An improved method for the determination of boron in plutonium is reported. Precipitation of plutonium (III) acid oxalate prior to color development with curcumin results in increased precision, greater speed, and lower costs. Results are presented of a statistical study involving all variables.

Abstract: The most adverse power distribution and power peaking factors have been developed for Type 3 replacement cores for SM-1, SM-1A, and PM-2A. Also included is the 37 element Type 3 core for SM-1, which is known as SM-1 Core III and is a prototype of a Type 3 core for PM-2A. The power distributions were compared with measured distributions obtained on type 3 fuel elements in SM-1, SM-1A and PM-2A core configurations. Using the measured data as a standard, correction factors were obtained and applied to the analytical predictions of the most adverse power distribution.

Abstract: Progress is reported on research and development tasks under the Program Plan for Engineering Support and Development of Army Pressurized Water Reactor Power Plants, Contract AT(30-1)-2639, during the six months' period October 1, 1061 to March 31, 1962.

This technical report discusses an infrared study of AlH3-2N(CH3)3 while the compound was in its gas phase. This investigation was then extended to include the Raman spectrum observed in liquid trimethylamine.

Abstract: An analysis and a summary are.given of the radioactivity buildup program at the Army Package Power Reactor during the last nine months. · Due to the wide fluctuation of water and crud results, only general interpretations can be made with this data. Metal test coupon data indicate a substantially greater buildup on Croloy 16-1 metal than on Type 304 stainless steel. Coupled with the decreased ability to remove the radioactivity buildup on Croloy 16-1 by conventional descaling techniques, the implication is that this metal might pose a serious problem for use as steam generator material. It was emphasized, however, that results to date ae only preliminary and extensive additional experimentation would be required to reach more definite conclusions.

Introduction: Seldom does the actual arrangement of control elements in a nuclear reactor confers to the ideal and convenient mathematical array. In order to achieve shim control. safety and regulation, it is desirable to design with rods of different sizes and materials. With given fuel element arrangement, typically in square or hexagonal lattice spacing, there will be rods located at different distances form the center of the core and from each other. As the reactor operates, absorbers will be withdrawn, leaving further asymmetries in the location of those remaining. It is the purpose of this report to develop in detail a two-group diffusion theory with as complete generality as possible. The method is as yet restricted to the unreflected core, or to the reflected core by use of reflector savings and bare equivalent geometries.

Summary: Prototype testing of the safety and control rod drives indicated that both units functioned properly. No major problems were encountered during testing. Seal leakage data collected indicated that the seal units were performing satisfactorily. Scram times during both cold and hot testing were excellent and actually better than expected.

Cowley's measurements of the short-range order parameters, αi, in Cu3Au at T=405°C have been re-evaluated taking into account the effects of thermal vibrations and static displacements due to differing atomic sizes. The separate corrections for the thermal vibrations and the first-neighbor atomic size factor are found to be quite large, demonstrating their importance in the usual experiments. When combined, the corrections in this case largely cancel, and only the values of α1 and α3 are appreciably changed. The corrected values are: α1= -.113, α2= +.185, α3= -.009, α4= +.082, α5= -.058.

An isochronal differential-type microcalorimeter has been designed and constructed. As a result of its simple design it is very easy to handle the samples and assemble the calorimeter. Important to the operation of the calorimeter is a program, also working on the differential principle, that provides linear temperature rise of the samples. This calorimeter is used to measure very small energy releases such as those found in precipitation, stored energy, etc. It is demonstrated that the calorimeter is easily capable of measuring 0.0005 cal with a probable error of the order of 1% to 2%.

The rf particle separator, proposed in 1959 by W.K.H. Panofsky and now in preparation for the Brookhaven Alternating Gradient Synchrotron, required a rf structure which gives a transverse impulse to a passing relativistic particle. In order to produce an accumulative transverse deflection of a traveling charged particle with an electromagnetic field, it is necessary that the field contains a synchronous component and in principle, waveguides and cavities are equivalent with respect to the particle dynamics. It was pointed out by H.G. Hereward, that the electric and magnetic deflection of a transverse electric mode (i.e., with no electric field component parallel to the direction of the particle velocity) cancel exactly at all particle velocities. The deflecting force of a transverse magnetic mode on a synchronous particle with the velocity v is proportional to the factor 1-(v/c)2 and vanishes therefore in the case of relativistic particles.

