Objective is to design synthesize, and evaluate cyclic and polycyclic host organic compounds for their abilities to complex and lipophilize guest metal ions, their complexes, and their clusters. Host organic compounds consist of strategically placed solvating, coordinating, and ion-pairing sites tied together by covalent bonds through hydrocarbon units around cavities shaped to be occupied by guest metal ions or by metal ions plus their ligands. Specificity in complexation is sought by matching the following properties of host and guest: cavity and metal ion sizes; geometric arrangements of binding sites; number of binding sites; character of binding sites; and valences. During this period, hemispherands based on an aryloxy or cyclic urea unit, spherands based on aryloxyl units only, and their complexes with alkali metals and alkaline earths were investigated. An attempt to separate /sup 6/Li and /sup 7/Li by gel permeation chromatography of lithiospherium chloride failed. (DLC)

The development of standardized techniques for the comparative evaluation of electric vehicle battery technologies is summarized. The methodology considers both the traditional measures of battery performance (energy density, energy storage costs, and cycle life) and the equally important usage related battery characteristics (probability of technical success, operating and maintenance parameters, and safety/environmental impact). This comparative rationale is supplemented by the ability to generate battery test programs normalized to specific technologies and electric vehicle mission specifications. These test programs allow the evaluation of different battery technologies at comparable levels of electric vehicle performance. It was found that cost optimized electric passenger vehicles will have range specifications of 100 to 110 KM, depending on the specific performance of the battery. Longer range vehicles are penalized by higher first costs while shorter range vehicles suffer from reduced battery life and the need for more frequent alternative car rentals (presumably petroleum fueled) for trips which exceed the EV's range capability.

The Gravimelt Process was extended to the desulfurization of ordinary mine-cleaned Kentucky No. 11 coal obtained from the Tennessee Valley Authority. Eight process runs were made resulting in reduction of the sulfur content from a starting 2.7 lbs S/10/sup 6/ Btu to a mean of 0.475 lbs S/10/sup 6/ Btu, (0.95 lbs SO/sub 2//10/sup 6/ Btu) for an average 82% sulfur reduction. The effect of utilization of molten sodium hydroxide alone vs molten mixed potassium and sodium hydroxide was investigated for this coal; sulfur reduction averaged 84% for the mixed melt and 78% for the use of sodium hydroxide alone. A double extraction with sodium hydroxide resulted in a reduction in total sulfur to 0.3 lbs S/10/sup 6/ Btu which is an 89% reduction. In a series of experiments, the melt was reused three times on fresh samples of coal, always giving the same amount of sulfur reduction. Extraction of the desulfurized Kentucky No. 11 coals with an additional dilute sulfuric acid wash reduced the ash content of the coal from 7.9% to a level of 0.3%, thus providing a solid hydrocarbon fuel similar in both ash and sulfur content to a medium grade fuel oil. Multiple experimentation on high …

The toxicology and metabolism of nickel compounds (e.g., NiCl/sub 2/, ..cap alpha..Ni/sub 3/S/sub 2/, and Ni(CO)/sub 4/) were investigated in rats and hamsters.

Equipment modifications to a Freon 11 boil-off type calorimeter are described. The calorimetric system was used to measure the enthalpies of thiophene experimentally. Data were taken over a temperature range of 100/sup 0/F to 750/sup 0/F at pressures of 50, 100, 200, 400, 600, 825.9 (the critical), 1000, and 1500 psia. Thermodynamic properties derived from the data are compared to values in the literature, and the agreement is exceptionally good. The data are then compared directly to results calculated by means of two correlations: a modification of the BWR equation of state by Kesler and Lee, and a modified SRK equation of state method. Both correlations are found to work well in predicting the enthalpy of thiophene.

Extremely smooth, uniform metal coatings of micrometer thicknesses on microscopic glass spheres (microspheres) are often needed as targets for inertial confinement fusion (ICF) experiments. The first part of this paper reviews those methods used successfully to provide metal coated microspheres for ICF targets, including magnetron sputtering, electro- and electroless plating, and chemical vapor pyrolysis. The second part of this paper discusses some of the critical aspects of magnetron sputter coating of microspheres, including substrate requirements, the sticking of microspheres during coating (preventing a uniform coating), and the difficulties in growing the desired dense, smooth, uniform microstructure on continuously moving spherical substrates.

