Accurately characterizing end-to-end Internet dynamics - the performance that a user actually obtains from the lengthy series of network links that comprise a path through the Internet - is exceptionally difficult, due to the network`s immense heterogeneity. At the heart of this work is a `measurement framework` in which a number of sites around the Internet host a specialized measurement service. By coordinating `probes` between pairs of these sites one can measure end-to-end behavior along O(N{sup 2}) paths for a framework consisting of N sites. Consequently, one obtains a superlinear scaling that allows measuring a rich cross-section of Internet behavior without requiring huge numbers of observation points. 37 sites participated in this study, allowing the author to measure more than 1,000 distinct Internet paths. The first part of this work looks at the behavior of end-to-end routing: the series of routers over which a connection`s packets travel. Based on 40,000 measurements made using this framework, the author analyzes: routing `pathologies` such as loops, outages, and flutter; the stability of routes over time; and the symmetry of routing along the two directions of an end-to-end path. The author finds that pathologies increased significantly over the course of 1995 and that Internet …

We constrain the apex of the Cabibbo-Kobayashi-Maskawa unitarity triangle with measurements of B {yields} K*{pi} amplitudes from analyses of B{sup 0} {yields} K{sup +}{pi}{sup -}{pi}{sup 0} and B{sup 0} {yields} K{sub S}{pi}{sup +}{pi}{sup -} decays. This constraint is consistent with the world average. The B{sup 0} {yields} K{sup +}{pi}{sup -}{pi}{sup 0} decay mode is reconstructed from a sample of 454 million B{sup 0}{bar B}{sup 0} events collected by the BABAR detector at SLAC. We measure direct CP violation in B{sup 0} {yields} K*{sup +}{pi}{sup -} decays at the level of 3{sigma} when measurements from both B{sup 0} {yields} K{sup +}{pi}{sup -}{pi}{sup 0} and B{sup 0} {yields} K{sub S}{pi}{sup +}{pi}{sup -} decays are combined.

This thesis presents the first measurement of the differential production cross section of a heavy flavor (bottom or charm) jet and direct photon at the Fermilab Tevatron. These measurements were performed using data recorded with the D0 detector from proton-antiproton collisions at a center of mass energy of {radical}s = 1.96 TeV. These results probe a kinematic range for the photon transverse momentum of 30 < p{sub T}{sup {gamma}} < 150 GeV and rapidity of |y{sup {gamma}}| < 1.0 and for jet transverse momentum p{sub T}{sup jet} > 15 GeV and rapidity of |y{sup jet}| < 0.8. These results are compared to next-to-leading-order theoretical calculations.

Search engines, such as Google, assign scores to news articles based on their relevancy to a query. However, not all relevant articles for the query may be interesting to a user. For example, if the article is old or yields little new information, the article would be uninteresting. Relevancy scores do not take into account what makes an article interesting, which would vary from user to user. Although methods such as collaborative filtering have been shown to be effective in recommendation systems, in a limited user environment there are not enough users that would make collaborative filtering effective. I present a general framework for defining and measuring the ''interestingness'' of articles, called iScore, incorporating user-feedback including tracking multiple topics of interest as well as finding interesting entities or phrases in a complex relationship network. I propose and have shown the validity of the following: 1. Filtering based on only topic relevancy is insufficient for identifying interesting articles. 2. No single feature can characterize the interestingness of an article for a user. It is the combination of multiple features that yields higher quality results. For each user, these features have different degrees of usefulness for predicting interestingness. 3. Through user-feedback, a …

For the last decade, the Trahanovsky research group has focused on the study of various reactive molecules such as o-quinodimethanes (o-QDM`s) and p-quinodimethanes (p-QDM`s) derived from benzene, furan, and thiophene. These types of molecules are reactive and dimerize or polymerize at room temperature. One of the group`s interests is to understand the dimerization mechanism of these molecules. Paper 1 describes the preparation and dimerization product analyses of 2-ethylidene-5-methylene-2,5-dihydrothiophene. Insights provided by these results into the mechanism of the dimerization of 2,5-dimethylene-2,5-dihydrothiophene are discussed. In paper 2, a convenient synthesis of cyclooctadecane is presented.