The purpose of this paper is to present tables of the perturbed wave functions which have been recently obtained in a calculation of the quadruple antishielding factors γ∞ for the Mn+2, Fe+3, Ga+3, and Ag+ ions. The wave functions v'1(nℓ-ℓ) which are tabulated represent the effect of the perturbation due to a nuclear quadruple moment Q on the wave functions of the outermost electrons of the ion core.

The enzymolysis by α-chymotrypsin of the substrates, N-acetyl-L-tryptophane ethyl ester and N-acetyl-L-tyrosine ethyl ester, was followed by means of fluorescence whose intensity increased fourfold and threefold per mole respectively as substrate was transformed into amino acid. The assay by fluorescence was several orders of magnitude more sensitive than the assay by differential absorption spectra of these substances and was in agreement with it in those concentration regions where both methods overlap. To maintain linearity between concentration and fluorescence intensity, the concentration of substrate should be no greater than 10-4 M/1. In such solutions the rate of esterolysis could be followed with the enzyme at 10-11 M/1.

A modification of the specimen support for the Norelco diffractometer permits X-ray diffraction studies to be made of specimens prepared for metallographic examination. The unit has been successfully used to identify phases present in specimens of plutonium-uranium alloys.

The oscillator of the 88-in. cyclotron which is being built in Berkeley is tunable from 5.3 to 16.5 Mc. It delivers a maximum c-w power of 300 kw. At the rated doc voltage of 75 kv the resonator stores 4.5 joules of electrical energy. The transients produced by this amount of energy, during sparking, place unusual requirements upon the design of the oscillator tube. The features of the RCA 6949 which make it particularly well-suited to this type of application are discussed in this paper. Other topics covered are the oscillator anode power supply, the hard-tube modulator, protective equipment, and oscillator instrumentation.

Strubl's polarographic method for the determination of uranium in the presence of iron can be used for the determination of uranium in plutonium solutions. A hydroxylamine hydrochloride solution (2M) is used as the supporting electrolyte. This reduces the plutonium to the plus three oxidation state without reducing the uranium. The uranium may then be determined polarographically by measuring the height of the uranyl reduction wave (UVI to UV) at -0.35 volts (vs. S.C.E.) applied potential. Solutions with a U/Pu weight ratio as low as 3.5 x 10(-3) were analyzed with an error of less than 2%. This error increased to 6% for solutions of 1 x 10(-3) U/Pu ration and is considerably larger for smaller U/Pu ratios.

This technical report describes a plant-scale procedure for concentrating plutonium and americium in slag and crucible (metal reduction residues) and other recovery solutions by a calcium oxalate carrier precipitation Conclusions from exploratory laboratory tests on the variables affecting the efficiency are included.

The role of the marrow as a site for antibody formation has been considered for many years. In 1912 Ludke reported the appearance of antibody in cultures of marrow cells obtained from previously immunized rabbits. Specific agglutinins for killed typhoid bacilli and lysins for ox red cells and sheep red cells were detected in the culture media 2 to 5 days later. However, the cultured cells failed to produce antibody when these antigens were added to the media. Similar findings by Reiter, Przygode, and Schilf appeared in the early literature with regard to the appearance of antibodies to various antigens in tissue cultures of bone marrow from immunized animals, along with failure to elicit antibody formation by addition of antigen to the culture resulted from the addition of excess amounts of antigen, so that if antibody synthesis occurred, the excess antigen combined with antibody and significant amounts of free antibody could not be detected in the culture media. Thorbecke and Keuning observed an increase in antibody in culture fluids when bone marrow fragments from rabbits immunized to paratyphoid B vaccine were cultured in roller tubes.

