This report covers an investigation made to develop a gasometric determination that can determine 1.2 x 10-(-5) g. of nitrite with a precision (99% limits) of +/- 8%, and discusses how this procedure works.

The following report is the third Quarterly Report in a series whose investigative purpose is to determine the extent to which zirconium and zirconium alloys exhibit delayed failure as caused by a combination of absorbed hydrogen and applied stress.

Abstract: A definitive investigation of the boron-carbon equilibrium system is being made by X-ray diffraction, metallographic, and thermal analytical techniques. On the basis of metallographic and X-ray diffraction studies it is concluded that boron carbide has a range of solubility from approximately 10 to 20 atomic per cent carbon at 1500 degrees to 2000 degrees Celsius. The melting point of the carbide-graphite eutectic has been established as 2325-2350 degrees Celsius. No reversible allotropy of the beta-rhombohedral structure has been observed. The solubility of carbon in boron is very small. The melting point of dilute carbon alloys is found to be essentially the same as that of pure boron (2040 degrees to 2050 degrees). No metallographic evidence of a three-phase reaction of dilute alloys is observed.

Abstract: "The niobium-carbon system has been determined by X-ray and metallographic examination of sintered and arc-cast alloys. Two carbides exist: hexagonal Nb2C with a limited range of homogeneity, and cubic NbC with a solubility range from 8.25 to 10.25 weight per cent carbon. Dilute alloys freeze by eutectic reaction at 2230 C. The solubility of carbon in niobium is 0.80 at the eutectic temperature, but this decreases rapidly with temperature. Metallographic evidence indicates a peritectic reaction between melt, Nb2C, and NbC; alloys richer in carbon than NbC freeze by eutectic reaction."

The following report is one of a series of quarterly reports following the progress and development of improved zirconium alloys for service in superheated water and steam. This report covers the period between January 1 to March 31, 1962 and was conducted by the United States and the European Atomic Energy Community (EURATOM). The major effort in this period has been devoted to ascertaining and evaluating corrosion behavior of 75 ternary compositions.

Introduction: Static, total immersion corrosion tests were carried out at room temperatures with Carboloy grades 44-A, 78, 907, X-3119-A and X-3119-B in Redox process solutions (ANL, June 1, 1949 Flowsheet) 1AX, 1AF, and 1AS.

From introduction: "At the request of WAPD, a study has been made of the effect of minor compositional variables on the corrosion behavior of uranium-molybdenum alloys in 650 F degassed water."

From statement of objectives: The purposes of the work described in this report are to provide data useful for designing and operating the dissolver solution clarification equipment to be installed in the Redox production plant.

The creep strength and tensile properties-were determined in vacuum for beta-quenched, derby uranium. The stresses to produce a secondary creep rate of- 0.0001 per cent per hr at 100, 250, 400, and 500 deg C were 48,000, sile strengths were 114,500, 35,100, 11,100, and 8,500 psi at temperatares of 28, 300, 500, and 700 deg C, respectively. The creep and tensile strengths decrease quite rapidly with increasing temperature in the temperatare range 250 to 400 deg C.

Abstract: An application of the magnetic mirror principle to the acceleration of a plasma is described. It is shown that an axially symmetric magnetic field which increases with time but decreases with distance along the axis can impart a net translational energy to a plasma. This effect on a plasma is contrasted with that arising from an impressed electric field, which is not effective in producing acceleration.

From page 2: "This article first describes the Bevatron [particle accelerator] and its operation, and then discusses a portion of the research program. The principles of the machine and its early history were given in "The Bevatron," by Lloyd Smith, Scientific American, February 1951."

Summary: "The low carbon 18-8 stainless steels containing approximately 1.7 per cent boron used for vertical safety rods at Hanford were found to be structurally stable in the temperature range 0-450 C. The addition of boron decreases the stability of this metastable austenitic alloy. Sufficient ferrite formation is induced by sub-zero temperature treatments to result in dimensional changes and a magnetic alloy. The difficulties encountered in machining this material are believed to be due primarily to segregation in the castings resulting in small areas of the hard intermetallic compound, FeB."

The following report demonstrates experimental verification of a method described in a previous paper--that involves measuring the dispersive microwave propagation coefficients simultaneously at several frequencies and comparing measured values with the values calculated for various distribution functions--and describes the procedure used to determine the distribution function in a sample laboratory plasma experiment.

This report describes the development and design of a large bakeable valve that is based on a unique seat arrangement and a novel motion seal.

The following report is a general monthly progress report for the University of California's radiation laboratory in Berkeley, covering the period of February 15 to March 15 of 1954.

Abstract: "Fabrication techniques for producing dispersion fuel elements with cores of 30 volume per cost of UC, U2Tl, U3Si, or U6Ni dispersed in Zircology 2 and 30 volume per cent of UC or UN dispersed in Type 18-8 stainless steel have been investigated. Roll-clad plate-type elements of all these compositions may be fabricated by powder-metallurgy methods in such a manner that good core-to-cladding bonds and cores with uniform dispersions of discrete uranium-composed particles are obtained. From the standpoint of fabricability, elements containing UC is Zircology 2, UC in stainless steel, and UN in stainless steel are the most promising. The UN in stainless steel has the best corrosion resistance in 680 F degassed water; however, UC in stainless steel has the best resistance to corrosion in 700 F NaK."

From introduction: This report summarizes a study of the composution and physical properties of a number of hydrocarbon diluents together with some generalizations regarding relations between [vapor pressure, density and viscosity] properties.

The following report describes the procedures developed for the x-ray photometric determination of uraniuim in metal oxides and sludge and compares results, precision, and length of time of analyses by the General Electric X-Ray Photometer with analyses by the present titration method.

This is a progress report on the carbonate process, compiled by the chemical development department of the Carbide and Carbon Chemicals Corporation's Y-12 plant, covering the month of September, 1949. In the previous month, the problem of immediate interest to the Monticello operation were listed. Projects that were left incomplete during that time were continued during this month, as well as a brief investigation of the process in which raw ore is leached with sodium carbonate, the sands and slime separated, the sands leached with acid, and the slimes roasted in a pellitized form.

The following report analyzes different values and measurements that give the same results for the captured cross section of thermal neutrons for Si.

Abstract: "An accurate calculation is given for the quantity which corresponds to the diffusion length in the theory of the pile. The procedure is to establish a relationship between the diffusion length and the change in thermal utilization from a pile with infinite sides to one with sides of a finite length. The calculation of this change in the thermal utilization is then carried through. Approximation to the answer and numerically exact calculations are given in the report. The results show that for radif very near the optimum values the exact diffusion length is slightly larger than the one obtained from the usual formula...However, over most of the range of radii the exact diffusion length is smaller than the approximate one."

"These notes are intended to serve as a summary of the current knowledge of properties of materials. In the future some need may exist for related information on methods od testing, design and fabrication. This issue presents information on thorium with subdivisions..."

The following report presents data from the investigations on discovering factors affecting the precipitation of tubanyl peroxide from Alpha and Beta gunk solutions at reduced temperatures.

Summary: "An apparatus is described which applies alternate pulses from two ion beams to a galvanometer network. The isotopic ratio is read directly from a potentiometer. The comparison is independent of ion beam intensity. This method is not practical for application to the standard Nier assay instrument because of the low ion currents normally used. It is suggested that this comparison method may have utility in a spectrometer utilizing a high intensity ion source such as capillary ore or condensed spark."