Efforts at the Jet Propulsion Laboratory toward the production of pure polycrystaline silicon are centered on the concept of silicon particle growth in a fluidized bed reactor (FBR) and a continuous flow pyrolyzer (CFP). The CFP possibly can provide the seed particles which will be grown to larger sizes in the FBR. In both the reactors polycrystalline silicon is obtaned from the pyrolysis of silane. A part of the JPL effort is to develop a model of silicon particle growth for the purpose of predicting particle growth rates and product particle size distributions in the FBR and the CFP. This repot describes the mathematical models of silicon particle growth in the FBR and the CFP.

This report is the first in a series and details the results accomplished under the following tasks: (1) evaluation of existing passive solar calculation methods, (2) BLAST/DOE-1 program interface and comparison with BR-202, and (3) development of analytic relationships between the thermal balance and weighting factor techniques. The various methods available for use in thermal load analysis are presented with detailed informaton on algorithms used in the thermal balance and weighting factor techniques. (MOW)

A computer-assisted thermochemical equilibrium analysis was conducted for the silicon transport reaction: Si(s) + SiF/sub 4/(g) = (intermediates) = Si(s) + SiF/sub 4/(g). The calculations indicated that a substantial transport rate should be possible at temperatures of 1700/sup 0/K and one atmosphere pressure. Computations were made to determine whether the elemental impurities present in metallurgical-grade silicon would transfer in this process. It was concluded that aluminum, chromium, copper, iron, manganese, molybdenum, nickel, vanadium, and zirconium would not transfer, but that boron, magnesium, phosphorus, and titanium would transfer.

The impacts described here for 1985 and 1990 are based on a national energy projection which assumes medium energy demand and fuel supply through 1990 but does not incorporate the policies of the National Energy Act (NEA). This scenario, referred to as the Projection Series C or the TRENDLONG MID-MID scenario, is one of six possible energy futures developed by the DOE Energy Information Administration for the Department's 1977 Annual Report to Congress. It was chosen as representative of the official DOE national energy projections when this project was initiated, prior to the passage of the National Energy Act. Since the RIIA program is part of an ongoing review of the regional impact of energy policies, the next phase will examine the National Energy Act (NEA) and initiatives suggested by the President's second National Energy Plan. However, since coal utilization increases under the NEA, in general, impacts identified in the TRENDLONG Series C Scenario should provide a framework for the discussion of impacts by NEA. The environmental impacts discussed in this volume are for Federal Region I (Maine, Vermont, New Hampshire, Massachusetts, Rhode Island, and Connecticut). However, there are nine companion volumes, one for each of the other Federal Regions.

Thermochemical equilibrium computations for the preparation of silicon (Si) by the reaction between sodium (Na), either liquid or vapor, with silicon tetrafluoride (SiF/sub 4/) and silicon tetrachloride (SiCl/sub 4/) are presented. Computations indicate that SiF/sub 4/ reacts with either liquid or gaseous Na to produce temperatures sufficiently high to form molten Si. Liquid Na reacts with SiF/sub 4/ to produce substantially higher Si yields than does the free combustion reaction with Na vapor; however, the Na vapor/SiF/sub 4/ reaction, if temperature-constrained at the Si melting point, produces an expected Si yield close to 100%. A stoichiometric mixture of liquid Na and SiCl/sub 4/ vapor reacts to produce liquid Si, gaseous sodium chloride (NaCl), and a small concentration of Si subhalides. Gaseous Na, however, reacts with SiCl/sub 4/ to form entirely gaseous reaction products and a high yield of Si (liquid) but subhalide concentrations are greater than when liquid Na is used. The reactions of a number of impurity elements in Na, during the course of the Na-Si halide reaction, have been described. Of those considered, only calcium (Ca), magnesium (Mg), phosphorus (P), and strontium (Sr) are expected to co-exist to any extent in Na vapor and none is expected to …

The structure and electrical activity of planar defects in EFG Silicon was investigated by optical, electron beam induced current (EBIC), and transmission electron microscopy (TEM). What appears to be twin boundaries by both optical microscopy + etching, and by EBIC are in reality systems of microtwins, some of which are only a few atomic lattice planes thick. The electrical activity of planar defects appears to be correlated with emission of dislocations especially at termination points. Impurity effects may also play a role. Twin boundaries per se appear not to be electricaly active.

A method is described whereby the absolute radiative quantum efficiency of paramagnetic ions in liquids or solids can be determined from photoacoustic measurements. 1 figure.

This report presents the results of a reconnaissance geochemical survey of the Joplin quadrangle, Kansas/Missouri. Field laboratory data is provided for 736 groundwater and 714 stream sediment samples.

Livermore results are reviewed and compared with recent measurements of high energy ions in the plasma focus device at other laboratories. We will also discuss diagnostic techniques for measuring high energy ions including nuclear activation, particle track detectors, solid state (silicon PIN) detectors, and neutron time-of-flight measurements.

The theory for photoacoustic-induced stress in condensed media is developed both for near-field and far-field conditions.