The cobalt and molybdenum positions had been derived from a three-dimensional Patterson function based on complete data out to λ-1 sin θMo≈ 1. From the separation of the separation of the Mo atoms it was thought that the structure contained free, unlinked MoO4 -2 ions, and this, together with the observed density and analyses for Co and Mo, suggested that the composition was probably Co2(MoO4)3. The paucity of structural information on complex oxide systems and the interesting properties, both structural and physical, of such systems prompted the present, detailed refinement of the structure. The result is more complicated and more interesting than had been anticipated: from the analysis of the X-ray data the compound is found to be NaCo2.31(MoO4)3, and this composition is consistent with chemical analyses. The structure shows several interesting features, including the partial occupancy of cobalt atoms in two independent CoO6 octahedral sites. In one arrangement of CoO6 octahedra there is the not too common face sharing to form infinite columns; in the other arrangement a zig-zag sheet, as far as we know differing from anything thus far reported, is formed by the sharing of edges and corners.

The analysis of closed circuit systems in which spontaneous steady-state electric currents appear can be carried out with the use of the function [function not transcribed]. The analysis indicates that any open circuit system of the form. Phase 1, barrier 1, phase 2, ......, phase b, barrier b, phase 1' is a chemical source of electromotive force when the phase 1 and 1' are identical, when the system contains two or more barriers whose sets of ionic transport members are different, and when the system is composed of two or more phases whose chemical properties are different. A general expression for the electromotive force of model systems composed of homogeneous phases and biological membranes in linear array can be written as [expression not transcribed] in which the indicated summations are to be performed for all barriers and for all ions to which each barrier is permeable.

A kinetic study of the exchange of normal and radioactive bromine in graphite-bromine lamellar compounds has been made at temperatures of 30° to 50°C. Natural and synthetic graphite powders were investigated. Two alternative mechanisms for the exchange, volume diffusion and surface exchange, were considered. The data were in better agreement with the diffusion mechanism. Diffusion coefficients of 10 -9 to 10 -8 cm2/sec and an activation energy of 11 to 14 kcal/mole were calculated for the natural graphite powders. The diffusion coefficients increased with increasing bromine content. Reversibly absorbed bromine exchanged more rapidly than irreversibly absorbed bromine.

Innes, Zemen, Frenkel, Borner and Wright (1962) described an outbreak of encephalitozoönosis of the central nervous system in mice, a summary of which is given below for an understanding of why this appendix may be of interest. When the paper was presented for publication, the editors of the journal decided to omit the history of our mouse colony. In our opinion, to understand (a) how this infection may have arisen and (b) may have spread, and still exist in some colonies, it is of prime importance to know the history of this strain of mice used by us (and others). It also has lessons on the establishment and maintenance of so-called "disease-free" or "specific pathogen-free"* colonies of laboratory animals in general. Information on the history of the mice has been culled from Col. H. Yager, VC, Director of the Division of Veterinary Medicine, Walter Reed Army Institute of Medical Research, Washington, D. C., and from Drs, Clara Lynch and John B. Nelson, Rockefeller Institute, New York.

In considering the problems associated with the measurement of SSNM content of Non-Production Fuels, two distinct problems are apparent. The first is the technical problem of obtaining highly accurate measurements in a complicated chemical and physical system. The second is the administrative problem of choosing a measurement system which provides a basic of financial settlement acceptable to both the seller (reactor operator) and the buyer (Commission).

Hastelloy F is a prime contender as a material of construction for plant dissolvers in the power fuel reprocessing program. Consequently, the fabrication and installation of dissolver was undertaken to delineate any unknown problems associated with the use of Hastelloy F; and, at the same time, to provide a vessel for development studies on the Niflex or the Sulfex processes. The purpose of this report is to describe the actual basis for design as well as to present the problems encountered during the fabrication of the vessels.

In early July, 1958, it appeared that Columbia River temperature at HAPO would be near 24.5ºC by the end of August. River temperature were averaging 4º to 5º above 1957 figures and were 3º to 4º above the ten year highs. It seemed desirable to examine the problem to determine if any corrective measure could be taken, since it was apparent that production losses were imminent.