Multi-fluid code simulations including anomalous non-diffusive transport of plasma and impurities in the tokamak SOL (open access)

Multi-fluid code simulations including anomalous non-diffusive transport of plasma and impurities in the tokamak SOL

Fast intermittent transport has been observed in the scrape-off layer (SOL) of major tokamaks including Alcator C-Mod, DIII-D, and NSTX. This kind of transport is not diffusive but rather convective. It strongly increases plasma flux to the chamber walls and enhances the recycling of neutral particles in the main chamber. We discuss anomalous cross-field convection (ACFC) model for impurity and main plasma ions and its relation to intermittent transport events, i.e. plasma density blobs and holes in the SOL. Along with plasma diffusivity coefficients, our transport model introduces time-independent anomalous cross-field convective velocity. In the discharge modelling, diffusivity coefficients and ACFC velocity profiles are adjusted to match a set of representative experimental data. We use this model in the edge plasma physics code UEDGE to simulate the multi-fluid two-dimensional transport for these three tokamaks. We present simulation results suggesting the dominance of anomalous convection in the far SOL transport. These results are consistent with the hypothesis that the chamber wall is an important source of impurities and that different impurity charge states have different directions of anomalous convective velocity.
Date: November 25, 2003
Creator: Pigarov, A. Yu; West, W. P.; Soukhanovskii, V.; Rognlien, T. D.; Maingi, R.; Lipschultz, B. et al.
System: The UNT Digital Library
Coherence Measurements of a Transient 14.7 nm X-ray Laser (open access)

Coherence Measurements of a Transient 14.7 nm X-ray Laser

We present the longitudinal coherence measurement of the transient inversion collisional x-ray laser for the first time. The Ni-like Pd x-ray laser at 14.68 nm is generated by the LLNL COMET laser facility and is operating in the gain-saturated regime. Interference fringes are produced using a Michelson interferometer setup in which a thin multilayer-coated membrane is used as a beam splitter. The longitudinal coherence length for the picosecond duration 4d{sup 1}S{sub 0} {yields} 4p{sup 1}P{sub 1} lasing transition is determined to be {approx}400 {micro}m (1/e HW) by adjusting the length of one interferometer arm and measuring the resultant variation in fringe visibility. This is four times improved coherence than previous measurements on quasi-steady state schemes largely as a result of the narrower line profile in the lower temperature plasma. The inferred gain-narrowed linewidth of {approx}0.29 pm is also substantially narrower than previous measurements on quasi-steady state x-ray laser schemes. This study shows that the coherence of the x-ray laser beam can be improved by changing the laser pumping conditions. The x-ray laser is operating at 4 - 5 times the transform-limited pulse.
Date: November 25, 2003
Creator: Remond, C; Dunn, J; Delmotte, F; Nilsen, J; Hubert, S; Ravet, M et al.
System: The UNT Digital Library
Cooper pair formation dynamics in Bi2Sr2CaCu2O8+delta (open access)

Cooper pair formation dynamics in Bi2Sr2CaCu2O8+delta

We utilize ultrafast terahertz pulses to monitor the carrierdynamics in the high-TC superconductor Bi2Sr2CaCu2O8+delta. Thetemperature, density and timedependence distinctly exposes a bimolecularrecombination process of quasiparticles which underlies formation ofCooper pairs.
Date: November 25, 2003
Creator: Kaindl, R. A.; Carnahan, M. A.; Orenstein, J.; Chemla, D. S.; Oh, S. & Eckstein, J. N.
System: The UNT Digital Library
Comparison of LiFePO4 from different sources (open access)

