N >= 4 Supergravity Amplitudes from Gauge Theory at Two Loops (open access)

N >= 4 Supergravity Amplitudes from Gauge Theory at Two Loops

We present the full two-loop four-graviton amplitudes in N = 4, 5, 6 supergravity. These results were obtained using the double-copy structure of gravity, which follows from the recently conjectured color-kinematics duality in gauge theory. The two-loop four-gluon scattering amplitudes in N = 0, 1, 2 supersymmetric gauge theory are a second essential ingredient. The gravity amplitudes have the expected infrared behavior: the two-loop divergences are given in terms of the squares of the corresponding one-loop amplitudes. The finite remainders are presented in a compact form. The finite remainder for N = 8 supergravity is also presented, in a form that utilizes a pure function with a very simple symbol.
Date: February 15, 2012
Creator: Boucher-Veronneau, C. & Dixon, L. J.
System: The UNT Digital Library
A 10,000 groove/mm multilayer coated grating for EUV spectroscopy (open access)

A 10,000 groove/mm multilayer coated grating for EUV spectroscopy

Ultra-high spectral resolution in the EUV and soft x-ray energy ranges requires the use of very high line density gratings with optimal design resulting in use of a Blazed Multilayer Grating (BMG) structure. Here we demonstrate the production of near-atomically perfect Si blazed substrates with an ultra-high groove density (10,000 l/mm) together with the measured and theoretical performance of an Al/Zr multilayer coating on the grating. A 1st order absolute efficiency of 13percent and 24.6percent was achieved at incidence angles of 11o and 36o respectively. Cross-sectional TEM shows the effect of smoothing caused by the surface mobility of deposited atoms and we correlate this effect with a reduction in peak diffraction efficiency. This work shows the high performance that can be achieved with BMGs based on small-period anisotropic etched Si substrates, but also the constraints imposed by the surface mobility of deposited species.
Date: February 7, 2011
Creator: Voronov, Dmytro; Anderson, Erik; Cambie, Rossana; Cabrini, Stefano; Dhuey, Scott; Goray, Leonid et al.
System: The UNT Digital Library
2011 Alkaline Membrane Fuel Cell Workshop Final Report (open access)

2011 Alkaline Membrane Fuel Cell Workshop Final Report

A workshop addressing the current state-of-the-art in alkaline membrane fuel cells (AMFCs) was held May 8-9, 2011, at the Crystal Gateway Marriott in Arlington, Virginia. This workshop was the second of its kind, with the first being held December 11-13, 2006, in Phoenix, Arizona. The 2011 workshop and associated workshop report were created to assess the current state of AMFC technology (taking into account recent advances), investigate the performance potential of AMFC systems across all possible power ranges and applications, and identify the key research needs for commercial competitiveness in a variety of areas.
Date: February 1, 2012
Creator: Pivovar, B.
System: The UNT Digital Library
2011 Chemical Reactions at Surfaces Gordon Research Conference (open access)

2011 Chemical Reactions at Surfaces Gordon Research Conference

The Gordon Research Conference on Chemical Reactions at Surfaces is dedicated to promoting and advancing the fundamental science of interfacial chemistry and physics by providing surface scientists with the foremost venue for presentation and discussion of research occurring at the frontiers of their fields.
Date: February 11, 2011
Creator: Stair, Peter
System: The UNT Digital Library
2011 Plant Lipids: Structure, Metabolism, & Function Gordon Research Conference (open access)

