Electrochemical arsenic remediation for rural Bangladesh (open access)

Electrochemical arsenic remediation for rural Bangladesh

Arsenic in drinking water is a major public health problem threatening the lives of over 140 million people worldwide. In Bangladesh alone, up to 57 million people drink arsenic-laden water from shallow wells. ElectroChemical Arsenic Remediation(ECAR) overcomes many of the obstacles that plague current technologies and can be used affordably and on a small-scale, allowing for rapid dissemination into Bangladesh to address this arsenic crisis. In this work, ECAR was shown to effectively reduce 550 - 580 mu g=L arsenic (including both As[III]and As[V]in a 1:1 ratio) to below the WHO recommended maximum limit of 10 mu g=L in synthetic Bangladesh groundwater containing relevant concentrations of competitive ions such as phosphate, silicate, and bicarbonate. Arsenic removal capacity was found to be approximately constant within certain ranges of current density, but was found to change substantially between ranges. In order of decreasing arsenic removal capacity, the pattern was: 0.02 mA=cm2> 0.07 mA=cm2> 0.30 - 1.1 mA=cm2> 5.0 - 100 mA=cm2. Current processing time was found to effect arsenic removal capacity independent of either charge density or current density. Electrode polarization studies showed no passivation of the electrode in the tested range (up to current density 10 mA=cm2) and ruled out oxygen …
Date: January 1, 2009
Creator: Addy, Susan Amrose
System: The UNT Digital Library
Extreme ultraviolet lithography: A few more pieces of the puzzle (open access)

Extreme ultraviolet lithography: A few more pieces of the puzzle

The work described in this dissertation has improved three essential components of extreme ultraviolet (EUV) lithography: exposure tools, photoresist, and metrology. Exposure tools. A field-averaging illumination stage is presented that enables nonuniform, high-coherence sources to be used in applications where highly uniform illumination is required. In an EUV implementation, it is shown that the illuminator achieves a 6.5% peak-to-valley intensity variation across the entire design field of view. In addition, a design for a stand-alone EUV printing tool capable of delivering 15 nm half-pitch sinusoidal fringes with available sources, gratings and nano-positioning stages is presented. It is shown that the proposed design delivers a near zero line-edge-rougness (LER) aerial image, something extremely attractive for the application of resist testing. Photoresist. Two new methods of quantifying the deprotection blur of EUV photoresists are described and experimentally demonstrated. The deprotection blur, LER, and sensitivity parameters of several EUV photoresists are quantified simultaneously as base weight percent, photoacid generator (PAG) weight percent, and post-exposure bake (PEB) temperature are varied. Two surprising results are found: (1) changing base weight percent does not significantly affect the deprotection blur of EUV photoresist, and (2) increasing PAG weight percent can simultaneously reduce LER and E-size in EUV …
Date: May 20, 2009
Creator: Anderson, Christopher N.
System: The UNT Digital Library
Measurement of CP Content and Time-Dependent CP Violation in B0 --> D*+D*- Decays (open access)

Measurement of CP Content and Time-Dependent CP Violation in B0 --> D*+D*- Decays

This dissertation presents the measurement of the Cp-odd fraction and time-dependent CP violation parameters for the B{sup 0} {yields} D*{sup +} D*{sup -} decay. These results are based on the full BABAR dataset of (467 {+-} 5) x 10{sup 6} B{bar B} pairs collected at the PEP-II B Factory at the Stanford Linear Accelerator Center. An angular analysis finds that the CP-odd fraction of the B{sup 0} {yields} D*{sup +} D*{sup -} decay is R{sub {perpendicular}} = 0.158 {+-} 0.028 {+-} 0.006, where the first uncertainty is statistical, and the second is systematic. A fit to the flavor-tagged, time-dependent, angular decay rate yields C{sub +} = 0.02 {+-} 0.12 {+-} 0.02; C{sub {perpendicular}} = 0.41 {+-} 0.50 {+-} 0.08; S{sub +} = -0.76 {+-} 0.16 {+-} 0.04; S{sub {perpendicular}} = -1.81 {+-} 0.71 {+-} 0.16, for the CP-odd ({perpendicular}) and CP-even (+) contributions. Constraining these two contributions to be the same results in C = 0.047 {+-} 0.091 {+-} 0.019; S = -0.71 {+-} 0.16 {+-} 0.03. These measurements are consistent with the Standard Model and with measurements of sin2{beta} from B{sup 0} {yields} (c{bar c})K{sup 0} decays.
Date: January 5, 2009
Creator: Anderson, Jacob M.
System: The UNT Digital Library
Search for the Standard Model Higgs Boson in the Missing Transverse Energy and b-jet signature in proton-antiproton collisions at a center-of-mass energy of 1.96 TeV (open access)