The objective of the BNL Neutral Beam Program is to develop a 250 keV neutral beam system suitable for heating experiments in toroidal or mirror plasma devices. The system will be based on acceleration and neutralization of negative hydrogen ions produced in and directly extracted from a source. The objective of source studies is to develop a unit delivering 10 A of negative ion currents in pulses of 1 s duration or longer, operating with extracted current densities of at least 0.5 A/cm/sup 2/ and having acceptable power and gas efficiencies and good beam optics. The 250 keV accelerator development work covers different structures, including those separated from the source by a bending magnet or a beam transfer system. During FY 1979 substantial progress was achieved toward the objectives of the program; in the same period the BNL program was reviewed by a panel, resulting in suggestions for a better orientation toward prospective users' requirements and in establishment of contacts with Princeton Plasma Physics Laboratory (TFTR Project) and Lawrence Berkeley and Livermore Laboratories (MFTF Project). A cooperative effort with Westinghouse was initiated in the second half of FY 1979 in order to utilize industrial facilities and expertise.

The price allocation guidelines (PAG) are an integrated set of specific cost targets for several task areas within the Low-cost Solar Array (LSA) Project. PAG is a working tool of LSA Project management designed to provide consistent and meaningful guidelines for costs of polycrystalline silicon material, sheet, cells, encapsulants, and module manufacturing. It is expected that advanced photovoltaic concepts derived from industry and the research community can be developed so that it will be possible by the end of 1982 to demonstrate production processes, all process steps, and prototype equipment required to manufacture flat-plate photovoltaic modules. This demonstration would incorporate production rates and product quality consistent with a specific market price determined by the program. This stage of development has been referred to as Technical Readiness. A goal of $0.70 per peak watt (1980 dollars) has been established for the cost of electricity generated by photovoltaic modules. The processes for producing modules demonstrated to be technically ready must be amenable to scale-up so that this price goal can eventually be achieved in the marketplace. The guidelines described in this document allocate portions of that goal to each module component. Sheet materials derived from the following five technologies are considered: Czochralski, …

In the second quarter of activities on developing Tailored Ceramic waste forms for SRP waste compositions, emphasis was on the chemistry controlling the incorporation of the waste elements into the crystalline phases of the high-alumina content ceramic and the major factors affecting the consolidation process. Research on the design and synthesis of oxide and phosphate ceramic waste forms has continued with emphasis on fluorite-structure oxides and on rare earth phosphates with the monazite structure. Dissolution studies to date indicate that monazite is very stable.

This will be an overview in which some of the general properties of loads are examined: their interface with the energy storage and switching devices; general problems encountered with different types of loads; how load behavior and fault modes can impact on the design of a power conditioning system (PCS).

In the preceding quarterly report, it was reported that while sampling the Solvent Refined Coal II (SRC II) pilot plant at Fort Lewis, Washington, the plant went down and vacuum bottoms waste material representing the minerals flow at the last steady state condition were obtained. This plant has been sampled again and samples of the incoming feed coal, sized coal and vacuum bottoms waste material were obtained. As part of our effort to trace the same mineral suite through mining, preparation and conversion, new samples of feed coal, cleaned coal and refuse were obtained from the District 4 commercial preparation plant. This preparation plant supplies coal to the SRC II pilot plant at Fort Lewis, Washington. A study of the thermal insulating properties of fired flyash based structural materials was completed and is included.

Most analytical and experimental approaches to the evaluation of fluid-structure interaction (FSI) effects in the General Electric Mark I BWR pressure suppression system treat the torus shell as rigid when the shell in real systems is flexible. This report describes linear three-dimensional finite-element analyses of one torus bay that investigated the qualitative effect of torus wall flexibility on hydrodynamic loads induced by a nominal safety relief valve (SRV) discharge. The results of these analyses support the general conclusion drawn from earlier two-dimensional analyses. The report also discusses finite-element analyses of a 3-D representation of the earlier 2-D plane-strain model of the torus shell.

