of free-radicals, such as phenylsulfide for the thiophenol sample. This type of reaction would be expected in pyrolysis reactions. Bimolecular reactions between organosulfur compounds would not be expected when the reaction is occurring at the surface of the solid coal matrix. The probability of the extracted organosulfur radicals having such bimolecular reactions is quite low. However, the reactions that are observed from the interaction of supercritical ethanol and the model coal compounds are not ones that show obvious indications of desulfurization of the compound.

We discuss dual-band infrared (DBIR) capabilities for imaging buried object sizes. We identify physical features affecting thermal contrast needed to distinguish buried object sites from undisturbed sites or surface clutter. Apart from atmospheric transmission and system performance, these features include: object size, shape, and burial depth; ambient soil, disturbed soil and object site thermal diffusivity differences; surface temperature, emissivity, plant-cover, slope, albedo and roughness variations; weather conditions and measurement times. We use good instrumentation to measure the time-varying temperature differences between buried object sites and undisturbed soil sites. We compare near surface soil temperature differences with radiometric infrared (IR) surface temperature differences recorded at 4.7 {plus_minus} 0.4 {mu}m and at 10.6 {plus_minus} 1.0 {mu}m. By producing selective DBIR image ratio maps, we distinguish temperature-difference patterns from surface emissivity effects. We discuss temperature differences between buried object sites, filled hole site (without buried objects), cleared (undisturbed) soil sites, and grass-covered sites (with and without different types of surface clutter). We compare temperature, emissivity-ratio, visible and near-IR reflectance signatures of surface objects, leafy plants and sod. We discuss the physical aspects of environmental, surface and buried target features affecting interpretation of buried targets, surface objects and natural backgrounds.

A thermal analysis of the horizontal shipping container (HSC) was performed to determine the temperatures at the outer surface of the inner container during normal conditions of transport with incident solar radiation. There are two methods by which this analysis can be performed: (1) it can be run as a steady-state problem where it is assumed that the incident solar radiation is applied to the package 24 hours per day, or (2) it can be run as a cyclic transient problem where the incident solar radiation is applied for 12 hours per day and the other 12 hours there is assumed to be no incident solar radiation. The steady-state method was initially attempted, but the temperatures determined from this analysis were judged to be significantly higher than one would find in the cyclic case. Thus, it was deemed necessary to perform a transient analysis to determine a more realistic temperature distribution within the HSC during normal conditions of transport. The heat transfer code HEATING 7.1 was used to perform these calculations. HEATING 7.1 is a heat conduction code capable of handling radiation, convection (forced and natural), and heat flux boundary conditions. Heat generation within a material is also possible with …

During the first quarter of the above contract, all the elements of Task 1 were completed. The first quarterly report presented an overview of a wetland and its increasing use in industrial wastewater treatment. An idealized, reaction engineering description of wetlands was presented to demonstrate how the various processes that occur in a wetland can be modeled. Previous work on the use of wetlands to remove BOD, TSS, Phosphorus and Nitrogen was reviewed. Recent literature on the application of wetland technology to the treatment of petroleum-related wastewater was critically evaluated and an outline of the research plans for the first year was delineated. Further, our literature search (nominally completed under Task 1) unearthed more recent studies (some unpublished) and a summary was included in the second quarterly report. In the second quarterly report, results of our efforts on the construction of a laboratory-type wetland were also reported. Initial studies on the use of wetland amendments such as modified-clays and algae cells were presented and discussed. Adsorption of heavy metal ions, Cu{sup 2+} and Cr(VI) onto soils drawn from the laboratory-type wetland built as a part of this contract has been undertaken and these results are presented and discussed in this …

In summary, significant bond cleavage was found only for thiophenol under the supercritical conditions studied. Less than 5% yield was found for the observed reaction products for all the other organosulfur compounds. The hydrogen sulfur bond in thiophenol is clearly the weakest of those studied and therefore it is the easiest to rupture. Also a general trend was observed the solvolysis reaction products such as ethylthiobenzene were the products initially formed at lower temperatures. But with higher temperatures the reaction product were those typically produced from the bimolecular association of free-radicals, such as phenylsulfide for the thiophenol sample. This type of reaction would be expected in pyrolysis reactions. Bimolecular reactions between organosulfur compounds would not be expected when the reaction is occurring at the surface of the solid coal matrix. The probability of the extracted organosulfur radicals having such bimolecular reactions is quite low. However, the reactions that are observed from the interaction of supercritical ethanol and the model coal compounds are not ones that show obvious indications of desulfurization of the compound.