Search for the Standard Model Higgs Boson in the Missing Transverse Energy and b-jet signature in proton-antiproton collisions at a center-of-mass energy of 1.96 TeV

We report on the results of a search for the standard model Higgs boson produced in association with a W or Z boson in p{bar p} collisions at {radical}s = 1.96 TeV recorded by the CDF II experiment at the Tevatron in a data sample corresponding to an integrated luminosity of 2.1 fb{sup -1}. We consider events having no identified charged leptons, a large imbalance in transverse momentum, and two or three jets where at least one jet contains a secondary vertex consistent with the decay of a b hadron. The main backgrounds are modeled with innovative techniques using data. The sensitivity of the search is optimized using multivariate discriminant techniques. We find good agreement between data and the standard model predictions. We place 95% confidence level upper limits on production cross section times branching ratio for several Higgs boson masses ranging from 110 GeV=c{sup 2} to 150 GeV=c{sup 2}. For a mass of 115 GeV=c{sup 2} the observed (expected) limit is 6.9 (5.6) times the standard model prediction.
Date: May 1, 2009
Creator: Apresyan, Artur
System: The UNT Digital Library
Development of extreme ultraviolet and soft x-ray multilayer optics for scientific studies with femtosecond/attosecond sources (open access)

Development of extreme ultraviolet and soft x-ray multilayer optics for scientific studies with femtosecond/attosecond sources

The development of multilayer optics for extreme ultraviolet (EUV) radiation has led to advancements in many areas of science and technology, including materials studies, EUV lithography, water window microscopy, plasma imaging, and orbiting solar physics imaging. Recent developments in femtosecond and attosecond EUV pulse generation from sources such as high harmonic generation lasers, combined with the elemental and chemical specificity provided by EUV radiation, are opening new opportunities to study fundamental dynamic processes in materials. Critical to these efforts is the design and fabrication of multilayer optics to transport, focus, shape and image these ultra-fast pulses This thesis describes the design, fabrication, characterization, and application of multilayer optics for EUV femtosecond and attosecond scientific studies. Multilayer mirrors for bandwidth control, pulse shaping and compression, tri-material multilayers, and multilayers for polarization control are described. Characterization of multilayer optics, including measurement of material optical constants, reflectivity of multilayer mirrors, and metrology of reflected phases of the multilayer, which is critical to maintaining pulse size and shape, were performed. Two applications of these multilayer mirrors are detailed in the thesis. In the first application, broad bandwidth multilayers were used to characterize and measure sub-100 attosecond pulses from a high harmonic generation source and …
Date: May 21, 2009
Creator: Aquila, Andrew Lee
System: The UNT Digital Library
Muon neutrino disappearance at MINOS (open access)

Muon neutrino disappearance at MINOS

A strong case has been made by several experiments that neutrinos oscillate, although important questions remain as to the mechanisms and precise values of the parameters. In the standard picture, two parameters describe the nature of how the neutrinos oscillate: the mass-squared difference between states and the mixing angle. The purpose of this thesis is to use data from the MINOS experiment to precisely measure the parameters associated with oscillations first observed in studies of atmospheric neutrinos. MINOS utilizes two similar detectors to observe the oscillatory nature of neutrinos. The Near Detector, located 1 km from the source, observes the unoscillated energy spectrum while the Far Detector, located 735 km away, is positioned to see the oscillation signal. Using the data in the Near Detector, a prediction of the expected neutrino spectrum at the Far Detector assuming no oscillations is made. By comparing this prediction with the MINOS data, the atmospheric mixing parameters are measured to be {Delta}m{sub 32}{sup 2} = 2.45{sub +0.12}{sup -0.12} x 10{sub -3} eV{sup 2} and sin{sup 2}(2{theta}{sub 32}) = 1.00{sub -0.04}{sup +0.00} (> 0.90 at 90% confidence level).
Date: August 1, 2009
Creator: Armstrong, R.
System: The UNT Digital Library
Uncovering the single top: observation of electroweak top quark production (open access)

