This article demonstrates the methods of semi-synthesis and biocatalysis that can be used as modules in succession and in different combinations to produce 6,8-dibromogenkwanin, a derivative of the anticancer natural product apigenin.

Article discussing an experimental and kinetic modeling study of the interaction between C₂H₂ and NOx under flow reactor conditions in the intermediate temperature range (600–900 K), high pressure (50–60 bar), and for stoichiometries ranging from reducing to strongly oxidizing. The results show that presence of NOx serves both to sensitize and inhibit oxidation of C₂H₂.

Article discussing an investigation of the reaction of H + CS₂ products. The reaction was found to be pressure dependent and in the fall-off region or near the low pressure limit. Transition state theory yields an estimate for the high-pressure limit of addition over 290–300 K of 1.3 × 10−9 exp( −7.2 kJ mol −1 /RT) cm3 molecule −1 s −1. Uncertainties are discussed in the text.

Article discussing further analyses of the recent report (by Sandeepa et al.) on the solubility of benzoic acid in six monosolvents (i.e. tributyl phosphate, diacetone alcohol, methyl-n-propyl ketone, methyl acetate, amyl acetate, and isooctane) and five binary systems (i.e. ethanol + hexane, isopropyl alcohol + hexane and chloroform + hexane, acetone + hexane, and acetone + water) along with some numerical analyses. The reported calculations have been reanalyzed based on combined nearly ideal binary solvent/Redlich-Kister, the modified Wilson model, general single model, Jouyban–Acree model and Jouyban–Acree–van’t Hoff model. The investigated models provide good estimation of the solubility behavior of benzoic acid in the binary solvent mixtures at various temperatures.

Rate coefficients, k, for the gas-phase reaction of the OH radical with (E)CF3CHCHCF3 ((E)-1,1,1,4,4,4-hexafluoro-2-butene, HFO-1336mzz(E)) were measured over a range of temperatures (211−374 K) and bath gas pressures (20−300 Torr; He, N2) using a pulsed laser photolysis−laser-induced fluorescence (PLP−LIF) technique. k1(T) was independent of pressure over this range of conditions with k1(296 K) = (1.31 ± 0.15) × 10−13 cm3 molecule−1 s−1 and k1(T) = (6.94 ± 0.80) × 10−13exp[−(496 ± 10)/T] cm 3 molecule−1 s−1, where the uncertainties are 2σ, and the pre-exponential term includes estimated systematic error. Rate coefficients for the OD reaction were also determined over a range of temperatures (262−374 K) at 100 Torr (He). The OD rate coefficients were ∼15% greater than the OH values and showed similar temperature dependent behavior with k2(T) = (7.52 ± 0.44) × 10−13exp[−(476 ± 20)/T] and k2(296 K) = (1.53 ± 0.15) × 10−13 cm3 molecule−1 s−1. The rate coefficients for reaction 1 were also measured using a relative rate technique between 296 and 375 K with k1(296 K) measured to be (1.22 ± 0.1) × 10−13 cm3 molecule−1 s−1, in agreement with the PLP−LIF results. In addition, the 296 K rate coefficient for the O3 +( E)CF3CHCHCF3 reaction …

This article investigates age-related changes in Ginkgo biloba trees to learn more about the molecular and metabolic mechanisms underlying their longevity. The results revealed that long-lived trees have evolved compensatory mechanisms to maintain a balance between growth and aging processes.

This article tested the cross-species application of the Affymetrix 600K Chicken SNP array in five species of North American prairie grouse (Centrocercus and Tympanuchus genera). This study study provided evidence for successful cross-species application of the chicken SNP array in grouse which diverged ca. 37 mya from the chicken lineage. As far as the authors are concerned, this is the first reported application of a SNP array in non-passerine birds, and it demonstrates the feasibility of using commercial SNP arrays in research on non-model bird species.

This article describes a new methodology for monitoring sucrose labeling using liquid chromatography tandem mass spectrometry (LC-MS/MS). To date, the most commonly used method to monitor sucrose labeling is by nuclear magnetic resonance, which requires substantial amounts of biological sample.

This article tested the cross-species application of the Affymetrix 600K Chicken SNP array in five species of North American prairie grouse (Centrocercus and Tympanuchus genera). Two individuals were genotyped per species for a total of ten samples and a high proportion (91%) of the total 580 961 SNPs were genotyped in at least one individual (73–76% SNPs genotyped per species).

