The 1,1-reductive elimination of ethane from three cis-bis(phosphine)-dimethylpalladium complexes, L/sub 2/Pd(CH/sub 3/)/sub 2/ (L = PPh/sub 3/, PPh/sub 2/,CH/sub 3/ and L/sub 2/ = Ph/sub 2/PCH/sub 2/CH/sub 2/PPh/sub 2/), and three trans analogs (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/ and L/sub 2/ = 2,11-bis(diphenylphosphinomethyl)benzo(c)phenanthrene (TRANSPHOS)) was carried out. The three cis complexes underwent reductive elimination in the presence of coordinating solvents (DMSO, DMF, and THF). The trans complexes which could isomerize to cis (L = PPh/sub 3/, PPh/sub 2/CH/sub 3/) did so in polar solvents and then underwent reductive elimination. TRANSPHOS dimethylpalladium would not undergo reductive elimination of ethane. The eliminations from the cis isomers were intramolecular and displayed first order kinetics. Although TRANSPHOS dimethylpalladium(II) would not undergo a 1,1-reductive elimination of ethane, the addition of CD/sub 3/I to a DMSO solution of this complex at 25/sup 0/C rapidly produced CD/sub 3/-CH/sub 3/, implicating a transient palladium(IV) intermediate. E- and Z-bromostyrylbis(diphenylmethylphosphine)palladium(0) react with methyl lithium in THF at ambient temperature to give the E- and Z- propenylbenzenes, respectively. At -78/sup 0/C, the intermediate E- and Z-styrylmethylbis(diphenylmethylphosphine)palladium(II) complexes (9a,b) can be isolated. On raising the temperature of solutions of 9a,b in THF, E- and Z-propenylbenzenes are produced. The reductive elimination …

Efforts have been primarily directed toward evaluation of the room temperature molten salt electrolyte in terms of its overall performance for photovoltaic cells. Mass transport processes may prove to be the rate-limiting factor for such electrolytes, unless the concentration of the photo-active redox component can be increased and the solvent viscosity reduced. Acid-base surface chemistry of n-GaAs as occurs in aqueous systems, has been found present and its consequences will be further explored. The selection and optimization of PEC electrolytes is a complex task and we believe that a systems approach would facilitate in identifying the basic electrolyte properties needed. A preliminary analysis reveals that although some of the criteria for an electrolyte are definable precisely, others do require empirical experimentation. It can be concluded that relatively few electrolytes in current use are adequate and it would appear that greater efforts to develop electrolytes would be advantageous. The various types of electrolytes that could be used for PEC's have been identified. Good quality MoSe/sub 2/ single crystals can be grown and short circuit currents greater than previously reported have been achieved in an I/sub 2//I/sup -//Pt cell. A novel technique to produce photo-active films by anodization is being investigated, initially …

Polycrystalline silicon films 14-22 ..mu..m thick and with average grain diameters of 20-40 ..mu..m were deposited by vacuum deposition onto both ceramic and sapphire substrates which were previously coated with a thin (1-2 ..mu..m) TiB/sub 2/ conducting layer. The large grains are the result of an interaction in the initial growth stages between silicon and TiB/sub 2/. SIMS studies of B/Ti/Al/sub 2/O/sub 3/, B/Al/sub 2/O/sub 3/, and Ti/Al/sub 2/O/sub 3/, interactions are reported as part of a continuing investigation of TiB/sub 2/ formation and silicon interactions on the TiB/sub 2/ surface. The increase in grain size has led to an improvement in the open-circuit voltage V/sub oc/, but not to an increase in the short-circuit current J/sub sc/. Capacitance-voltage measurements give results characteristic of an abrupt junction and a build-in voltage V/sub D/ consistent with the measured doping levels. A simple method for measuring the minority carrier diffusion length in the base region L/sub n/ is described. The measurements indicate that there is little change in L/sub n/ between large (20-40 ..mu..m) and small (approx. 5 ..mu..m) grained samples.