Uncovering the single top: observation of electroweak top quark production

The top quark is generally produced in quark and anti-quark pairs. However, the Standard Model also predicts the production of only one top quark which is mediated by the electroweak interaction, known as 'Single Top'. Single Top quark production is important because it provides a unique and direct way to measure the CKM matrix element V{sub tb}, and can be used to explore physics possibilities beyond the Standard Model predictions. This dissertation presents the results of the observation of Single Top using 2.3 fb{sup -1} of Data collected with the D0 detector at the Fermilab Tevatron collider. The analysis includes the Single Top muon+jets and electron+jets final states and employs Boosted Decision Tress as a method to separate the signal from the background. The resulting Single Top cross section measurement is: (1) {sigma}(p{bar p} {yields} tb + X, tqb + X) = 3.74{sub -0.74}{sup +0.95} pb, where the errors include both statistical and systematic uncertainties. The probability to measure a cross section at this value or higher in the absence of signal is p = 1.9 x 10{sup -6}. This corresponds to a standard deviation Gaussian equivalence of 4.6. When combining this result with two other analysis methods, the resulting …
Date: August 1, 2009
Creator: Benitez, Jorge Armando
System: The UNT Digital Library
Neutrino and antineutrino inclusive charged-current cross section measurement with the MINOS near detector (open access)

Neutrino and antineutrino inclusive charged-current cross section measurement with the MINOS near detector

This thesis presents the measurement of energy dependence of the neutrino-nucleon inclusive charged current cross section on an isoscalar target in the range 3-50 GeV for neutrinos and 5-50 GeV energy range for antineutrinos. The data set was collected with the MINOS Near Detector using the wide band NuMI beam at Fermilab. The size of the charged current sample is 1.94 x 10{sup 6} neutrino events and 1.60 x 10{sup 5} antineutrino events. The flux has been extracted using a low hadronic energy sub-sample of the charged current events. The energy dependence of the cross section is obtained by dividing the charged current sample with the extracted flux. The neutrino and antineutrino cross section exhibits a linear dependence on energy at high energy but shows deviations from linear behavior at low energy. We also present a measurement of the ratio of antineutrino to neutrino inclusive cross section.
Date: March 1, 2009
Creator: Bhattacharya, Debdatta & U., /Pittsburgh
System: The UNT Digital Library
Measurements of Time-Dependent CP-Asymmetry Parameters in B Meson Decays to \eta^{\prime} K^0 and of Branching Fractions of SU(3) Related Modes with BaBar Experiment at SLAC (open access)

Measurements of Time-Dependent CP-Asymmetry Parameters in B Meson Decays to \eta^{\prime} K^0 and of Branching Fractions of SU(3) Related Modes with BaBar Experiment at SLAC

