Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Final report (open access)

Diosmacycloalkanes as models for the formation of hydrocarbons from surface methylenes. Final report

Assignment of the vibrational modes Of Os{sub 2}(CO){sub 8}(CHCH{sub 3}) and Os(CO){sub 4}(C{sub 2}H{sub 4)} has given fingerprint vibrational spectra for the following species when chemisorbed on metal catalyst surfaces: ethylidene and ethylene bound in a metallacyclopropane mode. The formation and fragmentation of diosmacyclobutanes have been shown to involve slippage of the outgoing olefin onto a single osmium, and associative exchange of the olefin from that site. The incorporation of vinylcyclopropane without rearrangement has confirmed the absence of a diradical intermediate. The anomalous stability of the diosmacyclobutane derived from trans-2-butene has proven due to greater destabilization (by the substituent methyls) of the slipped intermediate than of the ground state. Reaction of an osmacyclobutane with 1,3- or 1,2-dienes (allenes) gives 1,2 rather than 1,4 addition to the diosmium unit. Treatment of Os(CO){sub 4}(C{sub 2}H{sub 4}) with triflic acid results in the formation of Os(CO){sub 4}(C{sub 2}H{sub 5})OTf. The authors have found that the reaction of an aryl iodine(III) reagent with propargyl stannanes or silanes results in o-iodo propargyl arenes.
Date: April 25, 1994
Creator: Norton, J. R.
Object Type: Report
System: The UNT Digital Library
Baseline Risk Assessment of Groundwater Contamination at the Uranium Mill Tailings Site Near Gunnison, Colorado. Revision 1 (open access)

Baseline Risk Assessment of Groundwater Contamination at the Uranium Mill Tailings Site Near Gunnison, Colorado. Revision 1

This report evaluates potential impacts to public health or the environment resulting from groundwater contamination at the former uranium mill processing site. The tailings and other contaminated material at this site are being placed in an off-site disposal cell by the US Department of Energy`s (DOE) Uranium Mill Tailings Remedial Action (UMTRA) Project. Currently, the UMTRA Project is evaluating groundwater contamination. This is the second risk assessment of groundwater contamination at this site. The first risk assessment was performed primarily to evaluate existing domestic wells to determine the potential for immediate human health and environmental impacts. This risk assessment evaluates the most contaminated groundwater that flows beneath the processing site towards the Gunnison River. The monitor wells that have consistently shown the highest concentration of most contaminants are used in this risk assessment. This risk assessment will be used in conjunction with additional activities and documents to assist in determining what remedial action is needed for contaminated groundwater at the site after the tailings are relocated. This risk assessment follows an approach outlined by the US Environmental Protection Agency (EPA). The first step is to evaluate groundwater data collected from monitor wells at the site. Evaluation of these data showed …
Date: April 1, 1994
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Chemically modified electrodes and related solution studies (open access)

Chemically modified electrodes and related solution studies

This report is divided into 5 sections: Ru[sub 4]/Fe complexes of tetra(4[prime]-methyl-2,2[prime]-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked [mu]-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo([mu]-S)][sub 2]S[sub 2]CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C.M.
Object Type: Report
System: The UNT Digital Library
Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992 (open access)

Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992

This report is divided into 5 sections: Ru{sub 4}/Fe complexes of tetra(4{prime}-methyl-2,2{prime}-bipyridine)porphyrin--catalytic epoxidation of olefins; water oxidation catalysis by doubly linked {mu}-oxo ruthenium complexes; polymer films formed by oxidation of transition metal electrodes into solutions of bisbipyridinealkane ligands; polymer films containing [CpMo({mu}-S)]{sub 2}S{sub 2}CHR dinuclear clusters;and conducting polymer films for catalyst incorporation.
Date: April 1, 1993
Creator: Elliott, C. M.
Object Type: Report
System: The UNT Digital Library
Bull Canyon District, Dolores Plateau area, Colorado (open access)

Bull Canyon District, Dolores Plateau area, Colorado

Illustrations regarding the Bull Canyon District Delores Plateau Area, Colorado.
Date: April 12, 1988
Creator: unknown
Object Type: Report
System: The UNT Digital Library
Report on the Carpenter Ridge District, Dolores Plateau Area, Colorado: [Figures and Calculations] (open access)