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A novel anion-exchange resin containing three amine groups was prepared by reaction of a chloromethylated polystyrene-divinylbenzene (PS-DVB) resin with diethylenetriamine. After being protonated by contact with an aqueous acid, this resin can be used for ion chromatographic separation of anions. The charge on the resins can be varied from +1 to +3 by changing the mobile phase pH. The selectivity of the new ion exchangers for various inorganic anions was quite different from that of conventional anion exchangers. The performance of this new anion exchanger was studied by changing the pH and the concentration of the eluent, and several different eluents were used with some common anions as testing analytes. Conductivity detection and UV-visible detection were applied to detect the anions after separation. The new resin can also be used for HPLC separation of neutral organic compounds. Alkylphenols and alkylbenzenes were separated with this new polymeric resin, and excellent separations were obtained under simple conditions. This report contains Chapter 1: General introduction and Chapter 6: General conclusions.

Many scientific and industrial applications call for quantum-efficient high-energy-resolution microcalorimeters for the measurement of x rays. The applications driving the development of these detectors involve the measurement of faint sources of x rays in which few photons reach the detector. Interesting astrophysical applications for these microcalorimeters include the measurement of composition and temperatures of stellar atmospheres and diffuse interstellar plasmas. Other applications of microcalorimeter technology include x-ray fluorescence (XRF) measurements of industrial or scientific samples. We are attempting to develop microcalorimeters with energy resolutions of several eV because many sources (such as celestial plasmas) contain combinations of elements producing emission lines spaced only a few eV apart. Our microcalorimeters consist of a metal-film absorber (250 {micro}m x 250{micro}m x 3 {micro}m of copper) coupled to a superconducting transition-edge-sensor (TES) thermometer. This microcalorimeter demonstrated an energy resolution of 42 eV (FWHM) at 6 keV, excellent linearity, and showed no evidence of position dependent response. The response of our microcalorimeters depends both on the temperature of the microcalorimeter and on the electrical current conducted through the TES thermometer. We present a microcalorimeter model that extends previous microcalorimeter theory to include additional current dependent effects. The model makes predictions about the effects of …

This thesis reports a study of the mechanism of electromigration failure in Al-2Cu-1Si thin-film conducting lines on Si. Samples were patterned from 0.5 {mu}m thick vapor-deposited films with various mean grain sizes (G), and had lines widths (W) of 1.3, 2, 4 and 6 {mu}m. The lines were aged at various conditions to change the Cu-precipitate distribution and were tested to failure at T = 225{degrees}C and j = 2.5 {times} 10{sup 6} A/cm{sup 2}. Some samples were tested over a range of substrate temperatures, current densities and current reversal times. Aging produces an initially dense distribution of metastable {Theta}{prime} (Al{sub 2}Cu; coherent) in the grain interiors, with stable {Theta} (Al{sub 2}Cu; incoherent) at the grain boundaries. The intragranular {theta}{prime} is gradually absorbed into the grain boundary precipitates. In the wide lines the mean time to failure increases slowly and monotonically with pre-aging time and current reversal time. The failure mode is the formation and coalescence of voids that form on grain boundaries with an apparent activation energy of 0.65 eV. In the narrow lines, the lines failed by a transgranular-slit mechanism with an activation energy near 0.93 eV. The distribution of the polygranular segments and the kinetics of failure …

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Organic semiconductors devices, such as, organic solar cells (OSCs), organic light-emitting diodes (OLEDs) and organic field-effect transistors (OFETs) have drawn increasing interest in recent decades. As organic materials are flexible, light weight, and potentially low-cost, organic semiconductor devices are considered to be an alternative to their inorganic counterparts. This dissertation will focus mainly on OSCs and OLEDs. As a clean and renewable energy source, the development of OSCs is very promising. Cells with 9.2% power conversion efficiency (PCE) were reported this year, compared to < 8% two years ago. OSCs belong to the so-called third generation solar cells and are still under development. While OLEDs are a more mature and better studied field, with commercial products already launched in the market, there are still several key issues: (1) the cost of OSCs/OLEDs is still high, largely due to the costly manufacturing processes; (2) the efficiency of OSCs/OLEDs needs to be improved; (3) the lifetime of OSCs/OLEDs is not sufficient compared to their inorganic counterparts; (4) the physics models of the behavior of the devices are not satisfactory. All these limitations invoke the demand for new organic materials, improved device architectures, low-cost fabrication methods, and better understanding of device physics. For …

