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Temperature dependent rate coefficients for the gas-phase OH + Furan-2,5-dione (C4H2O3, maleic anhydride) reaction (open access)

Temperature dependent rate coefficients for the gas-phase OH + Furan-2,5-dione (C4H2O3, maleic anhydride) reaction

Authors of the article assert that rate coefficients, k1(T), for the gas-phase reaction of the OH radical with Furan-2,5-dione (maleic anhydride (MA), C4H2O3), a biomass burning related compound, were measured under pseudo first-order conditions in OH using the pulsed laser photolysis - laser induced fluorescence method over a range of temperature and bath gas pressure. Their results are compared with a previous room temperature relative rate study of the OH + MA reaction and significant discrepancy between the studies is discussed. This is the accepted manuscript version of the published article.
Date: May 30, 2020
Creator: Chattopadhyay, Aparajeo; Papadimitriou, Vassileios C.; Marshall, Paul & Burkholder, James B. (James Bart), 1954-
Object Type: Article
System: The UNT Digital Library
Oxidation of methylamine (open access)

Oxidation of methylamine

Article describes how a detailed chemical kinetic model for oxidation of methylamine has been developed, based on theoretical work and a critical evaluation of data from the literature. The mechanism was validated against experimental results from batch reactors, flow reactors, shock tubes, and premixed flames. This is the accepted manuscript version of the published article.
Date: August 5, 2020
Creator: Glarborg, Peter; Andreasen, Charlotte S.; Hashemi, Hamid; Qian, Rachel & Marshall, Paul
Object Type: Article
System: The UNT Digital Library
On Polish groups admitting non-essentially countable actions (open access)

On Polish groups admitting non-essentially countable actions

Article addresses the question whether every Polish group that is not locally compact admits a Borel action on a standard Borel space whose associated orbit equivalence relation is not essentially countable. The authors e answer this question positively for the class of all Polish groups that embed in the isometry group of a locally compact metric space.
Date: September 17, 2019
Creator: Kechris, Alexander S.; Malicki, Maciej; Panagiotopoulos, Aristotelis & Zielinski, Joseph
Object Type: Article
System: The UNT Digital Library
Protein Determination with Molecularly Imprinted Polymer Recognition Combined with Birefringence Liquid Crystal Detection (open access)

Protein Determination with Molecularly Imprinted Polymer Recognition Combined with Birefringence Liquid Crystal Detection

Article integrating a molecularly imprinted polymer (MIP) film recognition unit with a liquid crystal (LC) in an optical cell transducer to incur the selectivity of liquid crystal-based sensors.
Date: August 20, 2020
Creator: Cieplak, Maciej; Węgłowski, Rafał; Iskierko, Z.; Węgłowska, Dorota; Sharma, Piyush S.; Noworyta, Krzysztof R. et al.
Object Type: Article
System: The UNT Digital Library
Long-range nonspreading propagation of sound beam through periodic layered structure (open access)

Long-range nonspreading propagation of sound beam through periodic layered structure

Article analyzing dispersion of sound in a solid-fluid layered structure and found a flex point on the isofrequency curve where D vanishes for given direction of propagation and frequency. Nonspreading propagation is experimentally observed in a water steel lattice of 75 periods (~1 meter long) and occurs in the regime of anomalous dispersion and strong acoustic anisotropy when the effective mass along periodicity is close to zero. Under these conditions the incoming beam experiences negative refraction of phase velocity leading to backward wave propagation. The observed effect is explained using a complete set of dynamical equations and our effective medium theory.
Date: September 2, 2020
Creator: Zubov, Yurii; Djafari-Rouhani, Bahram; Jin, Yuqi; Sofield, Mathew; Walker, Ezekiel; Neogi, Arup et al.
Object Type: Article
System: The UNT Digital Library
RNaseH-mediated simultaneous piggyback knockdown of multiple genes in adult zebrafish (open access)

RNaseH-mediated simultaneous piggyback knockdown of multiple genes in adult zebrafish

This article tests if it is possible to piggyback more than one antisense deoxyoligonucleotide (dO) with one vivo morpholino (VMO). The authors previously developed a piggyback knockdown method that was used to knockdown genes in adult zebrafish. In this article, the authors develop a method to knockdown three genes at one time, and by increasing the concentration of VMO by twofold, could knockdown six genes simultaneously. These multiple gene knockdowns will not only increase the efficiency of the method in whole genome-wide knockdowns but will also be useful to study multifactorial disorders.
Date: November 19, 2020
Creator: Raman, Revathi; Ryon, Mia & Jagadeeswaran, Pudur
Object Type: Article
System: The UNT Digital Library
Anisotropic optical properties of single Si2Te3 nanoplates (open access)

