Westinghouse Savannah River Company (WSRC) has established a configuration management (CM) plan to execute the SRS CM Policy and the requirements of the DOE Order 4700.1. The Reactor Restart Division (RRD) has developed its CM Plan under the SRS CM Program and is implementing it via the RRD CM Program Plan and the Integrated Action Plan. The purpose of the RRD CM program is to improve those processes which are essential to the safe and efficient operation of SRS production reactors. This document provides details of this plan.

Semiempirical interatomic potentials are developed for silicon and carbon by modeling the total energy of the system using tight-binding approaches. The parameters of the models were obtained by fitting to results from accurate first-principles Local Density Functional calculations. Applications to the computation of phonons as a function of volume for diamond-structured silicon and carbon and the thermal expansions for silicon and diamond yields results which agree well with experiment. The physical origin of the negative thermal expansion observed in silicon is explained. A tight-binding total energy model is generated capable of describing carbon systems with a variety of atomic coordinations and topologies. The model reproduces the total energy versus volume curves of various carbon polytypes as well as phonons and elastic constants of diamond and graphite. The model has also been used in the molecular-dynamics simulation of the properties of carbon clusters. The calculated ground-state geometries of small clusters (C{sub 2}--C{sub 10}) correlates well with results from accurate quantum chemical calculations, and the structural trend of clusters from C{sub 2} to C{sub 60} are investigated. 67 refs., 19 figs.

This report presents current data on production, consumption, stocks, imports, exports, and prices of the principal energy commodities in the United States. Also included are data on international production of crude oil, consumption of petroleum products, petroleum stocks, and production of electricity from nuclear-powered facilities. 36 figs., 57 tabs.

This Interim Report summarizes the findings of our first twenty in-depth interviews in the Advanced Nuclear Reactor Public Opinion Project. We interviewed 6 industry trade association officials, 3 industry attorneys, 6 environmentalists/nuclear critics, 3 state officials, and 3 independent analysts. In addition, we have had numerous shorter discussions with various individuals concerned about nuclear power. The report is organized into the four categories proposed at our April, 1991, Advisory Group meeting: safety, cost-benefit analysis, science education, and communications. Within each category, some change of focus from that of the Advisory Group has been required, to reflect the findings of our interviews. This report limits itself to describing our findings. An accompanying memo draws some tentative conclusions.

A realistic'' model for the time evolution of the SSC luminosity is given. The SDC instrumentation and physics strategy should be informed by this profile. 1 ref.

The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)

The Portsmouth Gaseous Diffusion Plant Security and Police Operations Department is responsible for protecting the US Department of Energy interests at the Portsmouth Plant from theft, sabotage, and other hostile acts that may adversely affect national security, the public health and safety, or property at the Department of Energy facility. This audit's purpose was to evaluate Martin Marietta Energy Systems, Inc.'s staff management at the Portsmouth Plant Security Department. The Portsmouth Plant Security Department could reduce operating cost up to an estimated $4.4 million over 5 years by: (1) Eliminating up to 14 unnecessary staff positions, and (2) reducing the length of relief breaks. These economies could be realized through implementing written operating procedures and negotiating removal of certain labor union restrictions. 2 tabs.

This report discusses basic properties of bituminous, subbituminous, and lignite coals. Properties of coal liquids are also investigated. Heats of immersion in strong acids are found for Pittsburgh {number sign}8, Illinois {number sign}6, and Wyodak coals. Production of coal liquids by distillation is discussed. Heats of titration of coal liquids and coal slurries are reported. (VC)

This report lists the 12 adopted United Nations Security Council resolutions relating to the Iraq-Kuwait situation through October 1991. The texts of these resolutions, along with the votes by members of the Council, are included in this report.

This report presents current data on production, consumption, stocks, imports, exports, and prices of the principal energy commodities in the United States. Also included are data on international production of crude oil, consumption of petroleum products, petroleum stocks, and production of electricity from nuclear-powered facilities.