In this thesis work we have measured the following upper limits at 90% of confidence level, for B meson decays (in units of 10{sup -6}), using a statistics of 465.0 x 10{sup 6} B{bar B} pairs: {Beta}(B{sup 0} {yields} {eta}K{sup 0}) < 1.6 {Beta}(B{sup 0} {yields} {eta}{eta}) < 1.4 {Beta}(B{sup 0} {yields} {eta}{prime}{eta}{prime}) < 2.1 {Beta}(B{sup 0} {yields} {eta}{phi}) < 0.52 {Beta}(B{sup 0} {yields} {eta}{omega}) < 1.6 {Beta}(B{sup 0} {yields} {eta}{prime}{phi}) < 1.2 {Beta}(B{sup 0} {yields} {eta}{prime}{omega}) < 1.7 We have no observation of any decay mode, statistical significance for our measurements is in the range 1.3-3.5 standard deviation. We have a 3.5{sigma} evidence for B {yields} {eta}{omega} and a 3.1 {sigma} evidence for B {yields} {eta}{prime}{omega}. The absence of observation of the B{sup 0} {yields} {eta}K{sup 0} open an issue related to the large difference compared to the charged mode B{sup +} {yields} {eta}K{sup +} branching fraction, which is measured to be 3.7 {+-} 0.4 {+-} 0.1 [118]. Our results represent substantial improvements of the previous ones [109, 110, 111] and are consistent with theoretical predictions. All these results were presented at Flavor Physics and CP Violation (FPCP) 2008 Conference, that took place in Taipei, Taiwan. They will be …
Date: January 22, 2009
Creator: Biassoni, Pietro & U., /Milan
System: The UNT Digital Library
Measurement of the Cross Section of Charmed Hadrons and the Nuclear Dependence Alpha (open access)

Measurement of the Cross Section of Charmed Hadrons and the Nuclear Dependence Alpha

With data from the SELEX experiment we study charm hadro-production. We report the differential production cross sections as function of the longitudinal and transverse momentum, as well as for two different target materials, of 14 charmed hadron and/or their decay modes. This is the most extensive study to date. SELEX is a fixed target experiment at Fermilab with high forward acceptance; it took data during 1996-1997 with 600 GeV/c {Sigma}{sup -} and {pi}{sup -}, and 540 GeV/c proton and {pi}{sup +} beams. It used 5 target foils (two copper and three diamond). We use the results to determine {alpha}, used in parametrizing the production cross section as {infinity} A{sup {alpha}}, where A is the mass number of the target nuclei. We found within our statistics that {alpha} is independent of the longitudinal momentum fraction x{sub F} in the interval 0.1 < x{sub F} < 1.0, with {alpha} = 0.778 {+-} 0.014. The average value of {alpha} for charm production by pion beams is {alpha}{sub meson} = 0.850 {+-} 0.028. This is somewhat larger than the corresponding average {alpha}{sub baryon} = 0.755 {+-} 0.016 for charm production by baryon beams ({Sigma}{sup -} and protons).
Date: December 1, 2009
Creator: Blanco-Covarrubias, E.Alejandro & U., /San Luis Potosi
System: The UNT Digital Library
Observation of excited state charge transfer with fs/ps-CARS (open access)

Observation of excited state charge transfer with fs/ps-CARS

Excited state charge transfer processes are studied using the fs/ps-CARS probe technique. This probe allows for multiplexed detection of Raman active vibrational modes. Systems studied include Michler's Ketone, Coumarin 120, 4-dimethylamino-4{prime}-nitrostilbene, and several others. The vibrational spectrum of the para di-substituted benzophenone Michler's Ketone in the first excited singlet state is studied for the first time. It is found that there are several vibrational modes indicative of structural changes of the excited molecule. A combined experimental and theoretical approach is used to study the simplest 7-amino-4-methylcoumarin, Coumarin 120. Vibrations observed in FTIR and spontaneous Raman spectra are assigned using density functional calculations and a continuum solvation model is used to predict how observed modes are affected upon inclusion of a solvent. The low frequency modes of the excited state charge transfer species 4-dimethylamino-4{prime}-nitrostilbene are studied in acetonitrile. Results are compared to previous work on this molecule in the fingerprint region. Finally, several partially completed projects and their implications are discussed. These include the two photon absorption of Coumarin 120, nanoconfinement in cyclodextrin cavities and sensitization of titania nanoparticles.
Date: August 1, 2009
Creator: Blom, Alex Jason
System: The UNT Digital Library
Measurement of electron neutrino appearance with the MINOS experiment (open access)

