Introduction: "The adoption of aluminum nitrate as salting agent in the Redox process made it imperative that a method be available for determining plutonium in the presence of aluminum. However, large amounts of aluminum have been found to interfere with the determination of plutonium by the lanthanum fluoride procedure. Previous attempts to increase the accuracy of the lanthanum fluoride method, by precipitating LaF3 from 4 M HF (rather than 2 M), have been successful only when the initial plutonium level was high."

The following documents are progress reports that follow chemical research studies in subjects such as ruthenium tetroxile distillations, extraction-scrub studies of zirconium and niobium, and oxidation of plutonium and stabilization of plutonium(VI) during extraction of IAF solutions.

The following report provides the results of laboratory corrosion tests held to investigate the behavior of austenitic stainless steel, Type 347, in selected O.R.N.L. #1 Redox streams.

Abstract: "Diameter measurements of 25 slugs taken before and after a prolonged heat treatment showed no evidence of differences that would indicate blistering. The average effects of the treatment was different for the various slugs. Large differences in diameter measurements between slugs. Large differences in diameter between slugs and significant differences between indices and positions were found."

Abstract: "The objectives of this program are the development of zirconium-base alloys possessing exceptionally good corrosion resistance to 680 F water or 750-900 F system and/or improved strength at elevated temperatures. Approximately 100 binary compositions were prepared and screened by corrosion testing in 680 F water; selected compositions were exposed to 750 F steam. The data obtained indicate promising bases for ternary and quaternary alloys. Related investigations involving zirconium purity and heat treatment for improvement of corrosion properties are proceeding. Hydrogen pickup and mechanical properties will be used as acceptability tests on promising compositions."

Abstract: A definitive investigation of the boron-carbon equilibrium system is being made by X-ray diffraction, metallographic, and thermal analytical techniques. On the basis of metallographic and X-ray diffraction studies it is concluded that boron carbide has a range of solubility from approximately 10 to 20 atomic per cent carbon at 1500 degrees to 2000 degrees Celsius. The melting point of the carbide-graphite eutectic has been established as 2325-2350 degrees Celsius. No reversible allotropy of the beta-rhombohedral structure has been observed. The solubility of carbon in boron is very small. The melting point of dilute carbon alloys is found to be essentially the same as that of pure boron (2040 degrees to 2050 degrees). No metallographic evidence of a three-phase reaction of dilute alloys is observed.

This report has two parts to it discussing mineralogical examination of pitchblende concentrates and nitric acid digest residues. Part I gives the results of a cursory examination with the petrographic microscope of samples of pitchblende concentrates and residues to see if there is a relationship between the mineral composition of the samples and the filterability of the residue. Part II gives a revaluation of the data in Report BMI-241 on the mineral composition of two residues from the nitric acid digestion of pitchblende concentrates at the Rallinckrodt Chemical Works.

This document reports progress during the month of February, 1961, recording investigations and studies of a flow rate using a curved pipe or S-tube and documenting measurements of mass flow, tube design and construction.

Quarterly report describing the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between October 1 to December 31, 1960 and was conducted by the United States and the European Atomic Energy Community (EURATOM).

Annual technical report describing the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between February 1, 1961 to February 28, 1962 and was conducted by the United States and the European Atomic Energy Community (EURATOM).

Abstract: "A method for determination of dibutyl phosphate in solvent streams containing tributyl phosphate is outlined. The method is based on analysis for total uranium of total phosphate after removal of uranium and phosphate in excess of that present as uranyl dibutyl phosphate. Results on plant solvent samples are presented. Difficulties with precipitation of [...] dibutyl phosphate, when fresh solvents were employed, are discussed. Small amounts of nonphosphate uranium-complexing agents were found in plant solvents. Diluent degradation is postulated as the source of these components. Emulsion-formation tendencies appeared to correlate better with concentrations of these contaminants than with dibutyl phosphate content."

Quarterly progress report describing work related to a study of radiation physics problems involved in the design of high-level cesium-137 gamma sources. It outlines work completed and ongoing goals for the project.

"Abstract: An evaluation of a modulator flux sensitive playback head to be used with an analog magnetic recorder for nuclear pulse information storage was made. The modulator head was found unsultable. A pulse stretching unit was constructed which takes pulses from a standard linear pulse amplifier and provides an output signal suitable for driving a recording head."