During the seventh quarter, water pretreatment experiments were done at lower pressures (1000 psig), with early H{sub 2}O injection or continuous H{sub 2}O injection, and with demineralized coals. In addition, a set of blank experiments was done with all four coals in helium at the following conditions: 350{degrees}C; 4000 psig; 20 minutes. An additional experiment was done with the Zap lignite at atmospheric pressure. Helium was used instead of nitrogen since it can be obtained in highly pure grades. The purpose of the blank experiments is to determine how much of the water pretreatment process is a thermal and/or pressure effort. The residues from the standard water pretreatment experiments with Illinois and Pittsburgh coals were subjected to analysis by TG-FTIR, solvent extraction, solvent swelling, oxygen reactivity index and donor solvent liquefaction. The pyridine extractables were analyzed. With regard to liquefaction behavior, improvements in the yields of oils and toluene solubles are observed for selected Illinois and Pittsburgh coals at longer pretreatment times ({ge} 60 minutes).

The energetics and structures of clean and adsorbate covered surfaces are investigated in this dissertation. First, the formalism, within the Corrected Effective Medium (CEM) method, for calculating the surface energy of a clean surface is derived. The surface energies for many different metals and their low index surfaces are presented. The minimization of the surface energy is then used to predict the multilayer relaxation of the Al(111), (100), Ni(100), (110) and Fe(100) surfaces. Extensions of the surface CEM formalism to calculate the binding energies of ordered adsorbates on metals surfaces are also derived. The minimization of the binding energy allowed determination of the binding heights, sites and the extent of induced multilayer relaxation for H and N atoms on the Fe(110), (100) and W(110) surfaces. The last topic deals with the dynamics of the epitaxial growth of metals on metal surfaces. The CEM method was first modified by making approximations to enable faster evaluations of the potential and its corresponding forces for molecular dynamics simulations. The goal of these simulations was to identify the important steps in the formation of equilibrium epitaxial structures. 180 refs., 31 figs., 18 tabs.

Our research program is devoted to understanding the dynamics of elementary ionic collisions at the level of the underlying potential surface by measuring energy and angular distributions of reactively scattered products with crossed beam methods over the relative center-of-mass energy range from 0.3 to several eV. We have performed reactive and non-reactive scattering studies on the proton and hydrogen atom transfer systems listed below: O + NH{sub 3} {yields} OH + NH{sub 2} {delta}H = {minus}0.2 eV O + H{sub 2}O {yields} OH + OH {delta}H = +0.4 eV. In both of these systems, the reactions are hypothesized to occur on potential energy surfaces having two minima. The first minimum corresponds to the formation of an electrostatically bound complex, e.g., O(H{sub 2}O), followed by an intramolecular hydrogen atom/proton transfer to yield OH{center dot}OH, which may then form the products by cleavage of the complex.

A high pressure apparatus constructed for measuring the rates of reactions in liquids under pressures ranging from 1 atm to 2000 atm has been used to measure the complexation kinetics of molybdenum hexacarbonyl reacting with 2,2-bipyridine, 4,4{prime}-dimethyl-2-2{prime}-bipyridine and 4,4{prime}-diphenyl-2-2{prime} bipyridine in toluene. Pentacarbonyl reaction intermediates are created by a 10 nsec flash of frequency tripled Nd:YAG laser light. Measured activation volumes for chelate ligand ring closure indicate a change in mechanism from associative interchange to dissociative interchange as steric hindrance increases. A similar high pressure kinetics study of molybdenum carbonyl complexation by several substituted phenanthrolines is now well advanced that indicates that with the more rigid phenanthroline ligands steric effects from bulky substituents have less effect on the ring closure mechanism than in the case of the bipyridine ligands. An experimental concentration dependence of the fluorescence quantum yield of cresyl violet has been harmonized with previously published contradictory reports. Fluorescence of cresyl violet in various solvents and in micellar systems has also been systematically explored.

