Metallurgical Laboratory, Chemical Research - Radiation Chemistry, Report for the Month Ending May 15, 1943 (open access)

Metallurgical Laboratory, Chemical Research - Radiation Chemistry, Report for the Month Ending May 15, 1943

Technical report that information has bee obtained on the effect of beta and gamma radiation on the electrical resistance of insulating materials The results are summarized. The recovery to original resistance values has been measured. In general, the initial rate is rapid for the first few hours; the rate then decreases sharply. Certain samples show evidence of complete recovery. Effects on mechanical properties of several plastics has also been studied. Data on gas evolution from several organic materials including those suggested by the physiological shield have been extended to include both beta and deuteron bombardments. Samples of "Press-wood" are being evaluated. The effect of current on the H2O2 production in water containing I- has been studied at several I- concentrations. Water contain-dissolved CO2 shows the presence of oxidant (presumably H2O2). H2O2 has been produced by recoil protons from the scattering of fast neutrons in de-oxygenated water. Radioactive solutions do not greatly affect the applicability the glass electrode providing the electrode is thoroughly washed with distilled water before immersion in the standard buffer solution.
Date: May 15, 1943
Creator: Franck, J.
System: The UNT Digital Library
Chemical Research -- U233 Production and Extraction; Report for the Month Ending June 21, 1943 (open access)

Chemical Research -- U233 Production and Extraction; Report for the Month Ending June 21, 1943

Abstract. The precipitation of Pa233 with MnO2 from a solution of thorium nitrate has been studied in some detail and seems quite satisfactory up to 36 gm Th(HO3)4 4H2O per 100 cc solution. The concentration of Pa233 with respect to the manganese dioxide carrier and the thorium precipitated with the carrier appears to be accomplished quite well by either a series of MnO2 cycles or thorium iodate cycles. Volatility methods for both the separation of Pa233 from the original thorium and for its separation from MnO2 are now under investigation. It has been decided that thorium carbonate will the the thorium compound used in the pile at Site X.
Date: June 21, 1943
Creator: Franck, J.
System: The UNT Digital Library
Metallurgical Laboratory, Chemical Research - Radiation Chemistry, Errara for CC-918 (open access)

Metallurgical Laboratory, Chemical Research - Radiation Chemistry, Errara for CC-918

Technical report listing the errata for pages 2, 4, 5, 6, 7, and 8 for report CC-918.
Date: October 16, 1943
Creator: Franck, J.
System: The UNT Digital Library
Metallurgical Laboratory, Chemical Research - Analytical, Graphite Purity Research Program (open access)

Metallurgical Laboratory, Chemical Research - Analytical, Graphite Purity Research Program

Abstract. Chemical analytical studies of graphite raw materials have revealed new sources of petroleum cokes and pitches of greater purity than those previously used in the manufacture of project graphite. The use of these raw materials of exceptional purity has resulted in an improvement in k of the order of one per cent as compared with the AGOT-AGNT graphite typical of the previous production. A study of the graphitizing process has shown that no dangerous impurities are introduced in the graphite in manufacture; rather, the process actually purifies. furthermore, impurities are distributed homogeneously within the furnace charge; thus the AGOT-AGNT distinction is no longer necessary. A comparison of the methods of graphite testing has demonstrated excellent correlations between chemical analytical data, the results of the function test at Argonne, and the sigma pile experiments. It may therefore be inferred that chemical testing should be an adequate control of the graphite purity. Methods are described for the analysis of ash, B, V, TI, FE, and Ca in petroleum coke, pitch, and graphite.
Date: December 22, 1943
Creator: Boyd, G. E.; Curtis, R. E. & Johnston, W. H.
System: The UNT Digital Library
Studies on the Determination of Carbon by the Low Pressure Combustion Method (open access)

Studies on the Determination of Carbon by the Low Pressure Combustion Method

Technical report: The apparatus for the low pressure combustion method of determining carbon in iron and steel has be redesigned to increase the speed of manipulation. It has been tested by running several thousand determinations and found to yield results in good agreement with Wooten's form of the apparatus. A detailed description of the equipment and its manipulation is given together with an account of experimental studies on the method. Results are also shown for the carbon content of copper.
Date: October 20, 1943
Creator: Murray, W M., Jr. & Ashley, S E. Q.
System: The UNT Digital Library