2011 Plant Lipids: Structure, Metabolism, & Function Gordon Research Conference

This is the second Gordon Research Conference on 'Plant Lipids: Structure, Metabolism & Function'. It covers current topics in lipid structure, metabolism and function in eukaryotic photosynthetic organisms including seed plants, algae, mosses and ferns. Work in photosynthetic bacteria is considered as well as it serves the understanding of specific aspects of lipid metabolism in plants. Breakthroughs are discussed in research on plant lipids as diverse as glycerolipids, sphingolipids, lipids of the cell surface, isoprenoids, fatty acids and their derivatives. The program covers nine concepts at the forefront of research under which afore mentioned plant lipid classes are discussed. The goal is to integrate areas such as lipid signaling, basic lipid metabolism, membrane function, lipid analysis, and lipid engineering to achieve a high level of stimulating interaction among diverse researchers with interests in plant lipids. One Emphasis is on the dynamics and regulation of lipid metabolism during plant cell development and in response to environmental factors.
Date: February 4, 2011
Creator: Benning, Christopher
System: The UNT Digital Library
2011 Raditation & Climate Gordon Research Conference (July 10-15 2011- Colby College, Waterville, Maine) (open access)

2011 Raditation & Climate Gordon Research Conference (July 10-15 2011- Colby College, Waterville, Maine)

The 2011 Gordon Research Conference on Radiation and Climate will present cutting-edge research on outstanding issues in climate change, particularly those in which the interactions between clouds, aerosols, and precipitation play a major role. The Conference will feature a broad range of topics, including grand challenges in atmospheric radiation and climate, cloud and water vapor feedbacks, aerosol-cloud-precipitation-climate interactions across scales, new approaches for remote sensing and in-situ observations of clouds, aerosols and precipitation, and multi-scale modeling challenges. The invited speakers will present the most important recent advances and future challenges in these areas. The Conference will bring together a collection of leading investigators who are at the forefront of their field, and will provide opportunities for scientists, especially junior scientists and graduate students, to present their work in poster format and exchange ideas with leaders in the field. The collegial atmosphere of this Conference, with programmed discussion sessions as well as opportunities for informal gatherings in the afternoons and evenings, provides an avenue for scientists from different disciplines to brainstorm and promotes cross-disciplinary collaborations in the various research areas represented.
Date: February 9, 2012
Creator: Hoggblom, Prof. Max
System: The UNT Digital Library
2012 MOLECULAR AND IONIC CLUSTERS GORDON RESEARCH CONFERENCE, JANUARY 29 - FEBRUARY 3, 2012 (open access)

2012 MOLECULAR AND IONIC CLUSTERS GORDON RESEARCH CONFERENCE, JANUARY 29 - FEBRUARY 3, 2012

The Gordon Research Conference on 'Molecular and Ionic Clusters' focuses on clusters, which are the initial molecular species found in gases when condensation begins to occur. Condensation can take place solely from molecules interacting with each other, mostly at low temperatures, or when molecules condense around charged particles (electrons, protons, metal cations, molecular ions), producing ion molecule clusters. These clusters provide models for solvation, allow a pristine look at geometric as well as electronic structures of molecular complexes or matter in general, their interaction with radiation, their reactivity, their thermodynamic properties and, in particular, the related dynamics. This conference focuses on new ways to make clusters composed of different kinds of molecules, new experimental techniques to investigate the properties of the clusters and new theoretical methods with which to calculate the structures, dynamical motions and energetics of the clusters. Some of the main experimental methods employed include molecular beams, mass spectrometry, laser spectroscopy (from infrared to XUV; in the frequency as well as the time domain) and photoelectron spectroscopy. Techniques include laser absorption spectroscopy, laser induced fluorescence, resonance enhanced photoionization, mass-selected photodissociation, photofragment imaging, ZEKE photoelectron spectroscopy, etc. From the theoretical side, this conference highlights work on potential surfaces and …
Date: February 3, 2012
Creator: McCoy, Anne
System: The UNT Digital Library
2014 Chemical Reactions at Surfaces Gordon Research Conference and Gordon Research Seminar (April 28-May 3, 2013 - Les Diablerets Conference Center, Les Diablerets, Switzerland) (open access)