Attenuation results from geometric spreading and from absorption. The former is almost independent of crustal geology or physiographic region. The latter depends strongly on crustal geology and the state of the earth's upper mantle. Except for very high-frequency waves, absorption does not affect ground motion at distances less than 25 to 50 km. Thus, in the near-field zone, the attenuation in the eastern United States will be similar to that in the western United States. Most of the differences in ground motion can be accounted for by differences in attenuation caused by differences in absorption. The other important factor is that for some Western earthquakes the fault breaks the earth's surface, resulting in larger ground motion. No Eastern earthquakes are known to have broken the earth's surface by faulting. The stress drop of Eastern earthquakes may be higher than for Western earthquakes of the same seismic moment, which would affect the high-frequency spectral content. This factor is believed to be of much less significance than differences in absorption in explaining the differences in ground motion between the East and the West. 6 figures.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

FORTRAN-callable subroutines have been written to enable controller--controllee interaction on the LLL DECsystem-10. These subroutines have been used to construct a controller (XTCTMR) for a tandem-mirror physics code (CTCTMR). A description of the subroutines and their use is presented. Also, sample results are given.

Work has progressed along two lines: obtaining of detailed occupation, industry, wage, and skill information; and obtaining of detailed materials and labor requirements (so-called direct requirements) for conservation and solar options. The latter is currently focused upon thermally tight single-family residences (vs. as-built). Both of these inputs will be used in conjunction with our input-output employment-energy model.

Laboratory experiments were performed to evaluate methods for removing plutonium from insulation, glass leach heel, and sand and slag heel. The methods evaluated included hydrochloric acid leaching, nitric acid leaching, and a treatment consisting of a fusion step followed by acid leaching. Results indicate that a nitric acid leach is effective in lowering the plutonium concentration of these solid wastes to the desired limit, if multiple contacts are used. A hydrochloric acid leach was found to be superior to a nitric acid leach for removing plutonium from the residues.

Weekly report of the Texas Crop and Livestock Reporting Service on turkey poult numbers in Texas and compared with other states. It includes compiled statistics across six consecutive weeks, from the week ending March 10 to the week ending April 7, during 1987 and 1979 for turkey eggs set and poults hatched.

We have successfully developed a new process for making strong, smooth, thick SiO/sub 2/ films on hemispherical Kovar mandrels of various sizes designed for multishell Laser Fusion Targets. The surface finish obtainable with a 13 ..mu..m thick SiO/sub 3/ coating on a 260 ..mu..m dia. mandrel is approximately 30 nm peak-to-peak, with a few defects of roughly 0.3 ..mu..m deep. The rf magnetron sputtered SiO/sub 2/ films were dense and crystalline.

The computer languages available for the systems and application implementation on the Supervisory Control and Diagnostics System (SCDS) for the Mirror Fusion Test Facility (MFTF) were surveyed and evaluated. Four language processors, CAL (Common Assembly Language), Extended FORTRAN, CORAL 66, and Sequential Pascal (SPASCAL, a subset of Concurrent Pascal (CPASCAL)) are commercially available for the Interdata 7/32 and 8/32 computers that constitute the SCDS. Of these, the Sequential Pascal available from Kansas State University appears best for the job in terms of minimizing the implementation time, debugging time, and maintenance time. This improvement in programming productivity is due to the availability of a high-level, block-structured language that includes many compile-time and run-time checks to detect errors. In addition, the advanced data-types in language allow easy description of the program variables. 1 table.

This study was conducted to understand and control the parameters governing the formation of defects in plasma polymerized surfaces. An inductively-coupled discharge was used as the source of activated monomer. Four types of well characterized surface irregularities were produced on glass slides which were subsequently fluorocarbon coated. Optimization of the process variables is discussed. (MOW)

Two components made from LLL stock tantalum sheets have failed to operate as designed under high-explosive loading. The as-fabricated metallurgical state of the tantalum was suspected as one possible cause. To investigate this possibility, the microstructure, hardness, and chemical composition of the component material was evaluated. Both as-received tantalum starting sheets and a formed component were evaluated. The evaluation showed that these components were given an anneal that relieved stresses but did not recrystallize the material. The components were thus stronger than necessary. A recrystallization anneal would further lower both the hardness and the yield stress. Nevertheless, the current metallurgical state of the components should have been adequate to serve the design function.

Studies of technical issues relating to nuclear waste management are described. It supplements previous TASC reports on this topic. Volume 1 addresses events occurring before emplacement of the waste in a repository. The subjects addressed are thermal analysis of interim storage accidents and doses to the worst-situated individual in all types of pre-emplacement accidents. Volume 2 deals with the possible release of waste from a geologic repository. Aspects of long-term repository performance which are discussed include water flow around shafts and boreholes and use of water from contaminated wells. New methods and results pertaining to the analysis of uncertainties in long-term risk predictions are also presented.

This report reviews results from early electron-beam heating experiments and more recent basic beam-plasma physics experiments as well as present theoretical understanding. We find tha rather simple electron-beams could be employed on the Tandem Mirror Experiment (TMX) at Lawrence Livermore Laboratory to carry out electron heating experiments.

The work to be performed by The Aerospace Corporation for the DOE/TEC is confined to the following basic task areas: (1) technical support of ongoing research and development programs in energy efficient transportation systems; (2) analysis for the future commercialization of transportation technologies; (3) new concept evaluation program support; (4) technical evaluation of new concepts, inventions, and ideas; (5) assessment of technological and other factors on the implementation and utilization of transportation in the United States; and (6) program planning analysis and documentation. The status of achieved progress through the period ending March 31, 1979, is presented, and the expenditure status is summarized. (WHK)

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.