"lsotope dilution techniques are described for the assay of chlorinated hydrocarbon pesticides and organic phosphorus pesticides in foods. Results are given for the determination of tetranitro-DDT-dianilide, dianilide of tetranitro- DDE, dieldrin, systox, and derivatives of these compounds. "

"As presented in the original proposal the project consisted essentially of three parts: Phase I, Development and refinement of a radiochemical flow counting technique for the study of kinetics of reactions in solution ; Phase II, The application of this technique to the detailed study of the mechanism of solvolysis of sulfonium salts in mixed solvents ; Phase II, The further application of this kinetic technique, as a longer term aim, to other reacting systems of biochemical or other interest. This report covers the work of the contractual period 1 Sept. 1959 to 31 Aug. 1960."

"The factors of atomic size, ion core potential, and charge, which contribute to the increment in electrical resistivity produced by solutes in metallic solutions, were separated and experimentally evaluated in liquid sodium. The results are expressed in a semi-empirical relationship which defines the increment in resistivity of a monovalent solution as the sum of the fractional difference in atomic volume of solute and solvent and the difference in atomic number of Na and the solutes Li, K, Cs, Rb, Ag, and Au."

"A finite difference approximation to a non-linear set of parabolic differential equations arising in shallow water theory is given. These difference equations were used to determine the shape and rate of propagation of a hum of fluid down a channel of constant depth. The hump of fluid was found to spread instead of steepen, as is the case in the usual shallow water theory."

"One of the fundamental concepts of macroscopic physics is that of a homogeneous system. The state of such a system is completely described by a set of intensive parameters which make no reference at all to the size or shape of the system, and by the total number of particles, N (unless otherwise specified we deal with one-component fluid). In actual systems, there are always inhomogeneities due to boundaries and to gravitational body forces."

"A brief examination of the post irradiation grafting of machine irradiated polyethylene film with acrylic acid monomer was made. Evidence of postgrafting was detected in samples that had been irradiated to a total dose of 10 Mrads at a dose rate of 0.01 Mrad/sec. and then exposed to a 25% purified acrylic acid solution in benzene for periods of 1 to 4 days."

"Rates of acetylene polymerization induced by Kr/sup 85/ in d-c fields were up to 15 times greater than those observed when no fields were imposed. Work to determine the relations between acetylene pressure, Kr/sup 85/ concentration, and the field intensity is continuing. In other activities, equipment is being designed to study the effects of megacycle electric fields on radioinduced chemical reactions."

"The problems of sequencing jobs through machines are discussed in a linear graph framework. The construction of feasible schedules from given technological orderings is related to the construction of transitive graphs from given component graphs. Methods of constructing transitive graphs are given and bounds on the number of different transitive graphs constructed from given components are determined. A recursive convex function defined on the transitive graphs-the job operation completion time and schedule time-is studied. Bounds on the number of different values that the schedule time can attain is obtained. Examples of multiprogramming, flow shop and machine shop scheduling are studied."

""Progress is reported on: design of a continuous flow system for the irradiation of silane using a Cos5 source; pile irradiation of silane samples at elevated temperatures; investigation of materials other than silane, including nonsilicon compounds as well as those containing the silyl group; modification of the existing vacuum system for handling larger quantities of silane as well as increasing the accuracy of the pressure measurements; and use of an electric discharge for the decomposition of silane. Studies were continued on the radiation- and thermalinduced decomposition of sikane at 325 and 350 deg C. A preliminary value of G= 33 was obtained for silane."

"Progress is reported on: design of a continuous flow system for the irradiation of silane using a Cos5 source; pile irradiation of silane samples at elevated temperatures; investigation of materials other than silane, including nonsilicon compounds as well as those containing the silyl group; modification of the existing vacuum system for handling larger quantities of silane as well as increasing the accuracy of the pressure measurements; and use of an electric discharge for the decomposition of silane. The work performed during the period of this report consisted of the following: 1. Preparation of samples of trichlorosilane and hydrogen and subsequent thermal and irradiation studies, and analysis of these samples. 2. Preparation of mixed samples of silane and argon and subsequent thermal and irradiation studies and and analysis. 3. Outlining of future investigations to be conducted on this project."