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Apparent Specific Volumes of Sucrose in Different Aqueous Cosolvent Mixtures at 298.2 K (open access)

Apparent Specific Volumes of Sucrose in Different Aqueous Cosolvent Mixtures at 298.2 K

This article explores research to determine the apparent specific volume of sucrose by measuring the density of sucrose in {cosolvent + water} mixtures at 298.2 K. The study finds that a mean apparent specific volume value of 0.632 cm³.g⁻¹ for sucrose in different aqueous-cosolvent mixtures could be adequate for practical purposes in pharmaceutical industries.
Date: December 30, 2018
Creator: Tinjacá, Darío; Muñoz, María M.; Martínez, Fleming; Jouyban, Abolghasem & Acree, William E. (William Eugene)
Object Type: Article
System: The UNT Digital Library
Foias Numbers (open access)

Foias Numbers

This article identifies the principal features in Foias’ original proof and streamlines them into a general result. The result gives further evidence to the observation that the connection between the sequence with initial seed the Foias constant and the Prime Number Theorem must be fortuitous.
Date: December 30, 2018
Creator: Anghel, Nicolae
Object Type: Article
System: The UNT Digital Library
Beyond the wall: High-throughput quantification of plant soluble and cell-wall bound phenolics by liquid chromatography tandem mass spectrometry (open access)

Beyond the wall: High-throughput quantification of plant soluble and cell-wall bound phenolics by liquid chromatography tandem mass spectrometry

Article describes a study in which a novel high-throughput ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC–MS/MS) method was established to quantify the levels of 19 flavonoids and 15 other phenolic compounds, including acids, aldehydes, and alcohols.
Date: December 26, 2018
Creator: Cocuron, Jean-Christophe; Casas, Maria Isabel; Yang, Fan & Grotewold, Erich
Object Type: Article
System: The UNT Digital Library
Continuum models of the electrochemical diffuse layer in electronic-structure calculations (open access)

Continuum models of the electrochemical diffuse layer in electronic-structure calculations

This article presents a critical comparison of continuum diffuse-layer models that can be coupled to an atomistic first-principles description of the charged metal surface in order to account for the electrolyte screening at electrified interfaces.
Date: August 31, 2018
Creator: Nattino, Francesco; Truscott, Matthew; Marzari, Nicola & Andreussi, Oliviero
Object Type: Article
System: The UNT Digital Library
Peptide signaling molecules CLE5 and CLE6 affect Arabidopsis leaf shape downstream of leaf patterning transcription factors and auxin (open access)

Peptide signaling molecules CLE5 and CLE6 affect Arabidopsis leaf shape downstream of leaf patterning transcription factors and auxin

Article describes a role in Arabidopsis leaf development for two members of the CLAVATA3/ESR‐RELATED peptide family, CLE5 and CLE6, which lie adjacent to each other on chromosome 2.
Date: December 20, 2018
Creator: DiGennaro, Peter; Grienenberger, Etienne; Dao, Thai Q.; Jun, Ji Hyung & Fletcher, Jennifer C.
Object Type: Article
System: The UNT Digital Library
Plasmonically-powered hot carrier induced modulation of light emission in a two-dimensional GaAs semiconductor quantum well (open access)

Plasmonically-powered hot carrier induced modulation of light emission in a two-dimensional GaAs semiconductor quantum well

Article describes an experiment in which a hot-electron-enabled route to controlling light with dissipative loss compensation in semiconductor quantum light emitters has been realized for tunable quantum optoelectronic devices via a two-species plasmon system.
Date: December 10, 2018
Creator: Ashalley, Eric; Gryczynski, Karol; Wang, Zhiming; Salamo, Gregory & Neogi, Arup
Object Type: Article
System: The UNT Digital Library
Identification and characterization of a core set of ROS wave‐associated transcripts involved in the systemic acquired acclimation response of Arabidopsis to excess light (open access)

Identification and characterization of a core set of ROS wave‐associated transcripts involved in the systemic acquired acclimation response of Arabidopsis to excess light

Article reveal that the systemic transcriptomic response of plants to excess light stress is extensive in the context of systemic acquired acclimation and involves an early (2 min) and transient stage of transcript expression that includes thousands of genes.
Date: December 6, 2018
Creator: Zandalinas, Sara I.; Sengupta, Soham; Burks, David; Azad, Rajeev K. & Mittler, Ron
Object Type: Article
System: The UNT Digital Library
Generalized molecular solvation in non-aqueous solutions by a single parameter implicit solvation scheme (open access)

Generalized molecular solvation in non-aqueous solutions by a single parameter implicit solvation scheme

Article presenting a systematic parametrization protocol for the Self-Consistent Continuum Solvation (SCCS) model resulting in optimized parameters for 67 non-aqueous solvents. The parametrization is based on a collection of ≈6000 experimentally measured partition coefficients, which were collected in the Solv@TUM database presented here. The accuracy of the optimized SCCS model is comparable to the well-known universal continuum solvation model (SMx) family of methods, while relying on only a single fit parameter and thereby largely reducing statistical noise.
Date: August 3, 2018
Creator: Acree, William E. (William Eugene); Hille, Christoph; Ringe, Stefan; Deimel, Martin; Kunkel, Christian; Reuter, Karsten et al.
Object Type: Article
System: The UNT Digital Library
Genome Mining of Plant NPFs Reveals Varying Conservation of Signature Motifs Associated With the Mechanism of Transport (open access)