Comparison of LiFePO4 from different sources

The lithium iron phosphate chemistry is plagued by the poor conductivity and slow lithium diffusion in the solid phase. In order to alleviate these problems, various research groups have adopted different strategies including decreasing the particle sizes, increasing the carbon content, and adding dopants. In this study we obtained LiFePO4 electrodes from six different sources and used a combined model-experimental approach to compare the performance. Samples ranged from one with no carbon coating to one with 15 percent coating. In addition, particle sizes varied by as much as a order of magnitude between samples. The study detailed in this manuscript allows us to provide insight into the relative importance of the conductivity of the samples compared to the particle size, the impact of dopant on performance and ideas for making materials in order to maximize the power capability of this chemistry.
Date: November 25, 2003
Creator: Striebel, Kathryn; Shim, Joongpyo; Srinivasan, Venkat & Newman, John
System: The UNT Digital Library
Characterization of high-power lithium-ion cells-performance and diagnostic analysis (open access)

Characterization of high-power lithium-ion cells-performance and diagnostic analysis

Lithium-ion cells, with graphite anodes and LiNi0.8Co0.15Al0.05O2 cathodes, were cycled for up to 1000 cycles over different ranges of SOC and temperatures. The decline in cell performance increases with the span of SOC and temperature during cycling. Capacity fade was caused by a combination of the loss of cycleable Li and degradation of the cathode. The room temperature anodes showed SEI compositions and degrees of graphite disorder that correlated with the extent of the Li consumption, which was linear in cell test time. TEM of the cathodes showed evidence of crystalline defects, though no major new phases were identified, consistent with XRD. No evidence of polymeric deposits on the cathode particles (FTIR) was detected although both Raman and TEM showed evidence of P-containing deposits from electrolyte salt degradation. Raman microscopy showed differences in relative carbon contents of the cycled cathodes, which is blamed for part of the cathode degradation.
Date: November 25, 2003
Creator: Striebel, K. A.; Shim, J.; Kostecki, R.; Richardson, T. J.; Ross, P. N.; Song, X. et al.
System: The UNT Digital Library
Electron beam conditioning by Thomson scattering (open access)

Electron beam conditioning by Thomson scattering

A method is proposed for conditioning electron beams via Thomson scattering. The conditioning provides a quadratic correlation between the electron energy deviation and the betatron amplitude of the electrons, which results in enhanced gain in free-electron lasers. Quantum effects imply conditioning must occur at high laser fluence and moderate electron energy. Conditioning of x-ray free-electron lasers should be achievable with present laser technology, leading to significant size and cost reductions of these large-scale facilities.
Date: November 25, 2003
Creator: Schroeder, C. B.; Esarey, E. & Leemans, W. P.
System: The UNT Digital Library
Atomic structure of defects in GaN:Mg grown with Ga polarity (open access)

Atomic structure of defects in GaN:Mg grown with Ga polarity

Abstract: Electron microscope phase images, produced by direct reconstruction of the scattered electron wave from a focal series of high-resolution images, were used to determine the nature of defects formed in GaN:Mg crystals. We studied bulk crystals grown from dilute solutions of atomic nitrogen in liquid gallium at high pressure and thin films grown by the MOCVD method. All the crystals were grown with Ga-polarity. In both types of samples the majority of defects were three dimensional Mg-rich hexagonal pyramids with bases on the (0001) plane and six walls on {l_brace}11{und 2}3{r_brace} planes seen in cross-section as triangulars. Some other defects appear in cross-section as trapezoidal (rectangular) defects as a result of presence of truncated pyramids. Both type of defects have hollow centers. They are decorated by Mg on all six side walls and a base. The GaN which grows inside on the defect walls shows polarity inversion. It is shown that change of polarity starts from the defect tip and propagates to the base, and that the stacking sequence changes from ab in the matrix to bc inside the defect. Exchange of the Ga sublattice with the N sublattice within the defect leads to 0.6 {+-} 0.2{angstrom} displacement between …
Date: November 25, 2003
Creator: Liliental-Weber, Z.; Tomaszewicz, T.; Zakharov, D.; Jasinski, J.; O'Keefe, M. A.; Hautakangas, S. et al.
System: The UNT Digital Library
Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries (open access)

