The Oak Ridge National Laboratory (ORNL) is responsible for developing new and environmentally acceptable energy technologies that will offer the nation safe options for energy supply and efficient systems for energy use. Martin Marietta Energy Systems, Inc., (Energy Systems) operates ORNL under a management and operating contract. The purpose of the audit was to review and evaluate the effectiveness of site development planning activities at ORNL. A site development plan is a long-range master plan for the acquisition, development, utilization, and disposal of land and physical facilities at a specific US Department of Energy (DOE) facility. ORNL did not have a current site development plan and had not submitted updates to the old plan. This condition existed because the DOE Field Office, Oak Ridge (OR), and ORNL management had not implemented their responsibilities set forth in applicable DOE orders for site development planning. As a result, DOE had no assurance that ORNL real property holdings would be planned and developed economically and efficiently.

Radiological dose to the offsite maximum individual or the 50-mile population is often estimated assuming that operational atmospheric releases originate from the geographical center of the Savannah River Site. Historically, meteorological data collected from instrumentation on the H-Area tower have been utilized to estimate atmospheric dispersion from centrally located releases.'' This paper examines the effect on dose predictions using meteorological data from seven onsite towers located at A, C, D, F, H, K, and P areas to describe meteorological conditions at the central release location. Maximum individual dose estimates using both annual and short-term average air concentrations are well within 20% of the mean prediction. Population dose estimates are also within 20% of the mean prediction. Population dose estimates are also within 20% of the mean except for two-hour doses using H-Area meteorological data, which is less than the average estimate by about 30%.

The production of hydroxyl radicals by the radiolytic decomposition of water vapor following alpha decay of {sup 222}Rn can be used to produce an ultrafine sulfuric acid aerosol in the presence of SO{sub 2}. In the past, the production of this aerosol appeared to have a limiting threshold in as much as sufficient conversion of SO{sub 2} to SO{sub 4} must be attained to achieve the concentration required for nucleation. This appeared to occur when the bulk average acidity reached an adequately high value. The threshold curve for the onset of the sulfuric acid aerosol formation is a function of the H{sub 2}O, SO{sub 2} and Rn concentrations. The hydroxyl radical formation is dependent on the H{sub 2}O and Rn concentrations. The mass conversion rate of SO{sub 2} to H{sub 2}SO{sub 4} has been studied by measuring the airborne H{sub 2}SO{sub 4} concentration by ion chromatography after it has been collected on a filter and leached into solution. 39 refs., 9 figs.

We are developing an advanced process for treatment of mixed wastes in molten salt media at temperatures of 700--1000{degrees}C. Waste destruction has been demonstrated in a single stage oxidation process, with destruction efficiencies above 99.9999% for many waste categories. The molten salt provides a heat transfer medium, prevents thermal surges, and functions as an in situ scrubber to transform the acid-gas forming components of the waste into neutral salts and immobilizes potentially fugitive materials by a combination of particle wetting, encapsulation and chemical dissolution and solvation. Because the offgas is collected and assayed before release, and wastes containing toxic and radioactive materials are treated while immobilized in a condensed phase, the process avoids the problems sometimes associated with incineration processes. We are studying a potentially improved modification of this process, which treats oxidizable wastes in two stages: pyrolysis followed by catalyzed molten salt oxidation of the pyrolysis gases at ca. 700{degrees}C. 15 refs., 5 figs., 1 tab.

This research uses several techniques to measure the concentration of catalyst sites and determine their stoichiometry for the catalyzed gasification of carbon. Both alkali and alkaline earth oxides are effective catalysts for accelerating the gasification rate of coal chars, but only a fraction of the catalyst appears to be in a form that is effective for gasification, and the composition of that catalyst is not established. Transient techniques with {sup 13}C labeling, are being used to study the surface processes, to measure the concentration of active sites, and to determine the specific reaction rates. We have used secondary ion mass spectrometry (SIMS) for both high surface area samples of carbon/alkali carbonate mixtures and for model carbon surfaces with deposited alkali atoms. SIMS provides a direct measure of surface composition. The combination of these results can provide knowledge of catalyst dispersion and composition, and thus indicate the way to optimally utilize carbon gasification catalysts.