Measurement of electron neutrino appearance with the MINOS experiment

MINOS is a long-baseline two-detector neutrino oscillation experiment that uses a high intensity muon neutrino beam to investigate the phenomena of neutrino oscillations. By measuring the neutrino interactions in a detector near the neutrino source and again 735 km away from the production site, it is possible to probe the parameters governing neutrino oscillation. The majority of the {nu}{sub {mu}} oscillate to {nu}{sub {tau}} but a small fraction may oscillate instead to {nu}{sub e}. This thesis presents a measurement of the {nu}{sub e} appearance rate in the MINOS far detector using the first two years of exposure. Methods for constraining the far detector backgrounds using the near detector measurements is discussed and a technique for estimating the uncertainty on the background and signal selection are developed. A 1.6{sigma} excess over the expected background rate is found providing a hint of {nu}{sub e} appearance.
Date: May 1, 2009
Creator: Boehm, Joshua Adam Alpern & U., /Harvard
System: The UNT Digital Library
Ion distributions at charged aqueous surfaces: Synchrotron X-ray scattering studies (open access)

Ion distributions at charged aqueous surfaces: Synchrotron X-ray scattering studies

Surface sensitive synchrotron X-ray scattering studies were performed to obtain the distribution of monovalent ions next to a highly charged interface at room temperature. To control surface charge density, lipids, dihexadecyl hydrogen-phosphate (DHDP) and dimysteroyl phosphatidic acid (DMPA), were spread as monolayer materials at the air/water interface, containing CsI at various concentrations. Five decades in bulk concentrations (CsI) are investigated, demonstrating that the interfacial distribution is strongly dependent on bulk concentration. We show that this is due to the strong binding constant of hydronium H3O+ to the phosphate group, leading to proton-transfer back to the phosphate group and to a reduced surface charge. Using anomalous reflectivity off and at the L3 Cs+ resonance, we provide spatial counterion (Cs+) distributions next to the negatively charged interfaces. The experimental ion distributions are in excellent agreement with a renormalized surface charge Poisson-Boltzmann theory for monovalent ions without fitting parameters or additional assumptions. Energy Scans at four fixed momentum transfers under specular reflectivity conditions near the Cs+ L3 resonance were conducted on 10-3 M CsI with DHDP monolayer materials on the surface. The energy scans exhibit a periodic dependence on photon momentum transfer. The ion distributions obtained from the analysis are in excellent agreement …
Date: August 15, 2009
Creator: Bu, Wei
System: The UNT Digital Library
COUPLED MULTI-GROUP NEUTRON PHOTON TRANSPORT FOR THE SIMULATION OF HIGH-RESOLUTION GAMMA-RAY SPECTROSCOPY APPLICATIONS (open access)

COUPLED MULTI-GROUP NEUTRON PHOTON TRANSPORT FOR THE SIMULATION OF HIGH-RESOLUTION GAMMA-RAY SPECTROSCOPY APPLICATIONS

The accurate and efficient simulation of coupled neutron-photon problems is necessary for several important radiation detection applications. Examples include the detection of nuclear threats concealed in cargo containers and prompt gamma neutron activation analysis for nondestructive determination of elemental composition of unknown samples.
Date: August 1, 2009
Creator: Burns, Kimberly A.
System: The UNT Digital Library
Search for Lepton Flavour Violating Decays Tau -> l Ks with the BABAR Detector (open access)

Search for Lepton Flavour Violating Decays Tau -> l Ks with the BABAR Detector

We present the search for the lepton flavour violating decay {tau} {yields} lK{sup 0}{sub s} with the BaBar experiment data. This process and many other lepton flavour violating {tau} decays, like {tau} {yields} {mu}{gamma} and {tau} {yields} lll, are one of the most promising channel to search for evidence of new physics. According to the Standard Model and the neutrino mixing parameters, branching fractions are estimated well below 10{sup -14}, but many models of new physics allow for branching fractions values close to the present experimental sensitivity. This analysis is based on a data sample of 469fb{sup -1} collected by BABAR detector at the PEP-II storage ring from 1999 to 2007, equivalent to 431 millions of {tau} pairs. the BABAR experiment, initially designed for studying CP violation in B mesons, has demonstrated to be one of the most suitable environments for studying {tau} decays. The tracking system, the calorimeter and the particle identification of BABAR, together with the knowledge of the {tau} initial energy, allow an extremely powerful rejection of background events that, for this analysis, is better than 10{sup -9}. Being {tau} {yields} lK{sup 0}{sub s} a decay mode without neutrinos, the signal {tau} decay can be fully reconstructed. …
Date: March 20, 2009
Creator: Cenci, Riccardo
System: The UNT Digital Library
Indium Growth and Island Height Control on Si Submonolayer Phases (open access)

