This article investigates the role of the highly conserved α,β-hydrolase enzymes PyiE and ORFZ during the biosynthesis of pyrichalasin H and the ACE1 metabolite, respectively, using gene knockout and complementation techniques. Taken together the results suggest that the α,β-hydrolase enzymes are essential for first ring cyclisation, but the precise nature of the intermediates remains to be determined.

Article asserts that ammonia (NH3) is a promising carbon-free energy carrier. The authors used experimental characterization and modeling to study the participation of alkali and sulfur species in ammonia conversion in a post-flame environment, focusing on the characteristics of NO emissions and NH3 slip.

This article reports pyrazinacenes containing the dihydro-decaazapentacene and dihydro-octaazatetracene chromophores and compares their properties/functions as a model case at an oxidizing metal substrate.

Article analyzing dispersion of sound in a solid-fluid layered structure and found a flex point on the isofrequency curve where D vanishes for given direction of propagation and frequency. Nonspreading propagation is experimentally observed in a water steel lattice of 75 periods (~1 meter long) and occurs in the regime of anomalous dispersion and strong acoustic anisotropy when the effective mass along periodicity is close to zero. Under these conditions the incoming beam experiences negative refraction of phase velocity leading to backward wave propagation. The observed effect is explained using a complete set of dynamical equations and our effective medium theory.

This article applies a developmental 3-dimensional critical window experimental design for a vertebrate, using time, temperature, and phenotypic response (i.e., variables measured). To assess thermal effects on fish development, the authors examined trout hatchling phenotypes following rearing in constant temperatures (5, 10, 15 and 17.5 °C) and following exposure to increased temperature above 5 °C during specific developmental windows.

This article describes the recent re-design of the code and the new features and improvements in performance of PAOFLOW, a software tool that constructs tight-binding Hamiltonians from self-consistent electronic wavefunctions by projecting onto a set of atomic orbitals.

Article describes study which found that persistent, recurring blood oxygen level dependent (BOLD) signals in triangulated rs-fMRI videoframes display previously undetected topological findings, i.e., vortex structures that cover brain activated regions.

This article is a dataset that describes behavioral results in zebrafish (Danio rerio) individually exposed to methanol, a solvent which is capable of altering physiology and behavior high concentrations.

This article analyzes the historical spatiotemporal behavior of the huemul (Hippocamelus bisulcus), an endangered deer endemic to Patagonia. Losing migratory traditions is a major threat, and may explain their presently prevalent skeletal diseases, reduced longevity, and lacking recolonizations for most remaining huemul subpopulations.

Article reviews recent evidence that protein–protein interactions in each of the three major phases of oil formation appear to have profound effects on specialized oil accumulation. This article is part of the special issue: Physiology and metabolism (2022).

Article exploring the association between second-hand smoke exposure, asthma, and asthma severity in children ages 6-17 as well as the effect of birth weight and prematurity (BWP) on parental smoking and asthma. Results indicate that focused asthma interventions in children should inquire about BWP status as well as parental smoking and household smoke exposure to reduce asthma morbidity and mortality.

This review article calls for establishing the CaMV 35S promoter as a quantitative reference standard for transcription activity in plants.

Article prepares and characterizes a small series of new [FeFe]-ase biomimics which contain a ferrocenyl diphosphine as a surrogate for the Fe₄S₄ moiety in the H-cluster of the enzyme. Mechanistic details of both proton reduction and H₂ oxidation have been studied by DFT allowing speculative reaction schemes to be developed.

Article investigating the utility of the non-biological element tellurium as a replacement for the widely biologically-utilized lighter chalcogenides sulfur and selenium in the realm of proton-reduction catalysis.

Article presenting research where twenty clusters of the general formula [(μ-H)₂Ru₃(μ₃-S)(CO)₇(μ-P–P*)] (P–P* = chiral diphosphine of the ferrocene-based Walphos or Josiphos families) have been synthesised and characterised.

Article modeling Metal-based bifunctional methane activators using density functional theory. The research yields insight into possible avenues for bio-inspired methane activators.

This article's aim is to determine whether (a) the spatial use of domestic dogs increases with habitat destruction, and (b) domestic dogs and habitat destruction drive the spatial use of native carnivores in a heavily degraded agricultural landscape. Conclusions highlight that domestic dog occupancy was positively correlated with habitat loss and future conditions of increased fragmentation and habitat loss will likely increase the potential contact between domestic dogs and native carnivores.

Article presents an overview of two successful examples of photosynthetic reaction center models combined with light-capturing antenna chromophores. This article is part of the JSS Focus Issue on Porphyrins, Phthalocyanines, and Supramolecular Assemblies in Honor of Karl M. Kadish.

Article presenting research where an electropolymerizable zinc porphyrin carrying eight entities of peripheral bithiophene, 4 was newly designed and synthesized.

Presentation on using a flipped course format and including an open textbook, OpenStax: Chemistry 2e. Flipped courses provide lecture content that is accessible online, and they use class time for active learning activities. It is a part of 2022 University of North Texas Open Access Symposium that was held on March 8, 2022.

This article simulates Antihydrogen formation involving magnetobound positronium by computing classical trajectories.

Article presents thin film analogs of practical catalysts that allow for the implementation of surface characterization tools, including advanced microscopy and operando spectroscopy methodologies.

This article discusses closed-form expressions for the magnetic fields produced by rectangular- and circular-shaped finite-length solenoids and current loops. The closed-form expression for the magnetic field of a rectangular-shaped finite-length solenoid is derived using the Biot–Savart law. Closed-form expressions for the magnetic fields of solenoids and current loops can be used to avoid approximations in analytical models and may reduce computation time in computer simulations.

Article is a study highlighting the mechanistic understanding of the dissolution process of SE415 by biocompatible PEG 400 in the (PEG 400 + water) cosolvent mixture using HSPs, Kirkwood–Buff integrals, and thermodynamic functional parameters for solubility.