Genome Mining of Plant NPFs Reveals Varying Conservation of Signature Motifs Associated With the Mechanism of Transport

This article focuses on four structural features of nitrate peptide families/proton-coupled oligopeptide transporters/peptide transporters that have been shown by structural and functional studies to be essential to proton-coupled symport transport.
Date: December 4, 2018
Creator: Longo, Antonella; Miles, Nicholas W. & Dickstein, Rebecca
Object Type: Article
System: The UNT Digital Library
Local and Systemic Metabolic Responses during Light-Induced Rapid Systemic Signaling (open access)

Local and Systemic Metabolic Responses during Light-Induced Rapid Systemic Signaling

This article reports that local application of light stress to one rosette leaf of bolting Arabidopsis (Arabidopsis thaliana) plants resulted in a metabolic response that encompassed local, systemic and transport tissues, demonstrating a high degree of physical and metabolic continuity between different tissues throughout the plant.
Date: December 2018
Creator: Choudhury, Feroza K.; Devireddy, Amith R.; Azad, Rajeev K.; Shulaev, Vladimir & Mittler, Ron
Object Type: Article
System: The UNT Digital Library
Genetic Mutations in the S-loop of Human Glutathione Synthetase: Links Between Substrate Binding, Active Site Structure and Allostery (open access)

Genetic Mutations in the S-loop of Human Glutathione Synthetase: Links Between Substrate Binding, Active Site Structure and Allostery

This article uses molecular dynamics simulations and experimental point mutations to probe the role of S-loop residues in tertiary structure, substrate binding, and allosteric communication.
Date: November 29, 2018
Creator: Ingle, Brandall L.; Shrestha, Bibesh; De Jesus, Margarita C.; Conrad-Webb, Heather M.; Anderson, Mary E. & Cundari, Thomas R., 1964-
Object Type: Article
System: The UNT Digital Library
Controlling Topological States in Topological/Normal Insulator Heterostructures (open access)

Controlling Topological States in Topological/Normal Insulator Heterostructures

This article contains a systematic investigation of the nature of the nontrivial interface states in topological/normal insulator (TI/NI) heterostructures.
Date: November 26, 2018
Creator: Costa, Marcio; Costa, Antônio T.; Freitas, Walter A.; Schmidt, Tome M.; Buongiorno Nardelli, Marco & Fazzio, Adalberto
Object Type: Article
System: The UNT Digital Library
Effects of Strategically Placed Water Droplets on Monolayer Growth of Molybdenum Disulfide (open access)

Effects of Strategically Placed Water Droplets on Monolayer Growth of Molybdenum Disulfide

This article presents results of molybdenum disulfide monolayer (MoS₂) growth by strategically placing water droplets on the growth substrate and/or in the source prior to its loading in the growth chamber.
Date: November 21, 2018
Creator: Jiang, Yan; Lin, Yuankun; Cui, Jingbiao & Philipose, Usha
Object Type: Article
System: The UNT Digital Library
Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe₂(CO)₄(κ²-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene) (open access)

Hydrogenase Biomimetics with Redox-Active Ligands: Synthesis, Structure, and Electrocatalytic Studies on [Fe₂(CO)₄(κ²-dppn)(µ-edt)] (edt = Ethanedithiolate; dppn = 1,8-bis(Diphenylphosphino)Naphthalene)

This article reports the preparation and characterisation of the simple dppn complex,[Fe2(CO)4(κ2-dppn)(µ-edt)], together with an investigation of its proton-reduction ability.
Date: November 20, 2018
Creator: Ghosh, Shishir; Rana, Shahed; Hollingsworth, Nathan; Richmond, Michael G.; Kabir, Shariff E. & Hogarth, Graeme
Object Type: Article
System: The UNT Digital Library
Diabetes Treatment with Sunshine captions transcript

Diabetes Treatment with Sunshine

Video from the Fall 2018 3 Minute Thesis (3MT®) Final Competition. In this video, Sujata Argawal presents her research methods, findings, and its significance in non-technical language.
Date: November 17, 2018
Creator: Argawal, Sujata
Object Type: Video
System: The UNT Digital Library
Immunized Plants: An Answer to Global Hunger captions transcript

Immunized Plants: An Answer to Global Hunger

Video from the Fall 2018 3 Minute Thesis (3MT®) Final Competition. In this video, Devasantosh Mohanty presents his research methods, findings, and its significance in non-technical language.
Date: November 17, 2018
Creator: Mohanty, Devasantosh
Object Type: Video
System: The UNT Digital Library
Improving Reliability and Failure Prevention in Automobile Microelectronics captions transcript

