The macropore structure of chars is a major factor in determining their reactivity during the gasification stage. The major objectives of this contract were to (a) quantify by direct measurements the effect of pyrolysis conditions of the macropore structure, and (b) establish how the macropores affected the reactivity pattern, the ignition behavior and the fragmentation of the char particles during gasification in the regime of strong diffusional limitations. Results from this project provide much needed information on the factors that affect the quality of the solid products (chars) of coal utilization processes (for example, mild gasification processes). The reactivity data will also provide essential parameters for the optimal design of coal gasification processes. (VC)

The proposed retrofit coil is made of superconducting Cable-in-Conduit Conductor (CICC). The coils are designed to produce a nominal vertical field of 4.5 tesla within the MHD channel based on a nominal current density of 13.05 MA/m{sup 2}. The coils are supported within a case, or so-called constant tension strap. When the magnet is energized, the electromagnetic J {times} B body forces push the winding pack laterally outward and vertically towards the machine's midplane, thus putting the strap in tension. The end turns add axial tension to the conductor (a condition which is not simulated by this 2-D model of the midlength cross section). A sketch of the magnet system and structure is shown in Fig. 1.0-1. The purpose of this report is to describe the progress made in the design and analysis of the DC CICC retrofit magnet, and to outline the proposed next step.

This project seeks to develop a technique, based on coal surface properties, for highly dispersing catalysts in coal for gasification and to investigate the potential of using potassium carbonate and calcium acetate mixtures as catalysts for coal gasification. The lower cost and higher catalytic activity of the latter compound will produce economic benefits by reducing the amount of K{sub 2}CO{sub 3} required for high coal char reactivities. As was shown in previous reports, coal loading with potassium or calcium at different pHs produced CO{sub 2} gasification activities which increased in the order pH 6 > pH 10 {much gt} pH 1. The current report shows that a similar trend was obtained when calcium and potassium were simultaneously loaded and char reaction times were less than about 75 min. Beyond this time, the coal impregnated with catalyst at pH 1 became more reactive, reaching 100% conversion after 1.5h. X-ray diffraction analysis suggest that the catalysts are well dispersed around pH 1 and 6 whereas reduced dispersion as obtained at pH 10. The reactivities are independent of the surface areas of the coals.

None

Purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts (Cu) in either fixed-bed or fluid-bed reactors. Catalyst development and micro-packed bed screening studies are underway. Engineering support for pre-design on the miniplant is struggling with the unit operations problem associated with separation of products from unreacted methane.

None

This project seeks to develop a technique, based on coal surface properties, for highly dispersing catalysts in coal for gasification and to investigate the potential of using potassium carbonate and calcium acetate mixtures as catalysts for coal gasification. The lower cost and higher catalytic activity of the latter compound will produce economic benefits by reducing the amount of K{sub 2}CO{sub 3} required for high coal char reactivities. As was shown in previous reports, coal loading with potassium or calcium at different pHs produced CO{sub 2} gasification activities which increased in the order pH 6 > pH 10 {much_gt} pH 1. The current report shows that a similar trend was obtained when calcium and potassium were simultaneously loaded and char reaction times were less than about 75 min. Beyond this time, the coal impregnated with catalyst at pH 1 became more reactive, reaching 100% conversion after 1.5h. X-ray diffraction analysis suggest that the catalysts are well dispersed around pH 1 and 6 whereas reduced dispersion as obtained at pH 10. The reactivities are independent of the surface areas of the coals.

The macropore structure of chars is a major factor in determining their reactivity during the gasification stage. The major objectives of this contract were to (a) quantify by direct measurements the effect of pyrolysis conditions of the macropore structure, and (b) establish how the macropores affected the reactivity pattern, the ignition behavior and the fragmentation of the char particles during gasification in the regime of strong diffusional limitations. Results from this project provide much needed information on the factors that affect the quality of the solid products (chars) of coal utilization processes (for example, mild gasification processes). The reactivity data will also provide essential parameters for the optimal design of coal gasification processes. (VC)

The proposed retrofit coil is made of superconducting Cable-in-Conduit Conductor (CICC). The coils are designed to produce a nominal vertical field of 4.5 tesla within the MHD channel based on a nominal current density of 13.05 MA/m{sup 2}. The coils are supported within a case, or so-called constant tension strap. When the magnet is energized, the electromagnetic J {times} B body forces push the winding pack laterally outward and vertically towards the machine`s midplane, thus putting the strap in tension. The end turns add axial tension to the conductor (a condition which is not simulated by this 2-D model of the midlength cross section). A sketch of the magnet system and structure is shown in Fig. 1.0-1. The purpose of this report is to describe the progress made in the design and analysis of the DC CICC retrofit magnet, and to outline the proposed next step.

Purpose of this contract is to develop a process for converting light alkane gases to methyl chloride via oxyhydrochlorination using highly selective, stable catalysts (Cu) in either fixed-bed or fluid-bed reactors. Catalyst development and micro-packed bed screening studies are underway. Engineering support for pre-design on the miniplant is struggling with the unit operations problem associated with separation of products from unreacted methane.