The availability of instrumentation to measure the high outlet gas temperature of a particle bed reactor is a topic of some concern. There are a number of possible techniques with advantages and disadvantages. In order to provide some baseline choice of instrumentation, a review has been conducted of these various technologies. This report summarizes the results of this review for a group of technologies loosely defined as optical techniques (excluding optical pyrometry). The review has concentrated on a number of questions for each technology investigated. These are: (1) Description of the technology, (2) Anticipated sensitivity and accuracy, (3) Requirements for implementation, (4) Necessary development time and costs, (5) Advantages and disadvantages of the technology. Each of these areas was considered for a technology and a large number of technologies were considered in a review of the literature. Based upon this review it was found that a large number of methods exist to measure temperatures in excess of 2000 K. None of the methods found were ideal. Four methods, however, appeared to warrant further consideration: opto-mechanical expansion thermometry, surface Raman spectroscopy, gas-phase Raman spectroscopy and coherent anti-Stokes Raman spectroscopy (CARS). These techniques will be discussed further in this document.

An analytic approach was used in this study to test the logic, coding, and the theoretical limits of the WIND System atmospheric models for the Savannah River Plant. In this method, dose or concentration estimates predicted by the models were compared to the analytic solutions to evaluate their performance. The results from AREA EVACUATION and PLTFF/PLUME were very nearly identical to the analytic solutions they are based on and the evaluation procedure demonstrated that these models were able to reproduce the theoretical characteristics of a puff or a plume. The dose or concentration predicted by PLTFF/PLUME was always within 1% of the analytic solution. Differences between the dose predicted by 2DPUF and its analytic solution were substantially greater than those associated with PUFF/PLUME, but were usually smaller than 6%. This behavior was expected because PUFF/PLUME solves a form of the analytic solution for a single puff, and 2DPUF performs an integration over a period of time for several puffs to obtain the dose. Relatively large differences between the dose predicted by 2DPUF and its analytic solution were found to occur close to the source under stable atmospheric conditions. WIND System users should be aware of these situations in which the …

During the seventh quarter, water pretreatment experiments were done at lower pressures (1000 psig), with early H{sub 2}O injection or continuous H{sub 2}O injection, and with demineralized coals. In addition, a set of blank experiments was done with all four coals in helium at the following conditions: 350{degrees}C; 4000 psig; 20 minutes. An additional experiment was done with the Zap lignite at atmospheric pressure. Helium was used instead of nitrogen since it can be obtained in highly pure grades. The purpose of the blank experiments is to determine how much of the water pretreatment process is a thermal and/or pressure effort. The residues from the standard water pretreatment experiments with Illinois and Pittsburgh coals were subjected to analysis by TG-FTIR, solvent extraction, solvent swelling, oxygen reactivity index and donor solvent liquefaction. The pyridine extractables were analyzed. With regard to liquefaction behavior, improvements in the yields of oils and toluene solubles are observed for selected Illinois and Pittsburgh coals at longer pretreatment times ({ge} 60 minutes).

The results produced by two of the WIND System atmospheric models, PUFF/PLUME and 2DPUF, were compared with a select group of eight MATS experiments to determine the performance of the models. Three of the MATS experiments employed TRAC vehicle sampling and the remaining five used a line of fixed samplers. The performance of the models was based on certain dispersion characteristics that are important in emergency response situations. Both PUFF/PLUME and 2DPUF were executed with the same source term and meteorological data. When the numerical results from the models were compared to the observed values from the MATS experiments, it was found that 2DPUF produced concentrations and plume widths that were closer to the observed values than PUFF/PLUME. Both models did not produce any bias in the values of the concentration when individual data points were examined; however, PUFF/PLUME consistently overpredicted the peak and total concentrations. 2DPUF did not exibit any bias in the peak and total concentrations. When wind direction errors were removed, 80--84% of the concentrations from PUFF/PLUME and 88% of the concentrations from 2DPUF where within a factor of 10 of the observed values. In some instances, both models were able to predict concentration values that were …