An evaluation was completed to ascertain the applicability of line focus technologies to electrical power applications and to compare their performance and cost potential with point focus central receiver power systems. It was concluded that although the high temperature line focus (SRI) and fixed mirror line focus (GA) concepts duplicate the heat source characteristics and power conversion technology of the central receiver concepts these configurations do not offer a sufficient improvement in cost to warrant full scale development. The systems are, however, less complex than their point focus counterpart and should the central receiver system development falter they provide reasonable technology alternatives. The parabolic trough concept (BDM) was found to provide a low temperature technology alternative to the central receiver concept with promising performance and cost potential. Its continued development is recommended, with special emphasis on lower temperature (< 700/sup 0/F) applications. Finally, a variety of new promising line focus power system configurations were identified for a range of utility and industrial applications and recommendations were made on their implementation. This volume contains the detailed report. (WHK)

Proton magnetic resonance data are presented for plasma-deposited amorphous Si:H as a function of annealing temperature up to 650/sup 0/C. The data indicate that hydrogen diffuses internally before major evolution occurs, that transfer of hydrogen occurs from a heavily clustered phase to a dilute phase coincident with evolution and that evolution occurs initially from the heavily clustered phase. Comparison with infrared data indicates that the heavily clustered phase can be either SiH/ sub x/t = 2,3) or SiH.

The application of hyperfiltration to selected food product streams and food processing wastewaters for energy conservation was examined. This literature survey had led to the following conclusions: no research has been conducted in the food industry using membranes with hot process streams due to the temperature limitation (&lt; 40/sup 0/C) of the typically studied cellulose acetate membranes; based on the bench-scale research reviewed, concentration of fruit and vegetable juices with membranes appears to be technically feasible; pretreatment and product recovery research was conducted with membranes on citrus peel oil, potato processing and brine wastewaters and wheys. The experiments demonstrated that these applications are feasible; many of the problems that have been identified with membranes are associated with either the suspended solids or the high osmotic pressure and viscosity of many foods; research using dynamic membranes has been conducted with various effluents, at temperatures to approx. 100/sup 0/C, at pressures to 1200 psi and with suspended solids to approx. 2%; and, the dynamic membrane is being prototype tested by NASA for high temperature processing of shower water. The literature review substantiates potential for dynamic membrane on porous stainless tubes to process a number of hot process and effluent streams in the …

Initial Tandem Mirror Hybrid Study predicts the ability to produce large amounts of fissile fuel (2 to 7 tonnes per year U233 from a 4000 MW plant) at a cost that adds less than 25% to the cost of power from an LWR.

Research on the technical and economic feasibility of producing solar-cell-quality sheet silicon by coating inexpensive ceramic substrates with a thin layer of polycrystalline silicon is reported. The coating methods to be developed are directed toward a minimum-cost process for producing solar cells with a terrestrial conversion efficiency of 11 percent or greater. By applying a graphite coating to one face of a ceramic substrate, molten silicon can be caused to wet only that graphite-coated face and produce uniform thin layers of large-grain polycrystalline silicon; thus, only a minimal quantity of silicon is consumed. A variety of ceramic materials have been dip coated with silicon. The investigation has shown that mullite substrates containing an excess of SiO/sub 2/ best match the thermal expansion coefficient of silicon and hence produce the best SOC layers. With such substrates, smooth and uniform silicon layers 25 cm/sup 2/ in area have been achieved with single-crystal grains as large as 4 mm in width and several cm in length. Crystal length is limited by the length of the substrate. The thickness of the coating and the size of the crystalline grains are controlled by the temperature of the melt and the rate at which the substrate …

This report describes a series of extended analyses requested by the US Nuclear Regulatory Commission to provide qualified understanding of possible fluid/structure interaction (FSI) effects for SRV teequencher test results. Three input pulses with total impulses varying by up to a factor of five are applied to two-dimensional finite-element models of the Mark I torus with shell diameter-to-thickness ratios of 0, 300, and 600. The results of these analyses support earlier conclusions that increased wall flexibility enhances attenuation of hydrodynamic loads and furthermore indicate that the magnitude of the attenuation is only weakly affected by the total impulse of the bubble pressure time-history.

The impact of diameter in the range of 10 to 15 cm on the cost of wafers sliced from Czochralski ingots is analyzed. Increasing silicon waste and decreasing ingot cost with increasing ingot size are estimated along with projected costs. Results indicate a small but continuous decrease in sheet cost with increasing ingot size in this size range. Sheet costs including silicon are projected to be $50 to $60/m/sup 2/ (1980 $) depending upon technique used.