There are four basic eruption processes that produce volcanic ash: (1) decompression of rising magma, gas bubble growth, and fragmentation of the foamy magma in the volcanic vent (magmatic), (2) explosive mixing of magma with ground or surface water (hydrovolcanic), (3) fragmentation of country rock during rapid expansion of steam and/or hot water (phreatic), and (4) breakup of lava fragments during rapid transport from the vent. Variations in eruption style and the characteristics of volcanic ashes produced during explosive eruptions depend on many factors, including magmatic temperature, gas content, viscosity and crystal content of the magma before eruption, the ratio of magma to ground or surface water, and physical properties of the rock enclosing the vent. Volcanic ash is composed of rock and mineral fragments, and glass shards, which is less than 2 mm in diameter. Glass shard shapes and sizes depend upon size and shape of gas bubbles present within the magma immediately before eruption and the processes responsible for fragmentation of the magma. Shards range from slightly curved, thin glass plates, which were broken from large, thin-walled spherical bubble walls, to hollow needles broken from pumiceous melts containing gas bubbles stretched by magma flow within the volcanic vent. …

Autoionizing electrons emitted following low energy ion-atom collisions may scatter significantly from the receding spectator ion's attractive Coulomb field. In such cases the observed electron intensity is focused'' in the direction of the scattering ion as a result of the effective compression of the emission solid angle. In addition, interference may occur between trajectories, corresponding to electrons scattering around opposite sides of the ion, which lead to the same final laboratory electron energy and emission angle. This Coulomb path'' interference mechanism manifests itself in the uncharacteristically rapid angular dependence of the He target 2s{sup 2} {sup 1}S autoionizing state measured near 0{degree} following low energy He{sup +} + He collisions. A classical trajectory model for Coulomb focusing is presented and a semi-classical approximation is used to model the Coulomb path'' interference mechanism. In this description we account for the evolution of the phase of the autoionizing state until its decay and the path dependence of the amplitude of the emitted electron following decay of the autoionizing state. Calculated model lineshapes, which include contributions from adjacent overlapping resonances, reproduce quite well the angular dependence observed in the data near 0{degree}. 14 refs., 7 figs.

The major objectives of the project are to: (1) demonstrate the performance of three combustion NO{sub x} control technologies; (2) determine the short-term NO{sub x} emission trends for each of the operating configurations; (3) determine the dynamic long-term NO{sub x} emission characteristics for each of the operating configurations using sophisticated statistical techniques; (4) evaluate progressive cost-effectiveness (i.e., dollars per ton of NO{sub x} removed) of the low NO{sub x} combustion technologies tested; and (5) determine the effects on other combustion parameters (e.g., CO production, carbon carry-over, particulate characteristics) of applying the low NO{sub x} combustion technologies. (VC)

To provide high-energy, high-power beams at short wavelengths for inertial-confinement-fusion experiments, we routinely convert the 1.053-{mu}m output of the Nova, Nd:phosphate-glass, laser system to its third-harmonic wavelength. We describe performance and conversion efficiency modeling of the 3 {times} 3 arrays potassium-dihydrogen-phosphate crystal plates used for type II/type II phase-matched harmonic conversion of Nova 0.74-m diameter beams, and an alternate type I/type II phase-matching configuration that improves the third-harmonic conversion efficiency. These arrays provide energy conversion of up to 65% and intensity conversion to 70%. 19 refs., 11 figs.

None

TPC's (Time Projection Chamber) used in E-810 at the AGS (Alternating Gradient Synchrotron) were exposed to fluxes equivalent to more than 10{sup 7} minimum ionizing particles per second to find if such high fluxes cause gain changes or distortions of the electric field. Initial results of these and other tests are presented and the consequences for the RHIC (Relativistic Heavy Ion Collider) TPC-based experiments are discussed.

The objective of this project is to produce one or more microorganisms capable of removing the organic and inorganic sulfur in coal. The specific technical objectives of the project are to: clone and characterize the genes encoding the enzymes of the 4S'' pathway (sulfoxide/sulfone/sulfonate/sulfate) for release of organic sulfur from coal; return multiple copies of genes to the original host to enhance the biodesulfurization activity of that organism; transfer this pathway into a fast-growing chemolithotrophic bacterium; and conduct a batch-mode optimization/analysis of scale-up variables.

The calculation of downwind concentrations from non-traditional sources, such as explosions, provides unique challenges to dispersion models. The US Department of Energy has assigned the Atmospheric Release Advisory Capability (ARAC) at the Lawrence Livermore National Laboratory (LLNL) the task of estimating the impact of accidental radiological releases to the atmosphere anywhere in the world. Our experience includes responses to over 25 incidents in the past 16 years, and about 150 exercises a year. Examples of responses to explosive accidents include the 1980 Titan 2 missile fuel explosion near Damascus, Arkansas and the hydrogen gas explosion in the 1986 Chernobyl nuclear power plant accident. Based on judgment and experience, we frequently estimate the source geometry and the amount of toxic material aerosolized as well as its particle size distribution. To expedite our real-time response, we developed some automated algorithms and default assumptions about several potential sources. It is useful to know how well these algorithms perform against real-world measurements and how sensitive our dispersion model is to the potential range of input values. In this paper we present the algorithms we use to simulate explosive events, compare these methods with limited field data measurements, and analyze their sensitivity to input parameters. …

