NITRITE INGROWTH AND STRESS CORROSION CHARACTERIZATION OF TANK 11H SUPERNATE (open access)

NITRITE INGROWTH AND STRESS CORROSION CHARACTERIZATION OF TANK 11H SUPERNATE

Waste supernate stored in Tank 11H was analyzed periodically from May 1973-August 1975 to determine the rate of nitrite ingrowth by radiolytic decomposition of nitrate. This waste was transferred to tank 33F in accordance with TA 2-892, Rev. 1, 'Use of Cracked Tank for Fresh High Level Waste,' during the week of November 10, 1975. This letter summarizes analytical and corrosion characterization which indicate that this transfer should not increase the risk of stress corrosion cracking in F Area non-stress-relieved tanks. An interpretation of the nitrite ingrowth data is presented and used as a basis for cokncluding that the crack in Tank 11H occurred early in 1974. The formation of nitrite in waste supernate was followed for 2 1/4 years during the last filling and storage cycle in 11H. The conversion of nitrate to nitrite in the 1 1/2 year period after filling was 4.9 x 10{sup -11} mol NO{sub 2}{sup -}/{ell} BTU of fission product heat. The energy released during the period was 1.15 x 10{sup 10} BTU with a corresponding increase in nitrite of 0.56 mol/{ell}. The crack that was first observed in Tank 11H in April 1974 probably made its final penetration through the wall in March …
Date: November 25, 1975
Creator: Ondrejoin, R.
System: The UNT Digital Library