Improving Reliability and Failure Prevention in Automobile Microelectronics

Video from the Fall 2018 3 Minute Thesis (3MT®) Final Competition. In this video, Muthappan Asokan presents his research methods, findings, and its significance in non-technical language.
Date: November 17, 2018
Creator: Asokan, Muthappan
Object Type: Video
System: The UNT Digital Library
A random walk version of Robbins' problem: small horizon (open access)

A random walk version of Robbins' problem: small horizon

This article considers an analogous problem in which the observed random variables are the steps of a symmetric random walk. Assuming continuously distributed step sizes, it describes the optimal stopping rules for the cases n = 2 and n = 3 in two versions of the problem: a "full information" version in which the actual steps of the random walk are disclosed to the decision maker; and a "partial information" version in which only the relative ranks of the positions taken by the random walk are observed. When n = 3, the optimal rule and expected rank depend on the distribution of the step sizes. The authors give sharp bounds for the optimal expected rank in the partial information version, and fairly sharp bounds in the full information version.
Date: November 17, 2018
Creator: Allaart, Pieter C. & Allen, Andrew
Object Type: Article
System: The UNT Digital Library
Pyrene Bearing Azo-Functionalized Porous Nanofibers for CO₂ Separation and Toxic Metal Cation Sensing (open access)

Pyrene Bearing Azo-Functionalized Porous Nanofibers for CO₂ Separation and Toxic Metal Cation Sensing

This article describes the construction of a novel luminescent azo-linked polymer from 1,3,6,8-tetra(4--aminophenyl)pyrene using a copper(I)-catalyzed oxidative homocoupling reaction.
Date: August 6, 2018
Creator: El-Kadri, Oussama M.; Tessema, Tsemre-Dingel; Almotawa, Ruaa M.; Arvapally, Ravi K.; Al-Sayah, Mohammad H.; Omary, Mohammad A. et al.
Object Type: Article
System: The UNT Digital Library
Computational Topology Techniques Help To Solve A  Long-Lasting Forensic Dilemma: Aldo Moro's Death (open access)

Computational Topology Techniques Help To Solve A Long-Lasting Forensic Dilemma: Aldo Moro's Death

The article shows how a recently-introduced method from algebraic topology, namely proximal planar vortex 1-cycles, might be helpful in detecting hidden features of the shapes and holes in images, therefore contributing to the solution of both cold and fresh forensic cases. They apply this technique in a recent case, Aldo Moro's death.
Date: November 13, 2018
Creator: Peters, James F. & Tozzi, Arturo
Object Type: Article
System: The UNT Digital Library
Rapid Responses to Abiotic Stress: Priming the Landscape for the Signal Transduction Network (open access)

Rapid Responses to Abiotic Stress: Priming the Landscape for the Signal Transduction Network

This article proposes that the integration of these signals is mediated through pulses of gene expression that are coordinated through out the plant in a systemic manner by the ROS/Ca⁺² waves.
Date: November 3, 2018
Creator: Kollist, Hannes; Zandalinas, Sara I.; Sengupta, Soham; Nuhkat, Maris; Kangasjärvi, Jaakko & Mittler, Ron
Object Type: Article
System: The UNT Digital Library
Polarizable ab initio QM/MM Study of the Reaction Mechanism of N-tert-Butyloxycarbonylation of Aniline in [EMIm][BF4] (open access)

Polarizable ab initio QM/MM Study of the Reaction Mechanism of N-tert-Butyloxycarbonylation of Aniline in [EMIm][BF4]

This article presents the use of AMOEBA-based polarizable ab initio AM/MM simulations to investigate the reaction mechanism of the N-tert-butoxycarbonylation of aniline in a water/1-ethyl, 3-methyl imidazolium/tetrafluoroborate mixture.
Date: October 31, 2018
Creator: Vázquez-Montelongo, Erik Antonio; Vázquez-Cervantes, José Enrique & Cisneros, Gerardo Andrés
Object Type: Article
System: The UNT Digital Library

Triplet electron transfer and spin polarization in a palladium porphyrin–fullerene conjugate

Access: Use of this item is restricted to the UNT Community
This article uses Transient electron paramagnetic resonance (TREPR) spectroscopy to investigate the pathway and dynamics of electron transfer in a palladium porphyrin–fullerene donor–acceptor conjugate.
Date: October 29, 2018
Creator: Poddutoori, Prashanth K.; Kandrashkin, Yuri E.; Obondi, Christopher O.; D'Souza, Francis & van der Est, Art
Object Type: Article
System: The UNT Digital Library
The 2019 materials by design roadmap (open access)

The 2019 materials by design roadmap

This roadmap article presents an overview of the current state of computational materials prediction, synthesis and characterization approaches, materials design needs for various technologies, and future challenges and opportunities that must be addressed.
Date: October 24, 2018
Creator: Alberi, Kirstin; Buongiorno Nardelli, Marco; Zakutayev, Andriy; Mitas, Lubos; Curtarolo, Stefano; Jain, Anubhav et al.
Object Type: Article
System: The UNT Digital Library