Effect of conductive additives in LiFePO4 cathode for lithium-ion batteries

The electrochemical properties of LiFePO4 cathodes with different carbon contents were studied to find out the role of carbon as conductive additive. LiFePO4 cathodes containing from 0 percent to 12 percent of conductive additive (carbon black or mixture of carbon black and graphite) were cycled at different C rates. The capacity of LiFePO4 cathode increased, as conductive additive content increased. Carbon increased the utilization of active material and the electrical conductivity of electrode, but decreased volumetric capacity of electrode.
Date: November 25, 2003
Creator: Shim, J.; Guerfi, A.; Zaghib, K. & Striebel, K.A.
System: The UNT Digital Library
The development of low cost LiFePO4-based high power lithium-ion batteries (open access)

The development of low cost LiFePO4-based high power lithium-ion batteries

The cycling performance of low-cost LiFePO4-based high-power lithium-ion cells was investigated and the components were analyzed after cycling to determine capacity fade mechanisms. Pouch type LiFePO4/natural graphite cells were assembled and evaluated by constant C/2 cycling, pulse-power and impedance measurements. From post-test electrochemical analysis after cycling, active materials, LiFePO4 and natural graphite, showed no degradation structurally or electrochemically. The main reasons for the capacity fade of cell were lithium inventory loss by side reaction and possible lithium deposition on the anode.
Date: November 25, 2003
Creator: Shim, Joongpyo; Sierra, Azucena & Striebel, Kathryn A.
System: The UNT Digital Library
Full-Scale Cookoff Model Validation Experiments (open access)

Full-Scale Cookoff Model Validation Experiments

This paper presents the experimental results of the third and final phase of a cookoff model validation effort. In this phase of the work, two generic Heavy Wall Penetrators (HWP) were tested in two heating orientations. Temperature and strain gage data were collected over the entire test period. Predictions for time and temperature of reaction were made prior to release of the live data. Predictions were comparable to the measured values and were highly dependent on the established boundary conditions. Both HWP tests failed at a weld located near the aft closure of the device. More than 90 percent of unreacted explosive was recovered in the end heated experiment and less than 30 percent recovered in the side heated test.
Date: November 25, 2003
Creator: McClelland, M. A.; Rattanapote, M. K.; Heimdahl, E. R.; Erikson, W. E.; Curran, P. O. & Atwood, A. I.
System: The UNT Digital Library
Dislocation Image Stresses at Free Surfaces by the Finite Element Method (open access)

Dislocation Image Stresses at Free Surfaces by the Finite Element Method

The finite element method has been routinely used to calculate the image stresses of dislocation segments. When these segments intersect with surfaces, the image stresses at the surfaces diverges singularly. At the presence of these singularities, both convergence and accuracy of using the finite element method need to be examined critically. This article addresses these issues with the aim toward the application of dislocation dynamics simulations in thin films.
Date: November 25, 2003
Creator: Cai, W; Bulatov, V; Tang, M & Xu, G
System: The UNT Digital Library
Measurement of the absolute hohlraum wall albedo under ignition foot drive conditions (open access)

Measurement of the absolute hohlraum wall albedo under ignition foot drive conditions

We present the first measurements of the absolute albedos of hohlraums made from gold or from high-Z mixtures. The measurements are performed over the range of radiation temperatures (70-100 eV) expected during the foot of an indirect-drive temporally-shaped ignition laser pulse, where accurate knowledge of the wall albedo (i.e. soft x-ray wall re-emission) is most critical for determining capsule radiation symmetry. We find that the gold albedo agrees well with calculations using the super transition array opacity model, potentially providing additional margin for ICF ignition.
Date: November 25, 2003
Creator: Suter, L. J.; Wallace, R. J.; Hammel, B. A.; Weber, F. A.; Landen, O. L.; Campbell, K. M. et al.
System: The UNT Digital Library
Nanostructured Energetic Materials with Sol-Gel Methods (open access)