2014 Chemical Reactions at Surfaces Gordon Research Conference and Gordon Research Seminar (April 28-May 3, 2013 - Les Diablerets Conference Center, Les Diablerets, Switzerland)

presentations on chemistry at solid and liquid surfaces of relevance to catalysis, synthesis, photochemistry, environmental science, and tribology. Topics include: Fundamental Surface Chemistry; Catalysis; Solid Liquid and Aerosol Interfaces; Surface Photochemistry; Synthesis of Surfaces; Environmental Interfaces; Hot Topics in Surface Chemical Reactions; Tribology; Gas-Surface Scattering and Reactions; Novel Materials and Environments.
Date: February 3, 2013
Creator: Stair, Peter C.
System: The UNT Digital Library
3D Surface Mapping of Capsule Fill-Tube Assemblies used in Laser-Driven Fusion Targets (open access)

3D Surface Mapping of Capsule Fill-Tube Assemblies used in Laser-Driven Fusion Targets

This paper presents the development of a 3D surface mapping system used to measure the surface of a fusion target Capsule Fill-Tube Assembly (CFTA). The CFTA consists of a hollow Ge-doped plastic sphere, called a capsule, ranging in outer diameter between 2.2 mm and 2.6 mm and an attached 150 {micro}m diameter glass-core fill-tube that tapers down to a 10{micro} diameter at the capsule. The mapping system is an enabling technology to facilitate a quality assurance program and to archive 3D surface information of each capsule used in fusion ignition experiments that are currently being performed at the National Ignition Facility (NIF). The 3D Surface Mapping System is designed to locate and quantify surface features with a height of 50 nm and 300 nm in width or larger. Additionally, the system will be calibrated such that the 3D measured surface can be related to the capsule surface angular coordinate system to within 0.25 degree (1{sigma}), which corresponds to approximately 5 {micro}m linear error on the capsule surface.
Date: February 18, 2011
Creator: Buice, E. S.; Alger, E. T.; Antipa, N. A.; Bhandarkar, S. D.; Biesiada, T. A.; Conder, A. D. et al.
System: The UNT Digital Library
Ab-initio description of quasiparticle band structures and optical near-edge absorption of transparent conducting oxides (open access)

Ab-initio description of quasiparticle band structures and optical near-edge absorption of transparent conducting oxides

None
Date: February 14, 2012
Creator: Schleife, A & Bechstedt, F
System: The UNT Digital Library
Ab Initio Many-Body Calculations of Deuteron-4He Scattering And 6Li States (open access)

Ab Initio Many-Body Calculations of Deuteron-4He Scattering And 6Li States

None
Date: February 8, 2011
Creator: Quaglioni, S & Navratil, P
System: The UNT Digital Library
Absorber height effects on SWA restrictions and 'Shadow' LER (open access)

Absorber height effects on SWA restrictions and 'Shadow' LER

As extreme-ultraviolet lithography (EUVL) approaches introduction at the 22-nm half-pitch node, several key aspects of absorber height effects remain unexplored. In particular, sidewall angle (SWA) restrictions based on the height of the mask absorber has not yet been clearly defined. In addition, the effects of absorber height on line-edge roughness (LER) from shadowing has not been examined. We make an initial investigation into how tight SWA constraints are and the extent to which shadow LER alters basic LER. Our approach to SWA aims to find SWA restrictions based on 10% of the total CD error budget (10% of CD). Thus, we allot the SWA budget a {+-}0.2nm tolerance for 22nm half-pitch. New with EUVL is the off-axis illumination system. One potential pitfall that must be carefully monitored is the effect of mask absorber height blocking light from reaching, and therefore, correctly detecting, the base edge position of a feature. While mask features can correctly compensate sizing to target at the wafer, the effects of this shadowing on LER have not yet been investigated. Specifically, shadow LER may exacerbate or mitigate the inherent LER on the mask. Shadowing may also cause a difference in the observed LER on the right and …
Date: February 21, 2011
Creator: McClinton, Brittany & Naulleau, Patrick
System: The UNT Digital Library
Accelerated Stress Testing of Hydrocarbon-Based Encapsulants for Medium-Concentration CPV Applications (open access)