An investigation of the effusive behavior of saturated vapors over a range of source pressures from 10/sup -6/ atm in the molecular flow region to 1 atm is reported. The purposes of the investigation were to clarify the situation regarding the upper pressure limit to effusive flow, to examine the transition of effusive flow from molecular to viscous behavior, and to clarify some limited aspects concerning the question of vapor saturation within an effusion cell. Mass flow rates of mercury vapor effusing through a thin-edged orifice or long channels into a vacuum from a region of nearly saturated vapor were obtained. (W.D.M.)

This paper describes methods for solid phase extraction and high performance liquid chromatography (HPLC). The following are described: Effects of Resin Sulfonation on the Retention of Polar Organic Compounds in Solid Phase Extraction; Ion-Chromatographic Separation of Alkali Metals In Non-Aqueous Solvents; Cation-Exchange Chromatography in Non-Aqueous Solvents; and Silicalite As a Stationary Phase For HPLC.

Second harmonic generation (SHG) and infrared-visible sum frequency generation (SFG) spectroscopies have been shown to be powerful and versatile for studying surfaces with submonolayer sensitivity. They have been used in this work to study bare diamond surfaces and molecular adsorption on them. In particular, infrared-visible SFG as a surface vibrational spectroscopic technique has been employed to identify and monitor in-situ surface bonds and species on the diamond (111) surface. The CH stretch spectra allow us to investigate hydrogen adsorption, desorption, abstraction, and the nature of the hydrogen termination. The C(111) surface dosed with atomic hydrogen was found to be in a monohydride configuration with the hydrogen atoms situated at top-sites. The ratio of the abstraction rate to the adsorption rate was appreciable during atomic hydrogen dosing. Kinetic parameters for thermal desorption of H on C(111) were determined showing a near first-order kinetics. For the fully H-terminated (111) surface, a large (110 cm{sup {minus}1}) anharmonicity and {approximately}19 psec lifetime were measured for the first-excited CH stretch mode. The bare reconstructed C(111)-(2 {times} l) surface showed the presence of CC stretch modes which were consistent with the Pandey {pi}-bonded chain structure. When exposed to the methyl radical, the SFG spectra of the …

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A nuclear fuel element and a method of manufacturing the element. The fuel element is comprised of a metal primary container and a fuel pellet which is located inside it and which is often fragmented. The primary container is subjected to elevated pressure and temperature to deform the container such that the container conforms to the fuel pellet, that is, such that the container is in substantial contact with the surface of the pellet. This conformance eliminates clearances which permit rubbing together of fuel pellet fragments and rubbing of fuel pellet fragments against the container, thus reducing the amount of dust inside the fuel container and the amount of dust which may escape in the event of container breach. Also, as a result of the inventive method, fuel pellet fragments tend to adhere to one another to form a coherent non-fragmented mass: this reduces the tendency of a fragment to pierce the container in the event of impact. 1 fig., 1 tab.

The following report measures and analyzes the nuclear internal momentum distributions of protons in light nuclei with the 340-Mev scattered proton beam from the synchocyclotron.

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Since the X(3872) was discovered by the Belle Collaboration in August 2003, it's interpretation through the Standard Model has been difficult. Many possible interpretations have been proposed due to its close proximity to the D{bar D}* mass threshold, ranging from a new state in the charmonium spectrum to a 4-quark state to a weakly bound meson molecule. Probing the X(3872) is also made difficult due to low statistical samples at e{sup +}e{sup -} colliders and large combinatoric backgrounds at hadron colliders such as the Tevatron. This paper presented the results of probes of this state performed at the D0 detector.

