The Inference of Adsorption from Differential Double Layer Capacitance Measurements (open access)

The Inference of Adsorption from Differential Double Layer Capacitance Measurements

From Abstract : "Dependence of boundary tension and capacitance at the mercury-aqueous 0.1 N HClO4 interface on polarization and organic solute concentration were determined for the colutes n-amyl alcohol and phenol. ... An earlier treatment proposed by this Laboratory based on a (non-thermodynamic) assumption of linear variation of surface charge density with coverage appears adequately justified for inference of fractional surface coverages near the electrocapillary maximum, but must be considered approximate for evaluation of molar area at full coverage in cases where linear variation of charge with coverage has not been demonstrated."
Date: April 26, 1963
Creator: Hansen, Robert S.; Kelsh, Dennis J. & Grantham, D. H.
System: The UNT Digital Library
High Purity Calcium (open access)

High Purity Calcium

Technical report. From Introduction : "For more than a century, methods employed in preparing calcium were based largely on electrowinning and the most successful were based on [Sir Humphrey] Davy's process. ... In general, the metal was of adequate quality for the industrial applications of the time, and although by 1940 some strides had been made in the purification of calcium, interests in the better grades of the metal were limited essentially to experimental work of academic concern."
Date: April 3, 1963
Creator: Wilhelm, H. A. & Carlson, O. N.
System: The UNT Digital Library
Design and Test of a Diaphragm Pump for Liquid Metals (open access)

Design and Test of a Diaphragm Pump for Liquid Metals

Technical report. From Abstract : "Details are provided on the construction and operation of a two-stage diaphragm pump successfully used for the first time in liquid metal service. From the results of 5,376 hr. test of the pump it was concluded that it is well suited to the pumping of liquid metals at low flow rates where pulsating flow can be tolerated and also where remote operation is required. Operating temperatures and pressures are limited only by the availability of suitable materials of construction."
Date: April 12, 1963
Creator: Westerheide, D. E. & Clifford, J. C.
System: The UNT Digital Library
Measurement of Thermal Properties by the Arc Image Furnace (open access)

Measurement of Thermal Properties by the Arc Image Furnace

Technical report. From Abstract : "A number of imaging furnace systems and sources are discussed with emphasis on the carbon arc image furnace. Several potential applications of the carbon arc image furnace in high temperature research are described and a new method of heat capacity determination is discussed."
Date: April 16, 1963
Creator: McMahon, W. R. & Wilder, D. R.
System: The UNT Digital Library
gem-Bis(disubstitutedphosphinyl)alkanes. II. Extraction Properties of Bis(di-n-hexlphosphinyl)methane (open access)

gem-Bis(disubstitutedphosphinyl)alkanes. II. Extraction Properties of Bis(di-n-hexlphosphinyl)methane

From abstract: "Bis(di-n-hexylphosphinyl)methane, HDPM, [(C6H13)2P(O)]2CH2, has been studied as an extractant for a variety of metals. HDPM was evaluated as an extractant for uranium(VI) and compared with tri-n-octylphosphine oxide, TOPO, (C8H13)3PO. In nonpolar solvents, HDPM forms a polymeric-like substance with compounds of uranium(VI). Viscosity measurements indicate that the molecular weight of this polymeric-like substance is about 100 times greater than the corresponding complex with TOPO. Polymer formation occurs only when nonpolar solvents are used as diluents for HDPM and is easily avoided by using polar solvents such as 1,2-aichlorobenzene. HDPM forms 1:1 and 2:1 complexes with uranium(VI) nitrate. Equilibrium constants for these complexes as well as that for the 2:1 TOPO complex were calculated and it was shown that the over-all constant is at least ten times larger for the HDPM complex than for the TOPO complex. The effect of concentration of various mineral acids, extractant concentration, temperature, and diluents on the extraction of uranium are discussed."
Date: April 11, 1961
Creator: Burke, Keith E.; Sakurai, Hiroshi; O'Laughlin, Jerome W. & Banks, Charles V.
System: The UNT Digital Library
Simple High-Voltage Trapezoidal Pulse Generator (open access)