Indium Growth and Island Height Control on Si Submonolayer Phases

Nanotechnology refers any technique that involves about object with nanoscale (10{sup -9} m) or even smaller. It has become more and more important in recently years and has changed our world dramatically. Most of modern electronic devices today should thanks to the miniaturizing driven by development of nanotechnology. Recent years, more and more governments are investing huge amount of money in research related to nanotechnology. There are two major reasons that nanostructure is so fascinate. The first one is the miniaturizing. It is obvious that if we can make products smaller without losing the features, we can save the cost and increase the performance dramatically. For an example, the first computer in the world, ENIAC, which occupied several rooms, is less powerful than the cheapest calculator today. Today's chips with sizes of less than half an inch contain millions of basic units. All these should thank to the development of nanotechnology. The other reason is that when we come to nanoscale, there are many new effects due to the quantum effect which can't be found in large systems. For an example, quantum dots (QDs) are systems which sizes are below 1{micro}m(10{sup -6}m) and restricted in three dimensions. There are many …
Date: May 9, 2009
Creator: Chen, Jizhou
System: The UNT Digital Library
Search for the Standard Model Higgs boson in the missing energy topology with D0 (open access)

Search for the Standard Model Higgs boson in the missing energy topology with D0

A search for the Standard Model Higgs boson in the missing energy and acoplanar b-jet topology is reported, using an integrated luminosity of 0.93 fb{sup -1} recorded by the D0 detector at the Fermilab Tevatron p{bar p} Collider. The analysis includes signal contributions from p{bar p} {yields} ZH {yields} {nu}{bar {nu}}b{bar b}, as well as from WH production in which the charged lepton from the W boson decay is undetected. Neural networks are used to separate signal from background. In the absence of a signal, limits are set on {sigma}(p{bar p} {yields} VH) x B(H {yields} b{bar b}) at the 95% C.L. of 2.6-2.3 pb, for Higgs boson masses in the range 105-135 GeV, where V = W, Z. The corresponding expected limits range from 2.8 to 2.0 pb. Potential improvements to the analysis with an extended dataset totalling 4 fb{sup -1} are also discussed. Essential maintenance related to the increased luminosity and RunIIb upgrade was carried out on the impact parameter (IP) based b-tagging trigger tool and the effect of the changes on the b-tagger's performance was investigated.
Date: June 1, 2009
Creator: Christoudias, Theodoros
System: The UNT Digital Library
Search for the Standard Model Higgs Boson in associated production with w boson at the Tevatron (open access)

Search for the Standard Model Higgs Boson in associated production with w boson at the Tevatron

A search for the Standard Model Higgs boson in proton-antiproton collisions with center-of-mass energy 1.96 TeV at the Tevatron is presented in this dissertation. The process of interest is the associated production of W boson and Higgs boson, with the W boson decaying leptonically and the Higgs boson decaying into a pair of bottom quarks. The dataset in the analysis is accumulated by the D0 detector from April 2002 to April 2008 and corresponding to an integrated luminosity of 2.7 fb{sup -1}. The events are reconstructed and selected following the criteria of an isolated lepton, missing transverse energy and two jets. The D0 Neural Network b-jet identification algorithm is further used to discriminate b jets from light jets. A multivariate analysis combining Matrix Element and Neural Network methods is explored to improve the Higgs boson signal significance. No evidence of the Higgs boson is observed in this analysis. In consequence, an observed (expected) limit on the ratio of {sigma} (p{bar p} {yields} WH) x Br (H {yields} b{bar b}) to the Standard Model prediction is set to be 6.7 (6.4) at 95% C.L. for the Higgs boson with a mass of 115 GeV.
Date: November 1, 2009
Creator: Chun, Xu
System: The UNT Digital Library
Synthesis, characterization, and application of surface-functionalized ordered mesoporous nanoparticles (open access)

