The enthalpies and heat capacities of seventeen fluoride mixtures in the liquid state have been determined using Bunsen Ice Calorimeters and copper block calorimeters. The fluoride mixtures were composed of the fluorides of two or more of the following metals: lithium, sodium, potassium, beryllium, zirconium, and uranium. The enthalpies and heat capacities of most of these mixtures were studied in the solid state also. Estimates of the heat of fusion have been made. General empirical equations have been developed which represent the enthalpies and heat capacities of the fluoride mixtures in the liquid and in the solid state.

A new gas-liquid countercurrent system (the ANCO system from Anisole-Complex) for the enrichment of boron isotopes has been developed. It is believed that use of this systems will result in a considerably lower unit cost for enriched boron-10 than was previously possible. The system utilizes the exchange reaction between BF3 (gas) and BF3·anisole (liquid) to concentrate boron-10 in the liquid phase. The single stage isotopic separation factor for this system has been found to vary from 1.039 at 0°C to 1.029 at 30°C. The isotopic exchange reaction has been shown to be rapid. Vapor pressures of the complex as a function of temperature have been measured and the heat of formation of the complex determined. Laboratory experiments show that quantitative removal of the BF3 from the complex can be accomplished by heating. A complete miniature ANCO plant was constructed and operated in the laboratory to test the feasibility of the system. The system was found to operate efficiently with a minimum of attention, and to enrich the isotopes of boron as expected. Based upon the experience obtained with the laboratory ANCO unit, a pilot plant large enough to utilize a 6-inch diameter exchange column was designed. The design calculations of …

An order of magnitude estimate was made to determine a minimum cost for 10% pure oxygen-17 when produced by a chemical exchange process. the calculations were based on separations factors of 1.03, 1.01, and 1.003. the cost of product was found to vary from $23 per gram for the large factor to $165 per gram for the smaller.

The dose of ionizing radiation received by passengers and crew members traveling on commercial airlines which transport radioisotopes is of interest to all persons who travel the airways frequently. Tariff regulations permit the air transport of 40 units of radioactive materials where one unit represents a quantity of radioisotopes which when packaged delivers a dose rate of one mr/hr at a distance of one meter from the center of the package. Using five different types of commercial aircraft, shipments of radioisotopes were simulated and dose levels determined at various locations in the aircraft under conditions normal to commercial travel. The survey indicates that the tariff regulations should be amended giving consideration to the type of aircraft involved.

This technical report described the formulation of a set of two-group neutron diffusion equations and the solution for the critical fuel cross section in a one-dimensional, multi-region spherical reactor. A subsequent report will describe the ORACLE code developed for survey calculations using this method.

The general Wigner-Eisenbud theory is used to develop a method of analysis for the cross sections of fissionable nuclei. The method is employed in giving a reasonable description of the low energy cross sections in U/sup 235/. The single level fit for U/sup 235/ is known to be unreasonable. Many level expressions for the cross sections are derived--the only approximation to the general theory being the neglect of all but a small group of resonances. It is shown that regardless of the number or definition of the fission channels the many-level expressions require few level parameters: the E/sub lambda /, GAMMA / sub lambda n/, GAMMA /sub lambda gamma / and GAMMA /sub lambda F/ of the single level theory for each resonance and a few additional parameters pertinent to the interference between levels. The interference terms are described and shown to be important. The shape and size of the U/sup 235/ cross sections below 2 ev are fitied to within one per cent using (a) only one negative energy resonance of smaller size than in the single level fits (b) no additional levels to fit the shape other than the observed levels at positive energies (c) three interference parameters …

To better understand the solvent extraction process much effort has been and is being expended at ORNL and elsewhere to measure reaction kinetics of the extraction reactions. To date these efforts have been largely unsuccessful, due to the attempt to apply homogeneous reaction kinetics to two-phase systems. An optical method has been devised for analyzing the concentration profile in the vicinity of a quiescent interface during steady-state diffusion at rather large molecular fluxes. The system under study is the extraction of uranyl ion from water by a TBP solution. Considerable effort has been directed to eliminating leaks in the diffusion cell and testing the optical system/

In order to make rational predictions of the operating characteristics of uranium anion exchange contactors, an understanding of the mechanism and kinetics of the exchange is necessary. Toward this objective an effort is being made to determine the equilibrium sorption isotherms and rates of sorption of uranium on the anion exchange resin Dovex 21K.

In order to make rational predictions of the operating characteristics of uranium anion exchange contactors, an understanding of the mechanism and kinetics of the exchange is necessary. Toward this objective an effort is being made to determine the equilibrium sorption isotherms and rates of sorption of uranium on the anion exchange resin Dovex 21K.

In a discussion about design of cyclotron resonators, the suggestion has been made that a wide range variable-frequency system might be constructed with two coupled resonant circuits. It also would present the possibility of tuning without the switching of high-current contacts, a troublesome item now commonly used for cyclotrons. One of the circuits would be the dee and its stem which might, or might not, be tuned. The second circuit could be located out of the magnet gap in a region where more space is usually available. Tuning could be accomplished by variation of the coupling between the two circuits and/or by, say, variable capacitance of the tuned, or tunable, circuit.

The attached paper is a translation of a rough draft of the paper, "Operating Experience of the APS-1", presented by M. Minashin in Russian at the IAEA Conference on Small and Medium Power Reactors, Vienna, Austria, September 5-9, 1960.