The potential for solr process heat applications for federal buildings in Texas is assessed. The three sites considered are Reese Air Force Base, Lubbock; Fort Bliss, El Paso; and Dyess Air Force Base, Abilene. The application at Lubbock is an electroplating and descaling facility for aircraft maintenance. The one at El Paso is a laundry facility. The Abilene system would use solar heat to preheat boiler feedwater makeup for the base hospital boiler plant. The Lubbock site is found to be the most appropriate one for a demonstration plant, with the Abilene site as an alternate. The processes at each site are described. A preliminary evaluation of the potential contribution by solar energy to the electroplating facility at Reese AFB is included. (LEW)

The Applied Physics Laboratory/Department of Energy Low Cost Flywheel Demonstration Program was initiated on 1 October 1977 and was successfully concluded on 31 December 19'9. The total cost of this program was $355,190. All primary objectives were successfully achieved as follows: demonstration of a full-size, 1)kWh flywheel having an estimated cost in large-volume production of approximately $50/kWh; developmeNt of a ball-bearing system having losses comparable to the losses in a totally magnetic suspension system; successful and repeated demonstration of the low-cost flywheel in a complete flywheel energy-storage system based on the use of ordinary house voltage and frequency; and application of the experience gained in the hardware program to project the system design into a complete, full-scale, 30-kWh home-type flywheel energy-storage system.

A careful study of a specially formed thin silicon layer on TiB/sub 2/-coated sapphire reveals that the interaction layer of TiSi/sub 2/ is composed of larger grains. Processing steps were developed which lead closer to the goal of fabricating polycrystalline silicon photovoltaic devices completely by vacuum deposition. Both n-type and p-type silicon are now being deposited. New deposition masks were made for depositing the n-regions upon the p-layers. New electrode deposition masks were also made for a direct electroding process to replace the photolithographic process used previously. The TiB/sub 2/ bottom electrode fabrication has been achieved in a single vacuum chamber. Reaction constants and activation energy for TiB/sub 2/ layer formation were determined to be less than those reported by other authors for bulk material. Studies of crystallite growth and interfacial interactions have continued. Major sources of undesirable impurities have been identified and removed from the vacuum chambers. The changes made this quarter have not been incorporated into a completed photovoltaic device.

The Sunkist Citrus Plant in Ontario, California, processes about 6 million pounds of citrus fruit per day to make products which include frozen concentrated juice; chilled, pasteurized, natural strength juice; molasses from peel; dried meal from peel; pectin; citrus oil; and bioflavonoids. The energy intensive operations at the plant include concentration, drying, and refrigeration. The objective of the two-year two-phase project is to identify an economically viable alternative to the existing method of meeting energy requirements. Progress on the technical work of Phase I is reported. The following are summarized: requirements (energy price projection, atmospheric emission requirements, citrus juice quality constraints, economic evaluations); characterization (basic citrus processing operations, energy consumption and fruit processed vs time, identification and measurement of energy uses, energy balance for a typical citrus juice evaporator); and thermodynamic analysis (heat pump model, thermal evaporator, and co-generation model).

Polycrystalline p-type films were vacuum deposited onto TiB/sub 2/ coated alumina and sapphire substrates. Epitaxial layers were also formed on single crystal silicon substrates. Junctions in the layers were created by both gaseous diffusion in a tube furnace and by vacuum deposition. The TiB/sub 2/ vacuum deposited bottom electrodes have resistivities between 30 and 40 ..mu.. ..cap omega..-cm. All-vacuum-deposited solar cells were fabricated for the first time. Efficiencies approaching those in the diffused junction devices were achieved. The n-layers were deposited on the previously deposited p-layer/TiB/sub 2//ceramic sandwiches by vacuum deposition of silicon in a phosphine (PH/sub 3/) atmosphere. Photovoltaic data in diffused junction samples, including efficiency and spectral response measurements, indicate that crystallite size may no longer be the limiting factor in achieving high efficiency; rather, performance is now being limited by the presence of impurities in the vacuum deposition silicon base region.

Chemical compositions of chlorite and sericite from one production well in the Roosevelt geothermal system have been determined by electron probe methods and compared with compositions of chlorite and sericite from porphyry copper deposits. Modern system sericite and chlorite occur over a depth interval of 2 km and a temperature interval of 250/sup 0/C.

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Results obtained from a program designed to locate a low- or moderate-temperature geothermal resource that might exist beneath Hill Air Force Base (AFB), Ogden, Utah are discussed. A phased exploration program was conducted at Hill AFB. Published geological, geochemical, and geophysical reports on the area were examined, regional exploration was conducted, and two thermal gradient holes were drilled. This program demonstrated that thermal waters are not present in the shallow subsurface at this site. (MHR)

A technical evaluation was made to determine whether geothermal energy obtained from a well could be used to space heat the new school building being constructed as well as the existing elementary wing of the Pittsville School. The first part deals with space heating the new school building only; the second part pertains to space heating the new school building together with the new existing wing. An addendum was added for new well and production pump costs. (MHR)