An analytic approach was used in this study to test the logic, coding, and the theoretical limits of the WIND System atmospheric models for the Savannah River Plant. In this method, dose or concentration estimates predicted by the models were compared to the analytic solutions to evaluate their performance. The results from AREA EVACUATION and PLTFF/PLUME were very nearly identical to the analytic solutions they are based on and the evaluation procedure demonstrated that these models were able to reproduce the theoretical characteristics of a puff or a plume. The dose or concentration predicted by PLTFF/PLUME was always within 1% of the analytic solution. Differences between the dose predicted by 2DPUF and its analytic solution were substantially greater than those associated with PUFF/PLUME, but were usually smaller than 6%. This behavior was expected because PUFF/PLUME solves a form of the analytic solution for a single puff, and 2DPUF performs an integration over a period of time for several puffs to obtain the dose. Relatively large differences between the dose predicted by 2DPUF and its analytic solution were found to occur close to the source under stable atmospheric conditions. WIND System users should be aware of these situations in which the …

We review models for spin-weighted parton distributions in a proton. Sum rules involving the nonsinglet components of the structure function xg{sub 1}{sup p} help narrow the range of parameters in these models. The contribution of the {gamma}{sub 5} anomaly term depends on the size of the integrated polarized gluon distribution and experimental predictions depend on its size. We have proposed three models for the polarized gluon distributions, whose range is considerable. These model distributions give an overall range is considerable. These model distributions give an overall range of parameters that can be tested with polarized beam experiments. These are discussed with regard to specific predictions for polarized beam experiments at energies typical of UNK.

The purpose of this report is to present information on the quality of some of the Energy Information Administration`s (EIA) coal data. This report contains discussions of data on production, direct labor hours, recoverable reserves, and prices from 1983 through 1988. Chapter 2 of this report presents a summary of the EIA coal data collection and identifies other sources providing similar data. Chapters 3 and 4 focus on data on coal production and direct labor hours, respectively. Detailed comparisons with data from the Mine Safety and Health Administration (MSHA) and State mining agencies are presented. Chapter 5 examines recoverable reserves. Included are internal comparisons as well as comparisons with other published reserve-related data, namely those of BXG, Inc. Chapter 6 describes how EIA obtains estimates of coal prices and discusses the variability in the prices caused by factors such as mine type, coal rank, and region. 5 figs., 5 tabs.

This Interim Report summarizes the findings of our first twenty in-depth interviews in the Advanced Nuclear Reactor Public Opinion Project. We interviewed 6 industry trade association officials, 3 industry attorneys, 6 environmentalists/nuclear critics, 3 state officials, and 3 independent analysts. In addition, we have had numerous shorter discussions with various individuals concerned about nuclear power. The report is organized into the four categories proposed at our April, 1991, Advisory Group meeting: safety, cost-benefit analysis, science education, and communications. Within each category, some change of focus from that of the Advisory Group has been required, to reflect the findings of our interviews. This report limits itself to describing our findings. An accompanying memo draws some tentative conclusions.

In photosynthetic reaction centers, a quinone molecule, Q{sub B}, is the terminal acceptor in light-induced electron transfer. The crystal structure of the reaction center implicates the protonatable amiho acid residues L212Glu and L213Asp in the binding of Q{sub B} to the reaction center and in proton transfer to the anionic forms of Q{sub B} generated by electron transfer from Q{sub A}. Here we report the construction of the double mutant L212Ala-L213Ala by site-specific mutagenesis, and the isolation and preliminary biophysical characterization of revertant and suppressor strains that have regained the ability to grow under photosynthetic conditions. Our results show that neither L212Glu nor L213Asp is essential for efficient light-induced electron or proton transfer in Rhodobacter capsulatus and that second-site mutations, located within the QB binding pocket or at a more distant site, can compensate for mutations at L212 and L213. Acquisition of a single negatively charged residue (at position L213, or on the other side of the binding pocket at position L225) or loss of a positively charged residue (at position M231) is sufficient to restore activity to the complex.

The objectives of this study are to establish the mechanisms and rates of basic steps in coal conversion processes, to integrate and incorporate this information into comprehensive computer models for coal conversion processes, to evaluate these models and to apply them to gasification, mild gasification and combustion in heat engines. (VC)