Report on the Carpenter Ridge District, Dolores Plateau Area, Colorado: [Figures and Calculations]

Index maps, detail figures, columnar sections, and calculation tables for the Carpenter Ridge District.
Date: April 12, 1988
Creator: Miller, Gardner B.
Object Type: Report
System: The UNT Digital Library
Report on the Dolores River District, Dolores Plateau Area, Colorado: [Calculations] (open access)

Report on the Dolores River District, Dolores Plateau Area, Colorado: [Calculations]

Tables from the Dolores River District
Date: April 12, 1988
Creator: Van Voorhis, B. W.
Object Type: Report
System: The UNT Digital Library
Report on West Paradox District, Dolores Plateau Area, Colorado-Utah: [Figures and Columns] (open access)

Report on West Paradox District, Dolores Plateau Area, Colorado-Utah: [Figures and Columns]

Figures and columns for the West Paradox District.
Date: April 12, 1988
Creator: Livingston, Clifton W.
Object Type: Report
System: The UNT Digital Library
Intermediate-grade uranium resource assessment project for part of the Maybell District, Sand Wash Basin, Colorado (open access)

Intermediate-grade uranium resource assessment project for part of the Maybell District, Sand Wash Basin, Colorado

"The purpose of this project was to evaluate and assess the Miocene Browns Park Formation of a part of the Maybell district in the Sand Wash Basin in Moffat County, Colorado, as an intermediate-grade uranium resource"
Date: April 1983
Creator: Goodknight, Craig S.
Object Type: Report
System: The UNT Digital Library
Detailed uranium geochemical and stream sediment survey data release for selected portions of the Craig NTMS quadrangle, Colorado, and Rawlins NTMS quadrangle, Wyoming, including concentrations of forty-five additional elements (open access)

Detailed uranium geochemical and stream sediment survey data release for selected portions of the Craig NTMS quadrangle, Colorado, and Rawlins NTMS quadrangle, Wyoming, including concentrations of forty-five additional elements

A report discussing data collected during a detailed geochemiccal survey for uranium in streams draining parts of the Browns Park and North Park formations, in Craig, Colorado
Date: April 1981
Creator: Shannon, Spencer S.; Gallimore, David L.; Martell, Calvin J.; Hensley, Walter K.; Jackson, C. Kaye & Macdonell, Carolyn J.
Object Type: Report
System: The UNT Digital Library
Multisource Data Set Integration and Characterization of Uranium Mineralization for the Montrose Quadrangle, Colorado (open access)

Multisource Data Set Integration and Characterization of Uranium Mineralization for the Montrose Quadrangle, Colorado

A report characterizing known uranium occurrences in the Montrose Quadrangle and to find other areas in the quadrangle with similar characteristics
Date: April 1981
Creator: Bolivar, Stephen L.; Balog, Susan H.; Campbell, Katherine; Fugelso, L. Erik; Weaver, Thomas A. & Wecksung, George W.
Object Type: Report
System: The UNT Digital Library

Multisource Data Set Integration and Characterization of Uranium Mineralization for the Montrose Quadrangle, Colorado: Figures

Color photographs of geologic maps, Landsat imagery, and density slices for the Montrose quadrangle, Colorado. Also included is a color composite for the COCH-1 classification scheme.
Date: April 1981
Creator: Bolivar, Stephen L.; Balog, Susan H.; Campbell, Katherine; Fugelso, L. Erik; Weaver, Thomas A. & Wecksung, George W.
Object Type: Photograph
System: The UNT Digital Library
Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 1. Montrose Detail Projects, Colorado (open access)

Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 1. Montrose Detail Projects, Colorado

4,231 miles of high sensitivty airborne radiometric and magnetic data were gathered in southwestern Colorado. Data were collected on traverse lines 1/4 mile apart and on tie lines of approximately 6 mile spacing in five seperate detail areas primarily within the Montrose 1° x 2° sheet. All data were fully reduced and interpered by geoMetrics and are presented as six volumes in this final report.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Report
System: The UNT Digital Library
Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #2, Colorado (open access)

Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #2, Colorado

The following report is the second volume discussing the detailed aerial gamma ray and magnetic survey results taken for the Montrose quadrangle. This report focuses on Area 2, a detail area in Colorado, and provides a detailed geologic summary, interpretation report, six gamma ray and one magnetic contour maps. geochemical analysis map, interpretation map, flight line map, individual corrected profiles, survey area histograms and statistical tables.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Report
System: The UNT Digital Library
Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #3, Colorado (open access)

Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #3, Colorado

The following report is the second volume discussing the aerial gamma ray and magnetic survey results taken for the Montrose quadrangle. This report focuses on Area 3, a detail area in Colorado, and provides a detailed geologic summary, interpretation report, six gamma ray and one magnetic contour maps. geochemical analysis map, interpretation map, flight line map, individual corrected profiles, survey area histograms and statistical tables.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Report
System: The UNT Digital Library
Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #5, Colorado (open access)

Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Detail Area #5, Colorado

The following report is the second volume discussing the detailed aerial gamma ray and magnetic survey results taken for the Montrose quadrangle. This report focuses on Area 5, a detail area in Colorado, and provides a detailed geologic summary, interpretation report, six gamma ray and one magnetic contour maps. geochemical analysis map, interpretation map, flight line map, individual corrected profiles, survey area histograms and statistical tables.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Report
System: The UNT Digital Library
Analysis of Stream Quality in the Yampa River Basin, Colorado and Wyoming (open access)

Analysis of Stream Quality in the Yampa River Basin, Colorado and Wyoming

From introduction: This report relates to the first of the above objectives by describing stream quality in the Yampa River basin through 1976, with particular emphasis on conditions from August 1975 through September 1976. The content of this report is, at times, relatively technical. This is intentional. The report is aimed not at planners and decision makers but rather at those persons assigned the task of having to design, implement, and interpret a river basin assessment. The techniques and procedures used to determine ambient stream quality in the Yampa River basin have been presented in detail so that their applicability to other river basins can be determined. For the planner and decision maker, the results presented in this report are summarized in less technical terms in phase-l (Steele and others, 1979) and phase-ll summary reports.
Date: April 1980
Creator: Wentz, Dennis A. & Steele, Timothy Doak
Object Type: Report
System: The UNT Digital Library

[Montrose Detail Area #2: Average Record Data Listings]

Average record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #2 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library

[Montrose Detail Area #2: Single Record Data Listings]

Single record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #2 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library

[Montrose Detail Area #3: Average Record Data Listings]

Average record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #3 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library

[Montrose Detail Area #3: Single Record Data Listings]

Single record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #3 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library

[Montrose Detail Area #5: Average Record Data Listings]

Average record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #5 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library

[Montrose Detail Area #5: Single Record Data Listings]

Single record data listings taken during aerial gamma-ray and magnetic surveys of the Montrose Detail Area #5 in Colorado.
Date: April 1980
Creator: EG & G GeoMetrics
Object Type: Dataset
System: The UNT Digital Library
Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Quadrangle (open access)

Aerial Gamma Ray and Magnetic Survey, Final Report: Volume 2. Montrose Quadrangle

The quadrangle includes portions of the Colorado Plateau and southern Rocky Mountains Physiographic Provinces. The entire area of the Gunnison Uplift and parts of the Uncompahgre and Sawatch Uplifts are included. A part of the Piceance Basin and a segment of the Rio Grande Rift Valley are also included. A basement complex of Precambrian metamorphic and igneous rocks is exposed in the core of the Gunnison and Sawatch Uplifts in the Southern Rocky Mountains. Jurassic and Cretaceous age sedimentary rocks lie directly on the Precambrian basement in most places. They lie on Paleozoic rocks at the west edge of the Sawatch Uplift in the north-central part of the quadrangle. Triassic beds are mapped only in the canyon of the Uncompahgre River near the southwest corner of the quadrangle. A suite of Tertiary volcanics and some sedimentary rocks occupy extensive areas. Plutonic rocks of Tertiary and laramide age occupy only a small part of the quadrangle. The literature consulted included information on about 100 separate occurrences of radioactive minerals and/or anomalous radioactivity within the quadrangle. Many fracture and stratigraphically controlled forms are reported. Most of these occurrences are clustered in three areas: Cochetopa Creek, Cebolla Creek, and Marshall Pass. Important uranium …
Date: April 1979
Creator: GeoMetrics, Inc.
Object Type: Report
System: The UNT Digital Library