Laboratory studies of the behavior of undissolved solids in both pulsed and packed column extraction systems (open access)

Laboratory studies of the behavior of undissolved solids in both pulsed and packed column extraction systems

A substantial fraction of the finely divided undissolved solid material found in nuclear fuel reprocessing dissolver-product solutions is hydrophobic and tends to ``seek`` any organic-aqueous interface existing within countercurrent liquid-liquid extraction systems. While passing through pulsed-type columns this material is swept out of the aqueous phase by the combined surface area of the tiny bubbles of dispersed phase. Because these bubbles have a net velocity towards the end of the column where the nominal interface is located, the solids are swept in that direction too. These solids tend to gather in a three-phase ``crud`` layer at the nominal interface point. At equilibrium, about the same amount breaks off from the crud layer and escapes into the liquid exiting from that end of the column as enters it from the other side. If large enough, the crud layer can even interfere with interface detection and control equipment. In packed-column extraction systems, an additional problem is that feed solids can accumulate within the packing material to the point that the column `` floods`` or even totally plugs. The keys to preventing solids-related problems is the correct choice of interface level, and with packed columns, the addition of a ``pulsing leg`` at the …
Date: April 18, 1989
Creator: Siemer, D. D.
Object Type: Article
System: The UNT Digital Library
Texas Register, Volume 14, Number 29, Pages 1849-1883, April 18, 1989 (open access)

Texas Register, Volume 14, Number 29, Pages 1849-1883, April 18, 1989

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.
Date: April 18, 1989
Creator: Texas. Secretary of State.
Object Type: Journal/Magazine/Newsletter
System: The Portal to Texas History