This invention is comprised of a process of preparing an actinide compound of the formula An{sub x}Z{sub y} wherein An is an actinide metal atom selected from the group consisting of thorium, uranium, plutonium, neptunium, and americium, x is selected from the group consisting of one, two or three, Z is a main group element atom selected from the group consisting of nitrogen, phosphorus, oxygen and sulfur and y is selected from the group consisting of one, two, three or four, by admixing an actinide organometallic precursor wherein said actinide is selected from the group consisting of thorium, uranium, plutonium, neptunium, and americium, a suitable solvent and a protic Lewis base selected from the group consisting of ammonia, phosphine, hydrogen sulfide and water, at temperatures and for time sufficient to form an intermediate actinide complex, heating said intermediate actinide complex at temperatures and for time sufficient to form the actinide compound, and a process of depositing a thin film of such an actinide compound, e.g., uranium mononitride, by subliming an actinide organometallic precursor, e.g., a uranium amide precursor, in the presence of an effective amount of a protic Lewis base, e.g., ammonia, within a reactor at temperatures and for time …

Three-axis particle impact probes detect particle impact vectors along x-, y-, and z-axes by means of a head mounted on the outer end of a shaft that is flexibly mounted in silicone rubber at the top of a housing so as to enable motion imparted to the head upon impact to be transmitted to a grounded electrode secured to the shaft within the housing. Excitable electrodes are mounted in the housing in a fixed position, spaced apart from the ground electrode and forming, with the ground electrode, capacitor pairs. Movement of the ground electrode results in changes in capacitance, and these differences in capacitance are used for measurement or derivation of momentum vectors along each of the three axes. In one embodiment, the ground electrode is mounted at the base of the shaft and is secured to a silicone rubber layer at the top of the housing, providing for cantilevered movement. In another embodiment, the shaft is mounted at its mid point in a flexible bushing so that it undergoes pivotal movement around that point.

This report is a letter about a review of the ``Quality Assurance Project Plan for the INEL Waste Isolation Pilot Plant Waste Characterization Project.`` The author of the letter recommended the approval of the quality assurance program. However in his review, several observations were made and were requested to be added to the program. Examples of these observations were safety of personnel involved in the program, safe characterization of hazardous materials studied, quality of calibrations required for measurement objectives, and reporting of hazardous sampling. (MB)

Weekly newsletter discussing natural resources, parks, hunting and fishing, and other information related to the outdoors in Texas.

Rock varnish is a microns-thick manganese- and iron-rich coating that forms on exposed rock surfaces in arid and semi-arid environments. Empirical correlations of the varnish cation ratio (K+Ca)/Ti with age have been used to estimate ages of geomorphic surfaces, with varnish chemistry generally acquired by either proton-induced x-ray emission (PIXE) analysis of natural varnish surfaces. Chemical analyses of rock varnish with SEM/EDX utilize a sequence of accelerating voltages to vary penetration depths into the sample. Using elemental x-ray maps of natural varnish surfaces with SEM/EDX, penetration into the substrate can be recognized at accelerating voltages where contamination with substrate is inferred from SEM/EDX chemical analyses. This demonstrates the ability of the SEM method to obtain varnish chemistry with minimal inclusion of substrate. Calculations of theoretical x-ray depth-distribution ({phi}({rho}z)) curves in varnish indicate that at an accelerating voltage of 10 kV most of the emitted electrons are generated in the upper 0.5 micron of a sample. At a higher voltage of 30 kV most of the signal is still restricted to the upper 2 microns, representing a very small percentage of total varnish volume in many cases. The ability of the SEM method to obtain empirical correlations of the chemistry of …

This talk deals with the investigation of secondary interactions in proton-nucleus and nucleus-nucleus collisions using the Monte Carlo event generator HIJET.

Atomic hydrogen inside solid H{sub 2} increases the energy density by 200 MegaJoules/m{sup 3}, for each percent mole fraction stored. How many atoms can be stored in solid hydrogen To answer this, we need to know: (1) how to produce and trap hydrogen atoms in solid hydrogen, (2) how to keep the atoms from recombining into the ground molecular state, and (3) how to measure the atom density in solid hydrogen. Each of these topics will be addressed in this paper. Hydrogen atoms can be trapped in solid hydrogen by co-condensing atoms and molecules, external irradiation of solid H{sub 2}, or introducing a radioactive impurity inside the hydrogen lattice. Tritium, a heavy isotope of hydrogen, is easily condensed as a radioactive isotopic impurity in solid H{sub 2}. Although tritium will probably not be used in future rockets, it provides a way of applying a large, homogenious dose to solid hydrogen. In all of the data presented here, the atoms are produced by the decay of tritium and thus knowing how many atoms are produced from the tritium decay in the solid phase is important. 6 refs., 6 figs.

The authors are investigating mechanisms of energy storage and release in tritiated solid hydrogens, by a variety of techniques including ESR, NMR and thermal and optical emission. The nuclear decay of a triton in solid hydrogen initiates the conversion of nuclear energy into stored chemical energy by producing unpaired hydrogen atoms which are trapped within the molecular lattice. The ability to store large quantities of atoms in this manner has been demonstrated and can serve as a basis for new forms of high energy density materials. This paper presents preliminary results of a study of the optical emission from solid hydrogen containing tritium over the visible and near infrared (NIR) spectral regions. Specifically, they have studied optical emission from DT and T{sub 2} using CCD, silicon diode and germanium diode arrays. 8 refs., 6 figs.