Anisotropic optical properties of single Si2Te3 nanoplates

Article reporting a combined experimental and computational study of the optical properties of individual silicon telluride (Si2Te3) nanoplates.
Date: November 5, 2020
Creator: Chen, Jiyang; Bhattarai, Romakanta; Cui, Jingbiao; Shen, Xiao & Hoang, Thang
Object Type: Article
System: The UNT Digital Library
Sub-wavelength lateral detection of tissue-approximating masses using an ultrasonic metamaterial lens (open access)

Sub-wavelength lateral detection of tissue-approximating masses using an ultrasonic metamaterial lens

Article demonstrating a phononic metamaterial lens (ML) for detection of laterally subwavelength object features in tissue-like phantoms beyond the phononic crystal evanescent zone and Fresnel zone of the emitter.
Date: November 24, 2020
Creator: Walker, Ezekiel; Jin, Yuqi; Reyes, Delfino & Neogi, Arup
Object Type: Article
System: The UNT Digital Library
Efficient separation of xylene isomers by a guest-responsive metal–organic framework with rotational anionic sites (open access)

Efficient separation of xylene isomers by a guest-responsive metal–organic framework with rotational anionic sites

Article demonstrating the adaptively molecular discrimination of xylene isomers by employing a NbOF52−-pillared metal–organic framework (NbOFFIVE-bpy-Ni, also referred to as ZU-61) with rotational anionic sites.
Date: October 28, 2020
Creator: Cui, Xili; Niu, Zheng; Shan, Chuan; Yang, Lifeng; Hu, Jianbo; Wang, Qingju et al.
Object Type: Article
System: The UNT Digital Library
Multitask deep-learning-based design of chiral plasmonic metamaterials (open access)

Multitask deep-learning-based design of chiral plasmonic metamaterials

This article presents an end-to-end functional bidirectional deep-learning (DL) model for three-dimensional chiral metamaterial design and optimization. This ML model utilizes multitask joint learning features to recognize, generalize, and explore in detail the nontrivial relationship between the metamaterials’ geometry and their chiroptical response, eliminating the need for auxiliary networks or equivalent approaches to stabilize the physically relevant output. This model efficiently realizes both forward and inverse retrieval tasks with great precision, offering a promising tool for iterative computational design tasks in complex physical systems. Other potential applications include photodetectors, polarization-resolved imaging, and circular dichroism (CD) spectroscopy.
Date: July 1, 2020
Creator: Ashalley, Eric; Acheampong, Kingsley; Besteiro, Lucas V.; Yu, Peng; Neogi, Arup; Govorov, Alexander O. et al.
Object Type: Article
System: The UNT Digital Library
MYB30 Orchestrates Systemic Reactive Oxygen Signaling and Plant Acclimation (open access)

MYB30 Orchestrates Systemic Reactive Oxygen Signaling and Plant Acclimation

This article explores the relationship among MYB30, the ROS wave, and systemic acclimation in Arabidopsis by determining the SAA response to HL stress of MYB30 mutants and wild-type plants.
Date: July 22, 2020
Creator: Fichman, Yosef; Zandalinas, Sara I.; Sengupta, Soham; Burks, David J.; Meyers, Ronald J., Jr.; Azad, Rajeev K. et al.
Object Type: Article
System: The UNT Digital Library
Proanthocyanidin Biosynthesis—a Matter of Protection (open access)

Proanthocyanidin Biosynthesis—a Matter of Protection

Article discussing key questions and opportunities in the field of Proanthocyanidins (PA) biosynthesis.
Date: August 18, 2020
Creator: Dixon, R. A. & Sarnala, Sai
Object Type: Article
System: The UNT Digital Library
Seedling Chloroplast Responses Induced by N-Linolenoylethanolamine Require Intact G-Protein Complexes (open access)

Seedling Chloroplast Responses Induced by N-Linolenoylethanolamine Require Intact G-Protein Complexes

This article shows that the activity of N-linolenoylethanolamine (NAE 18:3) requires an intact G-protein complex. Specifically, genetic ablation of the Gβγ dimer or loss of the full set of atypical Gα subunits strongly attenuates an NAE-18:3–induced degreening of cotyledons in Arabidopsis (Arabidopsis thaliana) seedlings. This effect involves, at least in part, transcriptional regulation of chlorophyll biosynthesis and catabolism genes. In addition, there is feedforward transcriptional control of G-protein signaling components and G-protein interactors. These results are consistent with NAE 18:3 being a lipid signaling molecule in plants with a requirement for G-proteins to mediate signal transduction, a situation similar, but not identical, to the action of NAE endocannabinoids in animal systems.
Date: July 14, 2020
Creator: Yan, Chengshi; Cannon, Ashley E.; Watkins, Justin; Keereetaweep, Jantana; Khan, Bibi Rafeiza; Jones, Alan M. et al.
Object Type: Article
System: The UNT Digital Library
SEIPIN Isoforms Interact with the Membrane-Tethering Protein VAP27-1 for Lipid Droplet Formation (open access)