Synthesis, characterization, and application of surface-functionalized ordered mesoporous nanoparticles

The dissertation begins with Chapter 1, which is a general introduction of the fundamental synthesis of mesoporous silica materials, the selective functionlization of mesoporous silica materials, and the synthesis of nanostructured porous materials via nanocasting. In Chapter 2, the thermo-responsive polymer coated mesoporous silica nanoparticles (MSN) was synthesized via surface-initated polymerization and exhibited unique partition activities in a biphasic solution with the thermally induced change. In Chapter 3, the monodispersed spherical MSN with different mesoporous structure (MCM-48) was developed and employed as a template for the synthesis of mesoporous carbon nanoparticles (MCN) via nanocasting. MCN was demonstrated for the delivery of membrane impermeable chemical agents inside the cells. The cellular uptake efficiency and biocompabtibility of MCN with human cervical cancer cells were also investigated. In addition to the biocompabtibility of MCN, MCN was demonstrated to support Rh-Mn nanoparticles for catalytic reaction in Chapter 4. Owing to the unique mesoporosity, Rh-Mn nanoparticles can be well distributed inside the mesoporous structure and exhibited interesting catalytic performance on CO hydrogenation. In Chapter 5, the synthesis route of the aforementioned MCM-48 MSN was discussed and investigated in details and other metal oxide nanoparticles were also developed via nanocasting by using MCM-48 MSN as a …
Date: January 1, 2009
Creator: Chung, Po-Wen
System: The UNT Digital Library
Exposure-Relevant Ozone Chemistry in Occupied Spaces (open access)

Exposure-Relevant Ozone Chemistry in Occupied Spaces

Ozone, an ambient pollutant, is transformed into other airborne pollutants in the indoor environment. In this dissertation, the type and amount of byproducts that result from ozone reactions with common indoor surfaces, surface residues, and vapors were determined, pollutant concentrations were related to occupant exposure, and frameworks were developed to predict byproduct concentrations under various indoor conditions. In Chapter 2, an analysis is presented of secondary organic aerosol formation from the reaction of ozone with gas-phase, terpene-containing consumer products in small chamber experiments under conditions relevant for residential and commercial buildings. The full particle size distribution was continuously monitored, and ultrafine and fine particle concentrations were in the range of 10 to>300 mu g m-3. Particle nucleation and growth dynamics were characterized.Chapter 3 presents an investigation of ozone reactions with aircraft cabin surfaces including carpet, seat fabric, plastics, and laundered and worn clothing fabric. Small chamber experiments were used to determine ozone deposition velocities, ozone reaction probabilities, byproduct emission rates, and byproduct yields for each surface category. The most commonly detected byproducts included C1?C10 saturated aldehydes and skin oil oxidation products. For all materials, emission rates were higher with ozone than without. Experimental results were used to predict byproduct exposure …
Date: April 1, 2009
Creator: Coleman, Beverly Kaye
System: The UNT Digital Library
Searches for the Theta_s(1540)+ Strange-Pentaquark Candidate in e+e- Annihilation, Hadroproduction and Electroproduction with the BaBar Detector (open access)

Searches for the Theta_s(1540)+ Strange-Pentaquark Candidate in e+e- Annihilation, Hadroproduction and Electroproduction with the BaBar Detector

Since early in 2003, several experiments have presented evidence for the existence of a positive strangeness baryon state of mass around 1540 MeV/c{sup 2} and width <8 MeV, the {Theta}(1540), which decays to K{sup +}n and K{sup 0}p. Such a state has minimum quark content udud{bar s} and consequently has been interpreted as the S = +1 member of the anti-decuplet of pentaquark states proposed by Diakonov et al. Subsequently, the NA49 experiment presented evidence for the S = -2 member of the anti-decuplet, the {Xi}{sub 5}(1860){sup --}, but this has yet to be observed in any other experiment. Results from the search for the production of the {Theta}(1540) memember of the anti-decuplet of pentaquark states using data from e{sup +}e{sup -} collisions obtained with the BABAR detector at the PEP-II Collider are presented. No signal is observed, and cross section limits for the {Theta}(1540) are given; these prove to be well below the cross section values for ordinary baryons of similar mass. In addition, a search has been carried out for the electroproduction of the {Theta}(1540) in the material of the BABAR detector. Event selection procedures are discussed in detail, the results of this search are presented, and are …
Date: July 29, 2009
Creator: Coleman, Jonathan P.
System: The UNT Digital Library
Surface modes at metallic an photonic crystal interfaces (open access)

