Synthetic fuel aromaticity and staged combustion (open access)

Synthetic fuel aromaticity and staged combustion

Samples of middle and heavy SRC-II distillates were distilled into 50 C boiling point range fractions. These were characterized by measurements of their molecular weight, elemental analysis and basic nitrogen content and calculation of average molecular structures. The structures typically consisted of 1 to 3 aromatic rings fused to alicyclic rings with short, 1 to 3 carbon aliphatic side chains. The lower boiling fractions contained significant amounts (1 atom/molecule) of oxygen while the heavier fractions contained so few heteroatoms that they were essentially hydrocarbons. Laboratory scale oxidative-pyrolysis experiments were carried out at pyrolysis temperatures of 500 to 1100 C and oxygen concentrations from 0 to 100 percent of stoichiometry. Analysis of liquid products, collected in condensers cooled with liquid nitrogen showed that aromatization is a major reaction in the absence of oxygen. The oxygen-containing materials (phenolics) seem to be more resistant to thermal pyrolysis than unsubstituted aromatics. Nitrogen converts from basic to nonbasic forms at about 500 C. The nonbasic nitrogen is more stable and survives up to 700 C after which it is slowly removed. A recently constructed 50,000 Btu/hr staged combustor was used to study the chemistry of the nitrogen and aromatics. SRC II combustion was studied under …
Date: November 15, 1982
Creator: Longanbach, J. R.; Chan, L. K. & Levy, A.
Object Type: Report
System: The UNT Digital Library
High-explosive-driven delay line pulse generator (open access)

High-explosive-driven delay line pulse generator

The inclusion of a delay line circuit into the design of a high-explosive-driven generator shortens the time constant of the output pulse. After a brief review of generator concepts and previously described pulse-shortening methods, a geometry is presented which incorporates delay line circuit techcniques into a coil generator. The circuit constants are adjusted to match the velocity of the generated electromagnetic wave to the detonation velocity of the high explosive. The proposed generator can be modeled by adding a variable inductance term to the telegrapher's equation. A particular solution of this equation is useful for exploring the operational parameters of the generator. The duration of the electromagnetic pulse equals the radial expansion time of the high-explosive-driven armature until it strikes the coil. Because the impedance of the generator is a constant, the current multiplication factor is limited only by nonlinear effects such as voltage breakdown, diffusion, and compression at high energies.
Date: November 15, 1982
Creator: Shearer, J.W.
Object Type: Article
System: The UNT Digital Library
Variation of the yield strength and strain-rate sensitivity exponent of type 21-6-9 stainless steel over a wide temperature range (open access)

Variation of the yield strength and strain-rate sensitivity exponent of type 21-6-9 stainless steel over a wide temperature range

The yield strength of solution-annealed 21-6-9 austenitic stainless steel was determined over a wider temperature range (-195 to 1100/sup 0/C) than has been previously reported. The most noteworthy characteristic of the variation of yield stress with temperature was the dramatic decrease in yield strength from -195/sup 0/C to 300/sup 0/C. The strain-rate sensitivity exponent, N, was determined using strain-rate change tests. A plot of N vs temperature showed that n dramatically increased at about 850/sup 0/C and that N is approximately independent of strain (structure). 3 figures.
Date: November 15, 1982
Creator: Kassner, M.E.
Object Type: Report
System: The UNT Digital Library

Hydrogeochemical and Stream Sediment Reconnaissance Basic Data for Phoenix Quadrangle -- report is missing

Data collected as part of a hydrogeochemical and stream sediment reconnaissance in Phoenix, Arizona including laboratory data on waters and sediments as well as field data.
Date: November 15, 1982
Creator: Union Carbide Corporation. Nuclear Division.
Object Type: Dataset
System: The UNT Digital Library