The purpose of this handbook is to assist in understanding the various procedures and requirements necessary for the development of geothermal energy in the State of Arizona. It contains the names of key persons and agencies who are directly or indirectly involved in the institutional process. A detailed assessment of all agencies and the role they play in geothermal energy development is provided. The handbook is divided into four sections: State and Local rules and regulations, the Federal rules and regulations, references, and a technical bibliography. (MHR)

The Applied Physics Laboratory/Department of Energy Low Cost Flywheel Demonstration Program was initiated on 1 October 1977 and was successfully concluded on 31 December 1979. The total cost of this program was $355,190. All primary objectives were successfully achieved as follows: demonstration of a full-size, 1-kWh flywheel having an estimated cost in large-volume production of approximately $50/kWh; development of a ball-bearing system having losses comparable to the losses in a totally magnetic suspension system; successful and repeated demonstration of the low-cost flywheel in a complete flywheel energy-storage system based on the use of ordinary house voltage and frequency; and application of the experience gained in the hardware program to project the system design into a complete, full-scale, 30-kWh home-type flywheel energy-storage system.

Comparisons between leveling surveys of different epochs are used to determine vertical displacement of permanent bench marks. Displacement of bench marks usually represents the movement of the surrounding area. In this report, the 1978 Houston-Galveston and Texas Gulf Coast releveling surveys are compared to the 1963, 1973, and 1976 releveling results. The changes in elevations of bench marks common to two or more epochs are tabulated and plotted in Appendix A. From these differences, contour maps were prepared for the 1963 to 1978 and 1973 to 1978 epochs in the 2/sup 0/ x 2/sup 0/ area of maximum subsidence. Annual subsidence rates computed for the 1973 to 1978 period are about 25% less in the maximum subsidence area than the rates computed for the 1963 to 1973 period.

The Johns Hopkins University Applied Physics Laboratory, is engaged in developing energy resource, utilization concepts, and monitoring and storage methods. This Quarterly Report summarizes the work on the various tasks as of 31 March 1980. The Energy Quarterly Report is divided into four sections. The first, Geothermal Energy Development Planning and Technical Assistance, contains reports on the progress of geothermal-related tasks on which effort was concentrated during the quarter. The second section, Operational Research, Hydroelectric Power Development, contains reports on small-scale hydroelectric investigations in the southeastern states. The third section, Seismotectonic Investigation, reports on a neotectonic investigation in Connecticut. The fourth section, Energy Conversion and Storage Techniques, contains two articles, the first on OTEC core unit testing supported by the Department of Energy/Division of Central Solar Technology (DOE/CST), and the second on an analysis of the Community Annual Storage Energy System at the US Naval Air Station, Norfolk, Va.

A compilation of data relating to geothermal energy in each of the 50 states is presented. The data are summarized on one page for each state. All summary data sheets use a common format. Following the summary data sheet there are additional data on the geology of each state pertaining to possible hydrothermal/geothermal resources. Also there is a list of some of the reports available pertaining to the state and state energy contacts. The intent of these documents is to present in a concise form reference data for planning by the Department of Energy.

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The Johns Hopkins University Applied Physics Laboratory, under contracts with several agencies of the federal government and an agency of the State of Maryland, is engaged in developing energy resources, utilization concepts, and monitoring and storage methods. This Quarterly Report summarizes the work on the various tasks as of 30 June 1980. The Energy Quarterly Report is divided into three sections. The first, Geothermal Energy Development Planning and Technical Assistance, supported by the Department of Energy/Division of Geothermal Energy (DOE/DGE), contains reports on the progress of geothermal-related tasks on which effort was concentrated during the quarter. The second section, Operational Research, Hydroelectric Power Development, supported by the Department of Energy/Resource Applications (DOE/RA), contains reports on small-scale hydroelectric investigations in the southeastern states. The third section, Energy Conversion and Storage Techniques, contains three articles. The first is on data analysis of OTEC core unit condenser tests, and is supported by the Department of Energy/Division of Central Solar Technology (DOE/CST). The second is on the current status of the Community Annual Storage Energy System at the U.S. Naval Air Station, Norfolk, Va., and is supported by the Department of Energy and the Department of Defense, Naval Facilities Engineering Command/Atlantic Division. The third …

This report contains preprints of papers pertaining to geothermal energy development in the Eastern United States written by members of the Center for Metropolitan Planning and Research (Metro Center) and by the Applied Physics Laboratory (APL) both of The Johns Hopkins University.