Accelerated Stress Testing of Hydrocarbon-Based Encapsulants for Medium-Concentration CPV Applications

Concentrating photovoltaic (CPV) systems have great potential to reduce photovoltaic (PV) electricity costs because of the relatively low cost of optical components as compared to PV cells. A transparent polymeric material is used to optically couple the PV cell to optical components and is thus exposed to the concentrated light source at elevated temperatures. In this work polymeric encapsulant materials are positioned close to a Xenon arc lamp to expose them to ultraviolet radiation (UV) that is about 42 times as intense as sunlight. Furthermore, different glass types are used as filters to modify the spectral distribution of light in the UV range. A strong sensitivity of non-silicone-based encapsulants to light below ~350 nm is demonstrated. Of all the materials examined in this study, the polydimethyl silicone samples performed the best. The next best material was an ionomer which maintained optical transmission but became photo-oxidized where exposed to the atmosphere.
Date: February 1, 2011
Creator: Kempe, M. D.; Moricone, T. J.; Kilkenny, M. & Zhang, J. Z.
System: The UNT Digital Library
Accelerating Atomic Orbital-based Electronic Structure Calculation via Pole Expansion plus Selected Inversion (open access)

Accelerating Atomic Orbital-based Electronic Structure Calculation via Pole Expansion plus Selected Inversion

We describe how to apply the recently developed pole expansion plus selected inversion (PEpSI) technique to Kohn-Sham density function theory (DFT) electronic structure calculations that are based on atomic orbital discretization. We give analytic expressions for evaluating charge density, total energy, Helmholtz free energy and atomic forces without using the eigenvalues and eigenvectors of the Kohn-Sham Hamiltonian. We also show how to update the chemical potential without using Kohn-Sham eigenvalues. The advantage of using PEpSI is that it has a much lower computational complexity than that associated with the matrix diagonalization procedure. We demonstrate the performance gain by comparing the timing of PEpSI with that of diagonalization on insulating and metallic nanotubes. For these quasi-1D systems, the complexity of PEpSI is linear with respect to the number of atoms. This linear scaling can be observed in our computational experiments when the number of atoms in a nanotube is larger than a few hundreds. Both the wall clock time and the memory requirement of PEpSI is modest. This makes it even possible to perform Kohn-Sham DFT calculations for 10,000-atom nanotubes on a single processor. We also show that the use of PEpSI does not lead to loss of accuracy required in …
Date: February 10, 2012
Creator: Lin, Lin; Chen, Mohan; Yang, Chao & He, Lixin
System: The UNT Digital Library
Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies (open access)

Accurate determination of Curium and Californium isotopic ratios by inductively coupled plasma quadrupole mass spectrometry (ICP-QMS) in 248Cm samples for transmutation studies

The French Atomic Energy Commission has carried out several experiments including the mini-INCA (INcineration of Actinides) project for the study of minor-actinide transmutation processes in high intensity thermal neutron fluxes, in view of proposing solutions to reduce the radiotoxicity of long-lived nuclear wastes. In this context, a Cm sample enriched in {sup 248}Cm ({approx}97 %) was irradiated in thermal neutron flux at the High Flux Reactor (HFR) of the Laue-Langevin Institute (ILL). This work describes a quadrupole ICP-MS (ICP-QMS) analytical procedure for precise and accurate isotopic composition determination of Cm before sample irradiation and of Cm and Cf after sample irradiation. The factors that affect the accuracy and reproducibility of isotopic ratio measurements by ICP-QMS, such as peak centre correction, detector dead time, mass bias, abundance sensitivity and hydrides formation, instrumental background, and memory blank were carefully evaluated and corrected. Uncertainties of the isotopic ratios, taking into account internal precision of isotope ratio measurements, peak tailing, and hydrides formations ranged from 0.3% to 1.3%. This uncertainties range is quite acceptable for the nuclear data to be used in transmutation studies.
Date: February 1, 2011
Creator: Gourgiotis, A.; Isnard, H.; Aubert, M.; Dupont, E.; AlMahamid, I.; Cassette, P. et al.
System: The UNT Digital Library
Activation Energy of Tantalum-Tungsten Oxide Thermite Reaction (open access)