Simple High-Voltage Trapezoidal Pulse Generator

From abstract: "A description is given of a simple circuit used to produce negative voltage pulses up to 60 kilovolts with a portion rising with constant slope up to 10 kilovolts per microsecond."
Date: April 2, 1962
Creator: Gonella, Luigi
System: The UNT Digital Library
The Application of Wax Laps to Vibratory Polishers (open access)

The Application of Wax Laps to Vibratory Polishers

From introduction: "In this paper the adaptation of the wax lab surface vibratory polisher is described. The wax lap requires little maintenance during the life of the lap. It is not necessary to remove any of the holding devices on the bowl to clean and recondition the lap. The bowl is merely washed out, recharged and placed in operation. The wax lap will not wrinkle or tear, nor is it necessary to change it each day such as the silk or nylon cloths."
Date: April 19, 1962
Creator: Hopkins, E. N. & Peterson, D. T.
System: The UNT Digital Library
The Mass Spectra of the α-Amino Acids (open access)

The Mass Spectra of the α-Amino Acids

From abstract: "The mass spectra of the α-amino acids have been obtained in a mass spectrometer equipped with a heated crucible ion source. Correlations of these data have been made with the molecular formulae of the ion fragments, and mechanisms leading to these fragments are proposed. Comparisons of these data have been made with the mass spectra of the ethyl esters of the amino acids and with other carboxylic acids and their esters."
Date: April 9, 1962
Creator: Junk, Gregor & Svec, Harry J. (Harry John), 1918-
System: The UNT Digital Library
Formation Constants of the Complex Species Formed by Interaction of Rare-Earth Nitrilotriacetate Complexes with an Equivalent Amount of Base (open access)

Formation Constants of the Complex Species Formed by Interaction of Rare-Earth Nitrilotriacetate Complexes with an Equivalent Amount of Base

From abstract: "The formation constants of the RChOH- species, formed by interaction of individual rare-earth nitrilotriacetate species and KOH at 25°C and an ionic strength of 0.1, have been determined by the potentiometric method, i.e., computed from the pH values of equilibrium mixtures containing varying proportions of rare-earth complex and base. The relationship of these constants to the ion-exchange separation of rare earths at high pH has been discussed."
Date: April 13, 1962
Creator: Guptak, Asim K. & Powell, Jack E.
System: The UNT Digital Library
Progress in Sintering (open access)

Progress in Sintering

From abstract: "Sintering is broadly defined as all aspects of the adhesion, densification, shrinkage, and consolidation which accompanies the reduction in surface energy of a powder compact which occurs upon application of heat and/or pressure. The process of sintering is then further divided into the initiation, material transport, and grain growth-recrystallization stages. A general review is made of each of these stages, noting typical work which has contributed to progress in each area involved."
Date: April 16, 1962
Creator: Wilder, D. R.
System: The UNT Digital Library
The Adsorption and Surface Reactions of Hydrocarbons on Clean Iridium (open access)

The Adsorption and Surface Reactions of Hydrocarbons on Clean Iridium

From abstract: "The adsorption of ethane, ethylene and acetylene on clean iridium in a field emission microscope has been found to cause characteristic changes in the work function of the iridium surface. Further changes, which are time and temperature dependent, result when such surfaces are heated. Flash filament experiments have shown that the changes in work function upon heating are due to desorption reactions and that the desorbed product consists principally of hydrogen. By assuming a linear relationship between surface coverage and work function, it has been possible to determine the desorption kinetics from the observed rates of work function change at various temperatures. The results are consistent with a mechanism involving stepwise surface dehydrogenation in which a pair of hydrogen atoms is removed from the hydrocarbon molecule in each step, followed by desoption of the adsorbed hydrogen. At very high temperatures the remaining carbon atoms are removed, presumably by evaporation."
Date: April 7, 1962
Creator: Arthur, John R., Jr. & Hansen, Robert S.
System: The UNT Digital Library