The Johns Hopkins University Applied Physics Laboratory, under contracts with several agencies of the federal government, is engaged in developing energy resources, utilization concepts, and monitoring and storage methods. This Quarterly Report summarizes the work on the various tasks as of 31 September 1980. The Energy Quarterly Report is divided into four sections. The first, Geothermal Energy Development Planning and Technical Assistance, supported by the Department of Energy/Division of Geothermal Energy (DOE/DGE), contains reports on the progress of geothermal-related tasks on which effort was concentrated during the quarter. The second section, Operational Research, Hydroelectric Power Development, supported by the Department of Energy/Resource Applications (DOE/RA), contains reports on small-scale hydroelectric investigations in the southeastern states. The third section, Seismotectonic Investigations, supported by the Reactor Safety Research Division of the Nuclear Regulatory Commission (NRC), reports on neotectonic investigations of the Manhattan Prong. The fourth section, Energy Conversion and Storage Techniques, contains three articles. The first is an evaluation of the Einstein refrigerator, supported by independent IR&D funds. The second concerns OTEC pilot plant performance calculations, supported by the Department of Energy/Division of Central Solar Technology (DOE/CST). The third, describing a study of landfill methane recovery, is supported by the National Park Service.

The Johns Hopkins University Applied Physics Laboratory, under contracts with several agencies of the federal government and an agency of the State of Maryland, is engaged in developing energy resources, utilization concepts, and monitoring and storage methods. This Quarterly Report summarizes the work on the various tasks as of 31 March 1980. The Energy Quarterly Report is divided into four sections. The first, Geothermal Energy Development Planning and Technical Assistance, supported by the Department of Energy/Division of Geothermal Energy (DOE/DGE), contains reports on the progress of geothermal-related tasks on which effort was concentrated during the quarter. The second section, Operational Research, Hydroelectric Power Development, supported by the Department of Energy/Resource Applications (DOE/DGE), contains reports on small-scale hydroelectric investigations in the southeastern states. The third section, Seismotectonic Investigation, supported by the Reactor Safety Research Division of the Nuclear Regulatory Commission, reports on a neotectonic investigation in Connecticut. The fourth section, Energy Conversion and Storage Techniques, contains two articles, the first on OTEC core unit testing supported by the Department of Energy/Division of Central Solar Technology (DOE/CST), and the second on an analysis of the Community Annual Storage Energy System at the U.S. Naval Air Station, Norfolk, Va. This work is supported …

Phytoplankton activity in an oligotrophic environment was studied on six cruises over a 14-month period. Phytoplankton biomass and productivity displayed considerable temporal variability despite the relative constancy of the physical and chemical environment. No evidence of seasonality or diurnal variability in phytoplankton biomass was observed. Annual average (+ s.d.) depth-integrated values (0-260 m) for chlorophyll a, phaeopigment, ATP, and primary productivity were 24.55 + 10.31 mg {center_dot} m{sup -2}, 11.81 + 7.20 mg {center_dot} m{sup -2}, 3.00 + 1.78 mg {center_dot} m{sup -2}, and 8.79 + 7.82 mg C {center_dot} m{sup -2}, h{sup -1}, respectively; over the year these parameters were seen to vary over ranges of 3X, 6X, 10X, and 26X, respectively. The mean depths of the chlorophyll and phaeopigment maxima were 85 + 9 m and 95 + 11 m, respectively; the pheopigment maximum was always located at or below that of chlorophyll. Size fractionation studies showed that at this oceanic station about 80% of the phytoplankton biomass occurred in the < 5 {micro}m fraction. Low ambient nutrient levels were typical at the depth of the chlorophyll maximum, indicating that nutrient assimilation was actively occurring in that layer. Elevated nutrient levels were typical at the deeper phaeopigment maximum …

Characteristics of the oceanic mixed layer over the North Pacific were examined utilizing a number of statistical methods. Based on the analyses of twelve years of data, a quasi-meridional differentiation (QMD) in sea surface temperature (SST) spectra across the North Pacific was observed. The SST spectra became increasingly red as an increasing function of latitude. A strong 21 to 26 day cycle in SST anomalies is discussed which may be a reflection of heat fluxes. These fluxes also vacillate significantly on this time-scale in conjunction with cycles observed in the atmospheric energy modes of available potential and kinetic energy. Examination of an oceanic heat budget on a spatial and temporal basis suggest that the impact of latent and sensible heat fluxes upon ..delta..SST is partially a function of the magnitude of the heat fluxes as well as of the depth to which their effects are mixed. The heat budget analyses and the fitting of power spectra of SST anomalies over the North Pacific to a two-parameter oceanic model, suggest that SST behavior over the mid-oceanic regions of the North Pacific is dominated by the influence of latent and sensible heat fluxes. On the other hand, over the remainder of the …