Abstract: "Following nitrate removal by means of a three-stage hydrochloric acid digestion, uranium was reduced with chromous sulfate reagent. In an inert atmosphere, the quadrivalent uranium was titrated at 80-95[degrees] with standard ferric sulfate solution. The end point was obtained with a potentiometric cell including a platinum in-titrant reference electrode and a platinum indicator electrode. Application was made to various low leverl uranium solutions. For samples containing 1 - 12 milligrams or uranium, less than one percent error may be expected. Iron and chromium do not interfere."

Introduction: "Room temperature and elevated temperature, static immersion and vapor suspicion, corrosion tests were conducted with Duriron, Hastelloy C, and tantalum in hydriotic acid and 234-5 project process supernatant solution (synthetic environments. The data relevant to these tests are contained herein."

From introduction: "This report is an attempt to examine, semiquantitavely, the way the competition between neutron emission and fission varies for heavy nuclei as a function of nuclear type and excitation energy. Many of the ideas herein are the results of discussions with R. H. Goeckermann and W. Heckrotte of the University of California Radiation Laboratory."

Abstract: "The reflections of microwaves from the walls of a plasma-containing vessel are studied. The probable cause of the reflections is discussed, and several suggestions are made for eliminating the reflections from the waveguide in the vessel and particularly from the pyrex vessel wall and copper tubing surrounding the pyrex. Quarter-wave-thick carbon-filled plastics or glasses having a very low vapor pressure room most promising when placed inside the pyrex cylinder. BaTiO3 appears to be an excellent material when placed outside the vacuum."

Abstract: "A theoretical criterion is given for the conditions under which the ions from an ion source may be decelerated by a decelerating grid, following the accelerating grid which extracts ions from the emitter, without causing a reduction in the current supplied by the source."

Abstract: "The valve-actuated pulse column is employed to give phase separation on each half cycle in the countercurrent flow cycle and provides independent control over each step in the cycle. The dependence on temperature of operation, on pulse frequency and amplitude, and on plate design and spacing has been studied for extraction and stripping of uranium with tributyl phosphate in a hydrocarbon diluent. It is found that the efficiency increases quite significantly as the temperature is raised regardless of the direction of transfer and this increased efficiency is accompanied by greater operational freedom. A decrease in hole size, decrease in plate separation and increase in frequency all lead to higher efficiency in agreement with the concept that small drops continually formed coalesced and reformed, lead to maximum interphase transfer. The high extraction efficiency of the column is probably aided further by the relatively sharp pulse produced."

Abstract: Beehive is a five energy group, two region, time independent spherical reactor code. It considers the problem of reactor system in which the core material is assumed to be at a higher energy (temperature) than the reflector material. The code obtains a closed solution for the critical reactor assembly by a procedure which is a logical extension of normal two group theory. The companion code, Hornet, computes the neutron fluxes for the critical assembly determined by the Beehive calculation. Both codes have been programmed for the IBM Magnetic Drum Data-Processing Machine, Type 650. The codes, together with the flow diagrams, are included with this report.

Abstract: "A radio-frequency ion accelerator is described which is capable of continuous currents of protons of 250 ma at an energy of 500 kev. The beam is less than 3 in. in diameter and has a divergence of less than 2 degree half angle. Operation of the machine accelerating deuterons to an energy of 1000 kev is also described."

Abstract: "The structure of an extremely strong magnetohydrodynamic shock is discussed in the limit of no particle collisions. It is tentatively concluded that the shock transition takes place through the mechanism of a strong electric field produced by charge separation. The pressure in the shocked plasma is due primarily to a very high electron temperature. The ions, on the other hand, undergo an irreversible temperature change of only 3."

This report presents the final results from the investigation of the ratio of Pu-239 fission cross section to U-235 fission cross section. Three sets of plutonium and uranium foils were prepared at KAPL and were investigated to acquire the final results.

Purpose: "The Hanford Works Analytical Manual for Process Water is designed to specify the analytical methods to be applied for control purposes in the Reactor Section, Process Sub-Section laboratories. The procedures are in general form and serve as references rather than outlined laboratory instructions. The manual us designed to replace the "Hanford Works Manual," HW-12862."