Nanostructured Energetic Materials with Sol-Gel Methods

The utilization of sol-gel chemical methodology to prepare nanostructured energetic materials as well as the concepts of nanoenergetics is described. The preparation and characterization of two totally different compositions is detailed. In one example, nanostructured aerogel and xerogel composites of sol-gel iron (III) oxide and ultra fine grained aluminum (UFG Al) are prepared, characterized, and compared to a conventional micron-sized Fe{sub 2}O{sub 3}/Al thermite. The exquisite degree of mixing and intimate nanostructuring of this material is illustrated using transmission and scanning electron microscopies (TEM and SEM). The nanocomposite material has markedly different energy release (burn rate) and thermal properties compared to the conventional composite, results of which will be discussed. Small-scale safety characterization was performed aerogels and xerogels of the nanostructured thermite. The second nanostructured energetic material consists of a nanostructured hydrocarbon resin fuel network with fine ammonium perchlorate (NH{sub 4}ClO{sub 4}) oxidizer present.
Date: November 25, 2003
Creator: Gash, A.; Satcher, J.; Simpson, R. & Clapsaddle, B.
System: The UNT Digital Library
Temporal Characterization of a Picosecond Laser-Pumped X-ray Laser (for Applications) (open access)

Temporal Characterization of a Picosecond Laser-Pumped X-ray Laser (for Applications)

Compact soft x-ray laser sources are now used routinely for various applications primarily because of their high repetition rate, high photon fluence and short pulse duration characteristics. For some of these applications, for example interferometry of high density laser-produced plasmas, longer optical drive pulses, 6-13 ps (FWHM), have been implemented to maximize the x-ray output and coherence. It is therefore important to know the x-ray laser pulse length, shape and repeatability for these specific experiments as a baseline measurement but also to better understand the temporal behavior as a function of the pumping conditions in general. We report a detailed temporal characterization of the picosecond-driven 14.7 nm Ni-like Pd ion x-ray laser on the Compact Multipulse Terawatt (COMET) laser at LLNL using an ultrafast x-ray streak camera measurement of a horizontal slice of the near-field x-ray laser pattern. This is measured as a function of the chirped pulse amplification pumping laser conditions, including varying the pump pulse from 0.5-27 ps (FWHM), varying the plasma column length as well as investigating traveling wave (TW) and non-TW irradiation conditions.
Date: November 25, 2003
Creator: Dunn, J; Nilsen, J; Shepherd, R; Shlyaptsev, V; Booth, R; Smith, R et al.
System: The UNT Digital Library
Estimation of host rock thermal conductivities using thetemperature data from the drift-scale test at Yucca Mountain,Nevada (open access)

Estimation of host rock thermal conductivities using thetemperature data from the drift-scale test at Yucca Mountain,Nevada

A large volume of temperature data has been collected from a very large, underground heater test, the Drift Scale Test (DST) at Yucca Mountain, Nevada. The DST was designed to obtain thermal, hydrological, mechanical, and chemical (THMC) data in the unsaturated fractured rock of Yucca Mountain. Sophisticated numerical models have been developed to analyze the collected THMC data. In these analyses, thermal conductivities measured from core samples have been used as input parameters to the model. However, it was not known whether these core measurements represented the true field-scale thermal conductivity of the host rock. Realizing these difficulties, elaborate, computationally intensive geostatistical simulations have also been performed to obtain field-scale thermal conductivity of the host rock from the core measurements. In this paper, we use the temperature data from the DST as the input (instead of the measured core-scale thermal conductivity values) to develop an estimate of the field-scale thermal conductivity values. Assuming a conductive thermal regime, we develop an analytical solution for the temperature rise in the host rock of the DST; and using a nonlinear fitting routine, we obtain a best-fit estimate of field-scale thermal conductivity for the DST host rock. The temperature data collected from the DST …
Date: November 25, 2003
Creator: Mukhopadhyay, Sumitra & Tsang, Y. W.
System: The UNT Digital Library