Sixty-two references, some annotated, were taken from foreign literature to determine the status of work done in this area of metallurgy during 1958 and 1959. The references are grouped into two categories: references pertinent to the subject and general metallurgical references on metallic fuels.

As reported in the previous Progress Report (December 16, 1959) a stock solution of Th 230 was prepared from pitchblende. Pulse height analysis of this solution indicated the presence of only Th 230 (93%), Th 227 (5%), Th 232 (1%), and Th 228 (1%). This solution was used to make up synthetic thorium solution of various concentration. These synthetic solutions were analyzed to establish a chemical yield for the procedure. Neither the precision nor the chemical yield of the procedure were considered to be satisfactory. In the next report period, we hope to complete the testing of the thorium procedure, both with regard to chemical yield and precision, as well as to determine decontamination factor from radium, uranium, and polonium. To do this, pure solutions of polonium, radium, and uranium will be prepared. The polonium and radium will be processed from pitchblende while the uranium will be made by purifying reagent grade uranyl nitrate.

A sequential method is described for the determination of strontium- 89, strontium-90, barium-140, and tungsten185 in rain water samples. A comparison is made of data on radioactivity in individual rain samples and in monthly pot samples. Data are included on the total strontiuro-90 fall-out collected in steep walled stainless steel pots during the period. Results are compared with cumulative data for 1958 end 1959. (C.H.)

Applications of radioisotopes in the preparation of labeled drugs are reviewed. Among the applications described are the preparation of carbon-14- labeled cardiac glycosides, and the biosyinthesis of carbon-14-labeled digitoxin, morphine, colchicine, atropine, podophyllotoxin, and nicotine. The fate and metabolism of many of these drugs were traced. Radiochemical procedures were developed for the synthesis of pure compounds of pharmacological interest labeled with carbon-14, sulfur-35, and tritium. Investigations were made on the phenomena of drug penetration into the central nervous system. Publications during the period are listed. (C.H.)

The work described in this report represents progress toward an agreement signed by the United States and the European Atomic Energy Community which provides a basis for cooperation in programs for the advancement of peaceful applications of atomic energy.

A stainless steel autoclave for superheated water corrosion test was installed and "conditioned". Tests were begun to investigate the feasibility of densifying slip cast stainless steel by means of liquid phase sintering. Attempts to prepare tubular fuel elements by vacuum forming were resumed. Although thick-walled vacuum formed casting have been sintered on the aluminum mandrels without cracking, this has not yet been accomplished with the think sections of interest.

A six-inch diameter "O" ring from the HRT Mockup was examined metallographically after 2452 hours exposure to uranyl sulfate solution at 300C. surface defects, except for cold work defects were found only in areas exposed to uranyl sulfates. Defects found were pits, transgranular cracks, surface cracks, and grain attacks.

The report covers work performed during the period December 1, 1959 through December 31, 1959. The general objectives of the program of "Studies of Reactor Containment" are to accomplish theoretical and experimental investigations of the loads to which external containment structures for nuclear reactors are subjected in the vent of a violent incident at the reactor core, the evaluation of methods of reducing that loading, and the study of the response of and design criteria for external containment structures as a result of such loading. Progress of technical effort during the report period is summarized for each of the eight tasks of the program..

The overall scope of the program encompasses both research into the physical parameters involved in the collection of airborne radioactive particles and the development, fabrication and calibration of balloon-borne sampling equipment to enable the precise determination of stratospheric particle concentration and particle size distribution.

Thorium Procedure: As was mentioned in the last report, ammonium nitrate was substituted for ferric nitrate as a salting agent. Also, the acidity of the nitrate solution was reduced from 3.0 molar to 0.5 molar. the revised thorium procedure is described in the report. Radium Procedure: Work has ben initiated on the procedure of Petrow, Nietzel and DeSesa (Winchester Procedure) to determine if the procedure is suitable for very low level concentrations of radium.

SNAP II is the designation for a nuclear auxiliary power unit, designed primarily for utilization in the WS117L satellite vehicle. The SNAP II system consists of a reactor heat source, a mercury Rankine engine, and an alternator. Dynamic analysis of the power conversion system was conducted utilizing a comprehensive analog computer simulation. Feasibility of a parasitic load control for numerous system disturbances was demonstrated. This analysis was performed under a subcontract to to Atomics International as part of the Atomic Energy Commission Contract No. AT(11-1)-GEN-8.

It has been reported in the literature that prolonged soaking of 16 wt & uranium-aluminum alloys at elevated temperatures induces a microstructural changed termed "conglobulation". this process is essentially a spheroidization of the UAl4 eutectic. Conclusions of the tests: (1) Extended soaking of 48 wt $ uranium-aluminum alloy billets at 600 C does not improve their hot-rolling characteristics. (2) Soaking periods of 50 hours and greater reduce the tensile and yield strengths of these alloys. (3) Soaking for 50 hours results in complete spheroidization of the eutectic in 48 wt % uranium-aluminum alloys.

In order to perform the various experiments with a bubble chamber, a high intensity flash tube is used. This report briefly describes the power supplies designed and constructed to power these lamps.

This report describes the preprocessing stage to be added to the present ORACLE-Algol translator which will enable it to translate programs containing procedures. The Algol 60 procedure is an extremely flexible tool, and its full implementation presents a number of difficulties. Since it is undesirable to undertake major revisions of the existing parts of the translator and impossible to solve all of these difficulties in a processing stage, it was necessary to impose certain restrictions on the use of procedures. The result, however, retains the more basic features of the Algol 60 procedure concept. Most of the algorithms published in the Communications of the Association for Computing Machinery can be handled by the preprocessor with few minor or no changes.

Experiments in the controlled melting of irradiated fuel specimens, particularly of the APPR, STR, and MTR types have confirmed that prolonged heating in air at temperatures in excess of the melting point results in the release of a large portion of the radioactivity. On the other hand, a moderate amount of heating in air or steam sufficient only to melt a specimen results mainly in the partial volatilization of the rare gases; the halogens, iodine and bromine; and the alkali metals, cesium and rubidium. In the presence of air or water vapor, strontium and other fission products are not released. At trace concentration of fission products, slow melting of the APPR plate at 1525 C in air or steam effected the release of 50 percent of the rare gases, 33 percent of the iodine, 9 percent of the cesium and traces of strontium. After 25% burn-up, the cesium value increased to about 60 percent. Aluminum alloy of the MTR type, also at trace concentration, upon melting at 700 C released up to 2 percent of the iodine, 10 percent of the rare gases, and negligible portions of other fission products. Zirconium alloy of the STR type after 15 percent burn …