IWT was asked by J. R. Schornhorst of NPSR to determine the distribution of the quantity of enriched uranium per disposal box (B-25) of the years 1985--1991 to provide input to an uptake of the E Area Safety Analysis. This information was considered important since the issue of criticality is an important concern in safety analyses. Information found in the COBRA data base shows no disposal containers exceeded 100 grams of U-235. The COBRA data base was queried in a two-step process. First a short program in the NATURAL language was used to retrieve all records beginning with January 1983 having a Burial Code of less than 4, indicating low-level waste disposed in trenches. These records were then passed to a temporary storage file and read into a program written in Statistical Analysis System (SAS) language. SAS was used to eliminate waste from the Naval Fuel Facility, which will not operate in the future, and to sort the records in order of increasing amounts of U-235. The SAS procedure FREQ was then used to produce a cumulative frequency distribution of grams of U-235. A total of 53,198 packages were disposed of during this time period, 277 of which contained U-235. …

Recent results on decays of charm particles are presented. The CLEO collaboration has measured two body decay modes of D{sub s} involving {eta}, {eta}{sup 1} or {rho}{sup +}, using the new CLEO 2 detector. They also have new measurements of the branching ratios of the D{sup *0} and D{sup *+}. In charm baryon decays, results from CLEO 2 are presented for {Lambda}{sub c}{sup +} {yields} {Sigma}{sup 0}{pi}{sup +}, {Lambda}{sub c}{sup +} {yields} {Lambda}{pi}{sup +}{pi}{sup 0}, and the W-exchange process {Xi}{sub c}{sup 0} {yields} {Omega}{sup {minus}} K{sup +} has been observed in the CLEO 1 data. 31 refs., 20 figs., 6 tabs.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

A weekly publication, the Texas Register serves as the journal of state agency rulemaking for Texas. Information published in the Texas Register includes proposed, adopted, withdrawn and emergency rule actions, notices of state agency review of agency rules, governor's appointments, attorney general opinions, and miscellaneous documents such as requests for proposals. After adoption, these rulemaking actions are codified into the Texas Administrative Code.

TPC`s (Time Projection Chamber) used in E-810 at the AGS (Alternating Gradient Synchrotron) were exposed to fluxes equivalent to more than 10{sup 7} minimum ionizing particles per second to find if such high fluxes cause gain changes or distortions of the electric field. Initial results of these and other tests are presented and the consequences for the RHIC (Relativistic Heavy Ion Collider) TPC-based experiments are discussed.

This research uses several techniques to measure the concentration of catalyst sites and determine their stoichiometry for the catalyzed gasification of carbon. Both alkali and alkaline earth oxides are effective catalysts for accelerating the gasification rate of coal chars, but only a fraction of the catalyst appears to be in a form that is effective for gasification, and the composition of that catalyst is not established. Transient techniques with {sup 13}C labeling, are being used to study the surface processes, to measure the concentration of active sites, and to determine the specific reaction rates. We have used secondary ion mass spectrometry (SIMS) for both high surface area samples of carbon/alkali carbonate mixtures and for model carbon surfaces with deposited alkali atoms. SIMS provides a direct measure of surface composition. The combination of these results can provide knowledge of catalyst dispersion and composition, and thus indicate the way to optimally utilize carbon gasification catalysts.

We were able to predict acid concentration to {plus_minus}0.08M HNO{sub 3}. In the presence of Al{sup 3} interference, the prediction dropped to {plus_minus}0.29 mols/liter over the range 0 to 9M HNO{sub 3}. Temperature affects the prediction of acid adversely and would have to be modelled out or the sample cell thermostated prior to using this method. 10 refs, 12 figs.(DLC)

Radiological dose to the offsite maximum individual or the 50-mile population is often estimated assuming that operational atmospheric releases originate from the geographical center of the Savannah River Site. Historically, meteorological data collected from instrumentation on the H-Area tower have been utilized to estimate atmospheric dispersion from centrally located ``releases.`` This paper examines the effect on dose predictions using meteorological data from seven onsite towers located at A, C, D, F, H, K, and P areas to describe meteorological conditions at the central release location. Maximum individual dose estimates using both annual and short-term average air concentrations are well within 20% of the mean prediction. Population dose estimates are also within 20% of the mean prediction. Population dose estimates are also within 20% of the mean except for two-hour doses using H-Area meteorological data, which is less than the average estimate by about 30%.

Progress was reported on adsorption work in experimental, theoretical and field projects. The reinjection task is now nearing completion of the work on optimizing injection into the Palinpinon geothermal field in the Philippines. Well test analysis research has been expanded with the initiation of a new project on multiwell interference test interpretation.

Progress was reported on adsorption work in experimental, theoretical and field projects. The reinjection task is now nearing completion of the work on optimizing injection into the Palinpinon geothermal field in the Philippines. Well test analysis research has been expanded with the initiation of a new project on multiwell interference test interpretation.