SEIPIN Isoforms Interact with the Membrane-Tethering Protein VAP27-1 for Lipid Droplet Formation

Article demonstrating that part of the function of two SEIPIN isoforms in Arabidopsis (Arabidopsis thaliana), AtSEIPIN2 and AtSEIPIN3, may depend on their interaction with the vesicle-associated membrane protein (VAMP)–associated protein (VAP) family member AtVAP27-1. The authors used a combination of biochemical, cell biology, and genetics approaches to show that AtVAP27-1 interacts with the N termini of AtSEIPIN2 and AtSEIPIN3 and likely supports the normal formation of LDs. This insight indicates that the ER membrane tethering machinery in plant cells could play a role with select SEIPIN isoforms in LD biogenesis at the ER, and additional experimental evidence in Saccharomyces cerevisiae supports the possibility that this interaction may be important in other eukaryotic systems.
Date: July 20, 2020
Creator: Greer, Michael Scott; Cai, Yingqi; Gidda, Satinder K.; Esnay, Nicolas; Kretzschmar, Franziska K.; Seay, Damien C. et al.
Object Type: Article
System: The UNT Digital Library
Cellular Plasticity in Response to Suppression of Storage Proteins in the Brassica napus Embryo (open access)

Cellular Plasticity in Response to Suppression of Storage Proteins in the Brassica napus Embryo

Article testing the tradeoff between protein and oil storage in oilseed crops by analyzing the effect of suppressing key genes encoding protein storage products (napin and cruciferin). This study provides mechanistic insights into the intriguing link between lipid and protein storage, which have implications for biotechnological strategies directed at improving oilseed crops.
Date: April 30, 2020
Creator: Rolletschek, Hardy; Schwender, Jorg; König, Christina; Chapman, Kent Dean; Romsdahl, Trevor; Lorenz, Christin et al.
Object Type: Article
System: The UNT Digital Library
Substrate Specificity of LACCASE8 Facilitates Polymerization of Caffeyl Alcohol for C-Lignin Biosynthesis in the Seed Coat of Cleome hassleriana (open access)

Substrate Specificity of LACCASE8 Facilitates Polymerization of Caffeyl Alcohol for C-Lignin Biosynthesis in the Seed Coat of Cleome hassleriana

This article finds that the transcript profile of the laccase gene ChLAC8 parallels the accumulation of C-lignin during seed coat development. Recombinant ChLAC8 oxidizes caffeyl and sinapyl alcohols, generating their corresponding dimers or trimers in vitro, but cannot oxidize coniferyl alcohol. The authors propose a basis for this substrate preference based on molecular modeling/docking experiments. Suppression of ChLAC8 expression led to significantly reduced C-lignin content in the seed coats of transgenic Cleome plants. Feeding of 13C-caffeyl alcohol to the Arabidopsis (Arabidopsis thaliana) caffeic acid o-methyltransferase mutant resulted in no incorporation of 13C into C-lignin, but expressing ChLAC8 in this genetic background led to appearance of C-lignin with >40% label incorporation. These results indicate that ChLAC8 is required for C-lignin polymerization and determines lignin composition when caffeyl alcohol is available.
Date: October 9, 2020
Creator: Wang, Xin; Zhuo, Chunliu; Xiao, Xirong; Wang, Xiaoqiang; Docampo-Palacios, Maite; Chen, Fang et al.
Object Type: Article
System: The UNT Digital Library
Leaf Lipid Alterations in Response to Heat Stress of Arabidopsis thaliana (open access)

Leaf Lipid Alterations in Response to Heat Stress of Arabidopsis thaliana

Article measuring lipid levels with mass spectrometry to confirm the previously observed changes in Arabidopsis thaliana leaf lipids under three heat stress regimens. Additionally, in response to heat, increased oxidation of the fatty acyl chains of leaf galactolipids, sulfoquinovosyldiacylglycerols, and phosphatidylglycerols, and incorporation of oxidized acyl chains into acylated monogalactosyldiacylglycerols are shown. The authors also observed increased levels of digalactosylmonoacylglycerols and monogalactosylmonoacylglycerols. The hypothesis that a defect in sterol glycosylation would adversely affect regrowth of plants after a severe heat stress regimen was tested, but differences between wild-type and sterol glycosylation-defective plants were not detected.
Date: July 4, 2020
Creator: Shiva, Sunitha; Samarakoon, Thilani; Lowe, Kaleb A.; Roach, Charles; Vu, Hieu Sy; Colter, Madeline et al.
Object Type: Article
System: The UNT Digital Library
In vitro anti-diabetic effects and phytochemical profiling of novel varieties of Cinnamomum zeylanicum (L.) extracts (open access)