This report is a letter about a review of the Quality Assurance Project Plan for the INEL Waste Isolation Pilot Plant Waste Characterization Project.'' The author of the letter recommended the approval of the quality assurance program. However in his review, several observations were made and were requested to be added to the program. Examples of these observations were safety of personnel involved in the program, safe characterization of hazardous materials studied, quality of calibrations required for measurement objectives, and reporting of hazardous sampling. (MB)

None

This report consists of two parts. Part 1 describes the development of novel analytical methods needed to predict the BOM performance and the subsequent performance degradation of the mutually obstructed RTGs for the CRAF and Cassini missions. Part II applies those methods to the two missions, presents the resultant predictions, and discusses their programmatic implications.; The results indicate that JPL's original power demand goals could have been met with two standard GPHS RTGs for each mission. However, JPL subsequently raised both the power demand profile and the duration for both missions, to the point where two standard RTGs could no longer provide the desired power margin. Each mission can be satisfied by adding a third RTG, and in the case of the Cassini mission the use of three RTGs appears to be unavoidable. In the case of the CRAF mission, there appears to be a possibility that modest modifications of the RTGs' design and/or operating scheme and meet the missions' power demand without the addition of a third RTG. The potential saving in cost and schedule pressure prompted Fairchild to undertake a study of various obvious and not-so-obvious stratagems, either singly or in combination, to determine whether they would make …

This report consists of two parts. Part 1 describes the development of novel analytical methods needed to predict the BOM performance and the subsequent performance degradation of the mutually obstructed RTGs for the CRAF and Cassini missions. Part II applies those methods to the two missions, presents the resultant predictions, and discusses their programmatic implications. The results indicate that JPL's original power demand goals could have been met with two standard GPHS RTGs for each mission. However, JPL subsequently raised both the power demand profile and the duration for both missions, to the point where two standard RTGs could no longer provide the desired power margin. Each mission can be satisfied by adding a third RTG, and in the case of the Cassini mission the use of three RTGs appears to be unavoidable. In the case of the CRAF mission, there appears to be a possibility that modest modifications of the RTGs' design and/or operating scheme and meet the missions' power demand without the addition of a third RTG. The potential saving in cost and schedule pressure prompted Fairchild to undertake a study of various obvious and not-so-obvious stratagems, either singly or in combination, to determine whether they would make …

None

None

This report documents the characterization of the latest batch of shells produced in the Ballistic Furnace System at the Lebedev Physical Institute, Moscow, Russia, that we received in mid-February, 1999. The batch consisted of three cassettes containing 36 shells in each cassette. An initial sphericity measurement was done, each shell was weighed, and shells were selected that were spherical enough to run on the Sphere Mapper AFM.

The goal of this project was to develop, through experiments and modeling, a better understanding of the physics issues and machining techniques related to short-pulse laser materials processing. Although we have successfully demonstrated many types of cuts in a wide range of materials, our general short-pulse machiing scientific knowledge and our ability to model the complex physical processes involved are limited. During this past year we made good progress in addressing some of these issues, but there remain many unanswered questions. Section 2 begins with a theoretical look at short-pulse laser ablation of material using a 1-D radiation-hydrodynamic code which includes a self-consistent description of laser absorption and reflection from an expanding plasma. In Section 3 we present measurements of scaling relationships, hole drilling progression, electric field and polarization effects, and a detailed look at the interesting structures formed during hole drilling of metals under various conditions. Section 4 describes the consequences of the presence of a prepulse before the main drilling pulse. In Section 5 we take a brief look at the plasma plume: how it can be useful, and how we can avoid it. Finally, Section 6 contains a couple of examples of machining non-metals. The laser system …

Periodical titled "Texas Looks to Grandfathered Facilities For Air Quality Improvements" that discusses air quality issues and regulations on emissions at the state and federal levels.

This work plan is prepared for the 716-A Motor Shops Seepage Basin, which is located in the A-Area at the Savannah River Site in Aiken, South Carolina.

Griffith Energy Limited Liability Corporation (Griffith) proposes to construct and operate the Griffith Energy Project (Project), a natural gas-fuel, combined cycle power plant, on private lands south of Kingman, Ariz. The Project would be a ''merchant plant'' which means that it is not owned by a utility and there is currently no long-term commitment or obligation by any utility to purchase the capacity and energy generated by the power plant. Griffith applied to interconnect its proposed power plant with the Western Area Power Administration's (Western) Pacific Northwest-Pacific Southwest Intertie and Parker-Davis transmission systems. Western, as a major transmission system owner, needs to provide access to its transmission system when it is requested by an eligible organization per existing policies, regulations and laws. The proposed interconnection would integrate the power generated by the Project into the regional transmission grid and would allow Griffith to supply its power to the competitive electric wholesale market. Based on the application, Western's proposed action is to enter into an interconnection and construction agreement with Griffith for the requested interconnections. The proposed action includes the power plant, water wells and transmission line, natural gas pipelines, new electrical transmission lines and a substation, upgrade of an existing …