Activation Energy of Tantalum-Tungsten Oxide Thermite Reaction

The activation energy of a high melting temperature sol-gel (SG) derived tantalum-tungsten oxide thermite composite was determined using the Kissinger isoconversion method. The SG derived powder was consolidated using the High Pressure Spark Plasma Sintering (HPSPS) technique to 300 and 400 C to produce pellets with dimensions of 5 mm diameter by 1.5 mm height. A custom built ignition setup was developed to measure ignition temperatures at high heating rates (500-2000 C {center_dot} min{sup -1}). Such heating rates were required in order to ignite the thermite composite. Unlike the 400 C samples, results show that the samples consolidated to 300 C undergo an abrupt change in temperature response prior to ignition. This change in temperature response has been attributed to the crystallization of the amorphous WO{sub 3} in the SG derived Ta-WO{sub 3} thermite composite and not to a pre-ignition reaction between the constituents. Ignition temperatures for the Ta-WO{sub 3} thermite ranged from approximately 465-670 C. The activation energy of the SG derived Ta-WO{sup 3} thermite composite consolidated to 300 and 400 C were determined to be 37.787 {+-} 1.58 kJ {center_dot} mol{sup -1} and 57.381 {+-} 2.26 kJ {center_dot} mol{sup -1}, respectively.
Date: February 25, 2010
Creator: Cervantes, O.; Kuntz, J.; Gash, A. & Munir, Z.
System: The UNT Digital Library
ACTIVE CAPPING TECHNOLOGY - NEW APPROACHES FOR IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS (open access)

ACTIVE CAPPING TECHNOLOGY - NEW APPROACHES FOR IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS

This study evaluated pilot-scale active caps composed of apatite, organoclay, biopolymers, and sand for the remediation of metal-contaminated sediments. The active caps were constructed in Steel Creek, at the Savannah River Site near Aiken, South Carolina. Monitoring was conducted for 12 months. Effectiveness of the caps was based on an evaluation of contaminant bioavailability, resistance to erosion, and impacts on benthic organisms. Active caps lowered metal bioavailability in the sediment during the one-year test period. Biopolymers reduced sediment suspension during cap construction, increased the pool of carbon, and lowered the release of metals. This field validation showed that active caps can effectively treat contaminants by changing their speciation, and that caps can be constructed to include more than one type of amendment to achieve multiple goals.
Date: February 13, 2012
Creator: Knox, A.; Paller, M. & Roberts, J.
System: The UNT Digital Library
Addressing Control of Hazardous Energy (COHE) Requirements in a Laser Safety Program (open access)

Addressing Control of Hazardous Energy (COHE) Requirements in a Laser Safety Program

OSHA regulation 29CFR1910.147 specifies control of hazardous energy requirements for 'the servicing and maintenance of machines and equipment in which the unexpected energization or start up of the machines or equipment, or release of stored energy could cause injury to employees.' Class 3B and Class 4 laser beams must be considered hazardous energy sources because of the potential for serious eye injury; careful consideration is therefore needed to safely de-energize these lasers. This paper discusses and evaluates control of hazardous energy principles in this OSHA regulation, in ANSI Z136.1 ''Safe Use of Lasers,'' and in ANSI Z244.1 ''Control of Hazardous Energy, Lockout/Tagout and Alternative Methods.'' Recommendations are made for updating and improving CoHE (control of hazardous energy) requirements in these standards for their applicability to safe laser operations.
Date: February 15, 2012
Creator: Woods, Michael
System: The UNT Digital Library
AdS/QCD and Applications of Light-Front Holography (open access)