The top quark is the heaviest known fundamental particle, with a mass of 172.0{sub -1.3}{sup +0.9}GeV. This is nearly twice the mass of the second heaviest known particle, the Z boson, and roughly the mass of a gold atom. Because of its unusually large mass, studying the top quark may provide insight into the Higgs mechanism and other beyond the standard model physics. Only two accelerators in the world are powerful enough to produce top quarks. The Tevatron, which first accelerated protons in 1983, has produced almost 400,000 top quarks, roughly half at each of its two detectors: DO and CDF. The LHC is a much newer accelerator which currently has accumulated about 0.5% as much data as the Tevatron. However, when running at full luminosity, the LHC is capable of producing a top quark about once every second and will quickly surpass the Tevatron as the leading producer of top quarks. This analysis uses data from the D0 detector at the Tevatron, which are described in chapter 3. Top quarks are produced most often in pairs of top and anti-top quarks through an interaction of the strong force. This production mode was first observed in 1995 at the Tevatron. …

We describe studies of the decays of B mesons to final states {eta}K{sup *}(892), {eta}K{sup *}{sub 0}(S-wave), {eta}K{sup *}{sub 2}(1430), and {eta}'K based on data collected with the BABAR detector at the PEP-II asymmetric-energy e{sup +}e{sup -} collier at the Stanford Linear Accelerator Center. We measure branching fractions and charge asymmetries for the decays B {yields} {eta}K{sup *}, where K{sup *} indicates a spin 0, 1, or 2 K{pi} system, making first observations of decays to final states {eta}K{sup *0}{sub 0}(S-wave), {eta}K{sup *+}{sub 0} (S-wave), and {eta}K{sup *0}{sub 2}(1430). We measure the time-dependent CP-violation parameters S and C for the decays B{sup 0} {yields} {eta}'K{sup 0}, observing CP violation in a charmless B decay with 5{sigma} significance considering both statistical and systematic uncertainties..

When an important compound`s discovery dates back as far as 1825, one would imagine that every facet of its chemical and physical properties has been illuminated in the meantime. Benzene, however, has not ceased to challenge the chemist`s notion of structure and bonding since its first isolation by Michael Faraday. This report is divided into the following six chapters: 1. Aromaticity -- Criteria, manifestations, structural limitations; 2. The role of delocalization in benzene; 3. The thermochemical properties of benzocyclobutadienologs; 4. Ab initio study of benzenes fused to four-membered rings; 5. Non-planar polycyclic aromatic hydrocarbons; and 6. Experimental details and input decks. 210 Refs.

The past decade is one of the most exciting period in the history of physics and astronomy. The discovery of cosmic acceleration dramatically changed our understanding about the evolution and constituents of the Universe. To accommodate the new acceleration phase into our well established Big Bang cosmological scenario under the frame work of General Relativity, there must exist a very special substance that has negative pressure and make up about 73% of the total energy density in our Universe. It is called Dark Energy. For the first time people realized that the vast majority of our Universe is made of things that are totally different from the things we are made of. Therefore, one of the major endeavors in physics and astronomy in the coming years is trying to understand, if we can, the nature of dark energy. Understanding dark energy cannot be achieved from pure logic. We need empirical evidence to finally determine about what is dark energy. The better we can constrain the energy density and evolution of the dark energy, the closer we will get to the answer. There are many ways to constrain the energy density and evolution of dark energy, each of which leads to …

After implantation of As, As + Be, and As + Ga into GaN and annealing for short durations at temperatures as high as 1500 C, the GaN films remained highly resistive. It was apparent from c-RBS studies that although implantation damage did not create an amorphous layer in the GaN film, annealing at 1500 C did not provide enough energy to completely recover the radiation damage. Disorder recovered significantly after annealing at temperatures up to 1500 C, but not completely. From SIMS analysis, oxygen contamination in the AIN capping layer causes oxygen diffusion into the GaN film above 1400 C. The sapphire substrate (A1203) also decomposed and oxygen penetrated into the backside of the GaN layer above 1400 C. To prevent donor-like oxygen impurities from the capping layer and the substrate from contaminating the GaN film and compensating acceptors, post-implantation annealing should be done at temperatures below 1500 C. Oxygen in the cap could be reduced by growing the AIN cap on the GaN layer after the GaN growth run or by depositing the AIN layer in a ultra high vacuum (UHV) system post-growth to minimize residual oxygen and water contamination. With longer annealing times at 1400 C or at …