Surface modes at metallic an photonic crystal interfaces

A surface mode is an electromagnetic field distribution bounded at a surface. It decays exponentially with the distance from the surface on both sides of the surface and propagates at the surface. The surface mode exists at a metal-dielectric interface as surface plasmon (1) or at a photonic crystal surface terminated properly (34; 35; 36). Besides its prominent near-filed properties, it can connect structures at its propagation surface and results in far-field effects. Extraordinary transmission (EOT) and beaming are two examples and they are the subjects I am studying in this thesis. EOT means the transmission through holes in an opaque screen can be much larger than the geometrical optics limitation. Based on our everyday experience about shadows, the transmission equals the filling ratio of the holes in geometrical optics. The conventional diffraction theory also proved that the transmission through a subwavelength circular hole in an infinitely thin perfect electric conductor (PEC) film converges to zero when the hole's dimension is much smaller than the wavelength (40). Recently it is discovered that the transmission can be much larger than the the filling ratio of the holes at some special wavelengths (41). This cannot be explained by conventional theories, so it …
Date: January 1, 2009
Creator: Dai, Weitao
System: The UNT Digital Library
GAiN: Distributed Array Computation with Python (open access)

GAiN: Distributed Array Computation with Python

Scientific computing makes use of very large, multidimensional numerical arrays - typically, gigabytes to terabytes in size - much larger than can fit on even the largest single compute node. Such arrays must be distributed across a "cluster" of nodes. Global Arrays is a cluster-based software system from Battelle Pacific Northwest National Laboratory that enables an efficient, portable, and parallel shared-memory programming interface to manipulate these arrays. Written in and for the C and FORTRAN programming languages, it takes advantage of high-performance cluster interconnections to allow any node in the cluster to access data on any other node very rapidly. The "numpy" module is the de facto standard for numerical calculation in the Python programming language, a language whose use is growing rapidly in the scientific and engineering communities. numpy provides a powerful N-dimensional array class as well as other scientific computing capabilities. However, like the majority of the core Python modules, numpy is inherently serial. Our system, GAiN (Global Arrays in NumPy), is a parallel extension to Python that accesses Global Arrays through numpy. This allows parallel processing and/or larger problem sizes to be harnessed almost transparently within new or existing numpy programs.
Date: April 24, 2009
Creator: Daily, Jeffrey A.
System: The UNT Digital Library
Bioinspired synthesis of magnetic nanoparticles (open access)

Bioinspired synthesis of magnetic nanoparticles

The synthesis of magnetic nanoparticles has long been an area of active research. Magnetic nanoparticles can be used in a wide variety of applications such as magnetic inks, magnetic memory devices, drug delivery, magnetic resonance imaging (MRI) contrast agents, and pathogen detection in foods. In applications such as MRI, particle uniformity is particularly crucial, as is the magnetic response of the particles. Uniform magnetic particles with good magnetic properties are therefore required. One particularly effective technique for synthesizing nanoparticles involves biomineralization, which is a naturally occurring process that can produce highly complex nanostructures. Also, the technique involves mild conditions (ambient temperature and close to neutral pH) that make this approach suitable for a wide variety of materials. The term 'bioinspired' is important because biomineralization research is inspired by the naturally occurring process, which occurs in certain microorganisms called 'magnetotactic bacteria'. Magnetotactic bacteria use biomineralization proteins to produce magnetite crystals having very good uniformity in size and morphology. The bacteria use these magnetic particles to navigate according to external magnetic fields. Because these bacteria synthesize high quality crystals, research has focused on imitating aspects of this biomineralization in vitro. In particular, a biomineralization iron-binding protein found in a certain species of …
Date: May 26, 2009
Creator: David, Anand
System: The UNT Digital Library