AdS/QCD and Applications of Light-Front Holography

Light-Front Holography leads to a rigorous connection between hadronic amplitudes in a higher dimensional anti-de Sitter (AdS) space and frame-independent light-front wavefunctions of hadrons in 3 + 1 physical space-time, thus providing a compelling physical interpretation of the AdS/CFT correspondence principle and AdS/QCD, a useful framework which describes the correspondence between theories in a modified AdS5 background and confining field theories in physical space-time. To a first semiclassical approximation, where quantum loops and quark masses are not included, this approach leads to a single-variable light-front Schroedinger equation which determines the eigenspectrum and the light-front wavefunctions of hadrons for general spin and orbital angular momentum. The coordinate z in AdS space is uniquely identified with a Lorentz-invariant coordinate {zeta} which measures the separation of the constituents within a hadron at equal light-front time. The internal structure of hadrons is explicitly introduced and the angular momentum of the constituents plays a key role. We give an overview of the light-front holographic approach to strongly coupled QCD. In particular, we study the photon-to-meson transition form factors (TFFs) F{sub M{gamma}}(Q{sup 2}) for {gamma}{gamma}* {yields} M using light-front holographic methods. The results for the TFFs for the {eta} and {eta}' mesons are also presented. Some …
Date: February 16, 2012
Creator: Brodsky, Stanley J.; /SLAC /Southern Denmark U., CP3-Origins; Cao, Fu-Guang; U., /Massey; de Teramond, Guy F. & U., /Costa Rica
System: The UNT Digital Library
AdS/QCD and Light Front Holography: A New Approximation to QCD (open access)

AdS/QCD and Light Front Holography: A New Approximation to QCD

The combination of Anti-de Sitter space (AdS) methods with light-front holography leads to a semi-classical first approximation to the spectrum and wavefunctions of meson and baryon light-quark bound states. Starting from the bound-state Hamiltonian equation of motion in QCD, we derive relativistic light-front wave equations in terms of an invariant impact variable {zeta} which measures the separation of the quark and gluonic constituents within the hadron at equal light-front time. These equations of motion in physical space-time are equivalent to the equations of motion which describe the propagation of spin-J modes in anti-de Sitter (AdS) space. Its eigenvalues give the hadronic spectrum, and its eigenmodes represent the probability distribution of the hadronic constituents at a given scale. Applications to the light meson and baryon spectra are presented. The predicted meson spectrum has a string-theory Regge form M{sup 2} = 4{kappa}{sup 2}(n+L+S/2); i.e., the square of the eigenmass is linear in both L and n, where n counts the number of nodes of the wavefunction in the radial variable {zeta}. The space-like pion form factor is also well reproduced. One thus obtains a remarkable connection between the description of hadronic modes in AdS space and the Hamiltonian formulation of QCD in …
Date: February 15, 2010
Creator: Brodsky, Stanley J. & de Teramond, Guy
System: The UNT Digital Library
AdS/QCD, Light-Front Holography, and Color Confinement (open access)

AdS/QCD, Light-Front Holography, and Color Confinement

This report talks about the AdS/QCD, Light-Front Holography, and Color Confinement
Date: February 1, 2013
Creator: Brodsky, Stanley J. & Teramond, Guy F. de
System: The UNT Digital Library
AdS/QCD, Light-Front Holography, and Sublimated Gluons (open access)