This article looks at molecules that can exist in multiple states with the possibility of toggling between those states based on different stimuli. They have potential for use in molecular switching or sensing applications. The coupling of two different oxidation states with two different charge-transfer states within one macrocyclic scaffold delivers up to five different optical outputs. This molecular switching manifold exploits intramolecular coupling of multiple redox active substituents within a single molecule.

This article establishes a clear distinction between two processes yielding anomalous diffusion and 1/ f noise. One of the processes, Aging Fractional Brownian Motion (AFBM), has been concluded to be the form of communication between the heart and the brain.

This article highlights a connection between Diophantine approximation and the lower Assouad dimension by using information about the latter to show that the Hausdorff dimension of the set of badly approximable points that lie in certain non-conformal fractals, known as self-affine sponges, is bounded below by the dynamical dimension of these fractals. The results, which are the first to advance beyond the conformal setting, encompass both the case of Sierpiński sponges/carpets (also known as Bedford–McMullen sponges/carpets) and the case of Barański carpets.

This is a correction of a previously released article. A mistake was found in Figure 2 of the published work. The names of the cell types, “mesophyll cell” and “bundle sheath” were erroneously interchanged.

The article evaluates the impacts of physical, chemical and genetic interventions to improve biomass processing singly and in combination. Based on their results and literature studies, some form of non-biological augmentation will likely be necessary for the foreseeable future to achieve high total carbohydrate solubilization (TCS) for most cellulosic feedstocks. The results show that this need not necessarily involve thermochemical processing, and need not necessarily occur prior to biological conversion.

The article shows how a recently-introduced method from algebraic topology, namely proximal planar vortex 1-cycles, might be helpful in detecting hidden features of the shapes and holes in images, therefore contributing to the solution of both cold and fresh forensic cases. They apply this technique in a recent case, Aldo Moro's death.

This article explores restoration, rather than protection, being the basis for developing a watershed level strategy for improving water quality in urbanizing watersheds.This study uses a geographical information system (GIS) approach that utilizes riparian characteristics extracted from 40-meter wide corridors centered on streams and rivers. The model was applied to 90 sub-watersheds in the watershed of an important drinking water reservoir in north central Texas, USA.

The dataset was developed to support research intended to develop a spatially explicit model that explores environmental data related to the risk of exposure to West Nile Virus (WNV), and the susceptibility to WNV disease based on demographic data of the potentially affected population. The model was developed and then tested on census tracts in an identified hot spot of WNV in central California. The dataset contains (1) U.S. Census Bureau 2010 demographic data for 1,133 census tracks in the hotspot, and (2) and average mosquito habitat risk data for each of those census tracks.

Paper discusses metabolomics studies that link changes in primary or specialized metabolism to the defense responses of plants against bacterial, fungal, nematode, and viral pathogens.

Describes study which assessed the upper (CTmax) and lower (CTmin) thermal limits of three freshwater macroinvertebrate taxa with restricted low elevation distribution (20 m a.s.l.) and three taxa restricted to upper elevations (480 and 700 m a.s.l.) in the Magellanic sub-Antarctic ecoregion of southern Chile, and argues that their low tolerance to temperature increase can make them useful as indicators of thermal alteration in their habitats.

This article is taken from the Proceedings of the 5th International Symposium on Sensor Science (I3S 2017). Molecularly imprinted polymers (MIPs) can be used in applications in selective chemosensing.

This article presents the analysis of genetic mouse models of synovial sarcoma to determine the extent of ossification in the tumors and its relationship with morbidity. The authors noted higher ossification within their metastatic mouse model of synovial sarcoma. Their conclusion is that both metastasis and ossification are dependent on time, but that they are independent of one another.

This article is a simplified analysis of a convenient thulium fiber laser source with 3 W of output power operating at a wavelength of 2059 nm with a slope efficiency of 49% with respect to input pump power and 60% with respect to absorbed pump power. The laser was applied in an atomic helium spectroscopy experiment to quench ³He (2058.63 nm) and ⁴He (2058.69 nm) meta-stable singlets (2¹S0), allowing for further investigation of the helium fine structure.

This abstract introduces the development of an inventive new technique for protein imprinting.

This article focuses on the effects of mild annealing on the structural and physical properties of the MoS₂ by heating the nanosheets in air and vacuum up to 350 °C. It was found that the annealing leads to an increase in resistivity for the nanosheets by 3 orders of magnitude, the appearance of two absorption bands in the visible range, and a hydrophilic to hydrophobic change in the surface wetting properties. Overall, this study provides another way to control the electrical, optical, and surface properties of MoS₂ nanosheets for fulfilling the needs of various applications.