In vitro anti-diabetic effects and phytochemical profiling of novel varieties of Cinnamomum zeylanicum (L.) extracts

Article exploring the use of pressured and decoctions water to extract anti-diabetic phytochemicals from cinnamon. The extensive metabolite profiling of novel SW and SG extracts and comparison of that with commercially available CC are reported for the first time in this study. The C. zeylanicum, SW accession holds some promise in the management of diabetes.
Date: April 27, 2020
Creator: Wariyapperuma, W.A. Niroshani M.; Kannangara, Sagarika; Wijayasinghe, Yasanandana S.; Subramanium, Sri & Jayawardena, Bimali
Object Type: Article
System: The UNT Digital Library
Using a Novel Approach to Estimate Packing Density and Related Electrical Resistance in Multiwall Carbon Nanotube Networks (open access)

Using a Novel Approach to Estimate Packing Density and Related Electrical Resistance in Multiwall Carbon Nanotube Networks

Article using contrast image processing to estimate the concentration of multi-wall carbon nanotubes (MWCNT) in a given network.
Date: September 25, 2020
Creator: Philipose, Usha; Jiang, Yan; Farmer, Gavin; Howard, Chris; Harcrow, Michael; Littler, Chris et al.
Object Type: Article
System: The UNT Digital Library
Workflow for the Quantification of Soluble and Insoluble Carbohydrates in Soybean Seed (open access)

Workflow for the Quantification of Soluble and Insoluble Carbohydrates in Soybean Seed

This article develops and validates a sequential protocol for quantifying reserve and structural carbohydrates in soybean seed. It was successfully applied to eight soybean genotypes harvested from two locations, and the resulting correlations of carbohydrate and oil or protein are presented. This methodology has the potential not only to guide soybean cultivar optimization processes but also to be expanded to other crops with only slight modifications.
Date: July 30, 2020
Creator: Moretti, Ademar; Arias, Cintia L.; Mozzoni, Leandro A.; Chen, Pengyin; McNeece, Brant T.; Mian, M. A. Rouf et al.
Object Type: Article
System: The UNT Digital Library
Computational Study of Methane C–H Activation by Main Group and Mixed Main Group–Transition Metal Complexes (open access)

Computational Study of Methane C–H Activation by Main Group and Mixed Main Group–Transition Metal Complexes

This article presents density functional theory (DFT) research where nine different molecules, each with different combinations of A (triel) and E (divalent metal) elements, were reacted to effect methane C–H activation.
Date: May 26, 2020
Creator: Carter, Carly C. & Cundari, Thomas R., 1964-
Object Type: Article
System: The UNT Digital Library
Parental transgenerational epigenetic inheritance related to dietary crude oil exposure in Danio rerio (open access)

Parental transgenerational epigenetic inheritance related to dietary crude oil exposure in Danio rerio

Article investigating the transgenerational inheritance from both parental lines in zebrafish. Adult zebrafish were separated into female and male groups exposed for 21 days to either a control diet or to a diet containing water accommodated fractions of crude oil. To determine the maternal and paternal influence on their offspring, the authors evaluated responses from molecular to whole organismal levels in both generations.
Date: January 22, 2020
Creator: Bautista, Naim M.; Crespel, Amélie; Crossley, Janna; Padilla, Pamela A. & Burggren, Warren W.
Object Type: Article
System: The UNT Digital Library
Remodeling the epigenome and (epi)cytoskeleton: a new paradigm for co-regulation by methylation (open access)

Remodeling the epigenome and (epi)cytoskeleton: a new paradigm for co-regulation by methylation

This article is a commentary on coordinated use of methyl marks to remodel both the epigenome and the (epi)cytoskeleton, which opens the possibility for integrated regulation (referred to as ‘epiregulation’) of other higher-level functions, such as muscle contraction or learning and memory, and could even have evolutionary implications.
Date: July 3, 2020
Creator: Walker, Cheryl & Burggren, Warren W.
Object Type: Article
System: The UNT Digital Library
Salt-water acclimation of the estuarine crocodile Crocodylus porosus involves enhanced ion transport properties of the urodaeum and rectum (open access)

Salt-water acclimation of the estuarine crocodile Crocodylus porosus involves enhanced ion transport properties of the urodaeum and rectum

This article reports that in addition to the well-documented functional plasticity of the lingual salt glands, the middle of the three cloacal segments (i.e. the urodaeum) responds to increased ambient salinity to enhance solute-coupled water absorption in estuarine crocodiles (Crocodylus porosus).
Date: July 16, 2019
Creator: Grosell, Martin; Heuer, Rachael M.; Wu, N. C.; Cramp, Rebecca L.; Wang, Yadong; Mager, Edward M. et al.
Object Type: Article
System: The UNT Digital Library