AdS/QCD, Light-Front Holography, and Sublimated Gluons

The gauge/gravity duality leads to a simple analytical and phenomenologically compelling nonperturbative approximation to the full light-front QCD Hamiltonian - 'Light-Front Holography', which provides a Lorentz-invariant first-approximation to QCD, and successfully describes the spectroscopy of light-quark meson and baryons, their elastic and transition form factors, and other hadronic properties. The bound-state Schroedinger and Dirac equations of the soft-wall AdS/QCD model predict linear Regge trajectories which have the same slope in orbital angular momentum L and radial quantum number n for both mesons and baryons. Light-front holography connects the fifth-dimensional coordinate of AdS space z to an invariant impact separation variable {zeta} in 3+1 space at fixed light-front time. A key feature is the determination of the frame-independent light-front wavefunctions of hadrons - the relativistic analogs of the Schroedinger wavefunctions of atomic physics which allow one to compute form factors, transversity distributions, spin properties of the valence quarks, jet hadronization, and other hadronic observables. One thus obtains a one-parameter color-confining model for hadron physics at the amplitude level. AdS/QCD also predicts the form of the non-perturbative effective coupling {alpha}{sub s}{sup AdS} (Q) and its {beta}-function with an infrared fixed point which agrees with the effective coupling a{sub g1} (Q{sup 2}) extracted …
Date: February 16, 2012
Creator: Brodsky, Stanley J. & de Teramond, Guy F.
System: The UNT Digital Library
Advanced Compton scattering light source R&D at LLNL (open access)

Advanced Compton scattering light source R&D at LLNL

We report the design and current status of a monoenergetic laser-based Compton scattering 0.5-2.5 MeV {gamma}-ray source. Previous nuclear resonance fluorescence results and future linac and laser developments for the source are presented. At MeV photon energies relevant for nuclear processes, Compton scattering light sources are attractive because of their relative compactness and improved brightness above 100 keV, compared to typical 4th generation synchrotrons. Recent progress in accelerator physics and laser technology have enabled the development of a new class of tunable Mono-Energetic Gamma-Ray (MEGa-Ray) light sources based on Compton scattering between a high-brightness, relativistic electron beam and a high intensity laser pulse produced via chirped-pulse amplification (CPA). A new precision, tunable gamma-ray source driven by a compact, high-gradient X-band linac is currently under development and construction at LLNL. High-brightness, relativistic electron bunches produced by an X-band linac designed in collaboration with SLAC will interact with a Joule-class, 10 ps, diode-pumped CPA laser pulse to generate tunable {gamma}-rays in the 0.5-2.5 MeV photon energy range via Compton scattering. Based on the success of the previous Thomson-Radiated Extreme X-rays (T-REX) Compton scattering source at LLNL, the source will be used to excite nuclear resonance fluorescence lines in various isotopes; applications include …
Date: February 16, 2010
Creator: Albert, F.; Anderson, S. G.; Anderson, G.; Betts, S. M.; Chu, T. S.; Gibson, D. J. et al.
System: The UNT Digital Library
ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE (open access)

ADVANCED OXIDATION: OXALATE DECOMPOSITION TESTING WITH OZONE

At the Savannah River Site (SRS), oxalic acid is currently considered the preferred agent for chemically cleaning the large underground Liquid Radioactive Waste Tanks. It is applied only in the final stages of emptying a tank when generally less than 5,000 kg of waste solids remain, and slurrying based removal methods are no-longer effective. The use of oxalic acid is preferred because of its combined dissolution and chelating properties, as well as the fact that corrosion to the carbon steel tank walls can be controlled. Although oxalic acid is the preferred agent, there are significant potential downstream impacts. Impacts include: (1) Degraded evaporator operation; (2) Resultant oxalate precipitates taking away critically needed operating volume; and (3) Eventual creation of significant volumes of additional feed to salt processing. As an alternative to dealing with the downstream impacts, oxalate decomposition using variations of ozone based Advanced Oxidation Process (AOP) were investigated. In general AOPs use ozone or peroxide and a catalyst to create hydroxyl radicals. Hydroxyl radicals have among the highest oxidation potentials, and are commonly used to decompose organics. Although oxalate is considered among the most difficult organic to decompose, the ability of hydroxyl radicals to decompose oxalate is considered to …
Date: February 29, 2012
Creator: Ketusky, E. & Subramanian, K.
System: The UNT Digital Library