MOLECULAR DESIGN OF COLLOIDS IN SUPERCRITICAL FLUIDS (open access)

MOLECULAR DESIGN OF COLLOIDS IN SUPERCRITICAL FLUIDS

The environmentally benign, non-toxic, non-flammable fluids water and carbon dioxide (CO2) are the two most abundant and inexpensive solvents on earth. Emulsions of these fluids are of interest in many industrial processes, as well as CO2 sequestration and enhanced oil recovery. Until recently, formation of these emulsions required stabilization with fluorinated surfactants, which are expensive and often not environmentally friendly. In this work we overcame this severe limitation by developing a fundamental understanding of the properties of surfactants the CO2-water interface and using this knowledge to design and characterize emulsions stabilized with either hydrocarbon-based surfactants or nanoparticle stabilizers. We also discovered a new concept of electrostatic stabilization for CO2-based emulsions and colloids. Finally, we were able to translate our earlier work on the synthesis of silicon and germanium nanocrystals and nanowires from high temperatures and pressures to lower temperatures and ambient pressure to make the chemistry much more accessible.
Date: April 6, 2009
Creator: Johnston, Keith P.
Object Type: Report
System: The UNT Digital Library
Thermodynamics of Neptunium (V) Complexes with Phosphate at Elevated Temperatures (open access)

Thermodynamics of Neptunium (V) Complexes with Phosphate at Elevated Temperatures

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Date: April 6, 2009
Creator: Xia, Yuanxian; Friese, Judah I.; Bachelor, Paula P.; Moore, Dean A. & Rao, Linfeng
Object Type: Article
System: The UNT Digital Library
Reversibility Aspect of Metal Borohydrides (open access)

Reversibility Aspect of Metal Borohydrides

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Date: April 6, 2009
Creator: Au, M. & Tom Walters, T.
Object Type: Article
System: The UNT Digital Library
Scalable Systems Software Enabling Technology Center (open access)

Scalable Systems Software Enabling Technology Center

NCSA’s role in the SCIDAC Scalable Systems Software (SSS) project was to develop interfaces and communication mechanisms for systems monitoring, and to implement a prototype demonstrating those standards. The Scalable Systems Monitoring component of the SSS suite was designed to provide a large volume of both static and dynamic systems data to the components within the SSS infrastructure as well as external data consumers.
Date: April 6, 2009
Creator: Showerman, Michael T.
Object Type: Report
System: The UNT Digital Library
Country Report on Building Energy Codes in Canada (open access)

Country Report on Building Energy Codes in Canada

This report is part of a series of reports on building energy efficiency codes in countries associated with the Asian Pacific Partnership (APP) - Australia, South Korea, Japan, China, India, and the United States of America . This reports gives an overview of the development of building energy codes in Canada, including national energy policies related to building energy codes, history of building energy codes, recent national projects and activities to promote building energy codes. The report also provides a review of current building energy codes (such as building envelope, HVAC, lighting, and water heating) for commercial and residential buildings in Canada.
Date: April 6, 2009
Creator: Shui, Bin & Evans, Meredydd
Object Type: Report
System: The UNT Digital Library
Critical issues in the formation of quantum computer test structures by ion implantation (open access)

Critical issues in the formation of quantum computer test structures by ion implantation

The formation of quantum computer test structures in silicon by ion implantation enables the characterization of spin readout mechanisms with ensembles of dopant atoms and the development of single atom devices. We briefly review recent results in the characterization of spin dependent transport and single ion doping and then discuss the diffusion and segregation behaviour of phosphorus, antimony and bismuth ions from low fluence, low energy implantations as characterized through depth profiling by secondary ion mass spectrometry (SIMS). Both phosphorus and bismuth are found to segregate to the SiO2/Si interface during activation anneals, while antimony diffusion is found to be minimal. An effect of the ion charge state on the range of antimony ions, 121Sb25+, in SiO2/Si is also discussed.
Date: April 6, 2009
Creator: Schenkel, T.; Lo, C. C.; Weis, C. D.; Schuh, A.; Persaud, A. & Bokor, J.
Object Type: Article
System: The UNT Digital Library