The objective of the program is to develop an underground superconducting power transmission system which is economical and technically attractive to the utility industry. The system would be capable of carrying very large blocks of electric power, thus enabling it to supplant overhead lines in urban and suburban areas and regions of natural beauty. The program consisted initially of work in the laboratory to develop suitable materials, cryostats, and cable concepts. The materials work covers the development and testing of suitable superconductors and dielectric insulation. The laboratory work has now been extended to an outside test facility which represents an intermediate step between the laboratory scale and a full-scale system. The facility will allow cables several hundred feet long to be tested under realistic conditions. In addition, the refrigerator has been designed for optimum service for utility applications.

Progress during this report period was marked by the initial operation of the Process Development Unit at about 50% of design capacity with indications that many aspects of the facility operated satisfactorily. However, a downstream constriction, the cause of which is being isolated, led to termination of the run after one-half hour of operation. In the light of observations made during earlier start-up efforts, several modifications of equipment and technique were made for improved operation. Vacuum outgassing experiments (850 to 1100/sup 0/C, 1 to 256 h) were carried out on miniplant-produced granules containing 360 and 3900 ppMw of zinc in the deposited silicon. Treatment of the data so that it can be extrapolated to the expected product of the Experimental Process System Development Unit awaits development of an appropriate model.

The Sunkist Citrus Plant in Ontario, California, processes about 6 million pounds of citrus fruit per day to make products which include frozen concentrated juice; chilled, pasteurized, natural strength juice; molasses from peel; dried meal from peel; pectin; citrus oil; and bioflavonoids. The energy intensive operations at the plant include concentration, drying, and refrigeration. The objective of the two-year two-phase project is to identify an economically viable alternative to the existing method of meeting energy requirements. Progress on the technical work of Phase I is reported. The following are summarized: requirements (energy price projection, atmospheric emission requirements, citrus juice quality constraints, economic evaluations); characterization (basic citrus processing operations, energy consumption and fruit processed vs time, identification and measurement of energy uses, energy balance for a typical citrus juice evaporator); and thermodynamic analysis (heat pump model, thermal evaporator, and co-generation model).

Thin film gold/polycrystalline cadmium telluride Schottky solar cells made by electrodepositing the semiconductor on an ITO-coated glass substrate serving also as an ohmic contact demonstrated an internal efficiency of 4% over 2 mm/sup 2/ areas. During the year being reported upon, Monosolar devoted mator attention to refining the electroplating process and determining the parameters governing CdTe film stoichiometry, grain size, substrate adhesion, and quality. UCLA acting as a Monosolar sub-contractor characterized both the CdTe films themselves and solar cells made from them. Techniques were developed for making measurements on films often less than 1 micron in thickness. The highest values achieved for efficiency parameters, not necessarily all in the same cell, were V/sub oc/ = 0.5 V, J/sub sc/ = 11 mA/cm/sup 2/, and fill factor = 0.55 before corrections in the absence of anti-reflection coatings. Typical resistivities for n-CdTe films were 10/sup 5/ ..cap omega..-cm. Lifetimes of about 10/sup -10/ sec were measured. Absorption coefficient of these films is in the order of 10/sup 4/ for lambda < 0.7 ..mu..m. Measured energy gap for these CdTe films is 1.55 eV, sightly higher than the 1.45 eV value for single crystal CdTe. The activation energy of the dominating trap level …

This document is intended as a supplement to the two-volume report entitled Federal Policies to Promote the Widespread Utilization of Photovoltaic Systems that was submitted to Congress by the Department of Energy in February and April of 1980. This supplement contains review comments prepared by knowledgeable experts who reviewed early drafts of the Congressional report. Responses to the review comments by the Jet Propulsion Laboratory, preparer of the Congressional report, are also included in this supplement. The Congressional report, mandated in the Solar Photovoltaic Energy Research, Development, and Demonstration Act of 1978 (P.L. 95-590), discusses various issues related to promoting the deployment of photovoltaic systems through the Federal Photovoltaic Program. Various program strategies and funding levels are examined.