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Dioxygen: What Makes This Triplet Diradical Kinetically Persistent? (open access)

Dioxygen: What Makes This Triplet Diradical Kinetically Persistent?

This article examines experimental heats of formation and enthalpies obtained from G4 calculations to find that the resonance stabilization of the two unpaired electrons in triplet O₂, relative to the unpaired electrons in two hydroxyl radicals, amounts to 100 kcal/mol.
Date: June 14, 2017
Creator: Borden, Weston T.; Hoffmann, Roald; Stuyver, Thijs & Chen, Bo
System: The UNT Digital Library
Tracing the accretion history of supermassive black holes through X-ray variability: results from the Chandra Deep Field-South (open access)

Tracing the accretion history of supermassive black holes through X-ray variability: results from the Chandra Deep Field-South

This article studies the X-ray variability properties of distant active galactic nuclei (AGNs) in the Chandra Deep Field-South region over 17 yr, up to z ~ 4, and compare them with those predicted by models based on local samples.
Date: July 14, 2017
Creator: Paolillo, Maurizio; Papadakis, I.; Brandt, William Nielsen; Luo, Bin; Xue, Yongquan; Tozzi, Paolo et al.
System: The UNT Digital Library
Epigenetic reprogramming converts human Wharton's jelly mesenchymal stem cells into functional cardiomyocytes by differential regulation of Wnt mediators (open access)

Epigenetic reprogramming converts human Wharton's jelly mesenchymal stem cells into functional cardiomyocytes by differential regulation of Wnt mediators

This article studies the differentiation of human Wharton's jelly mesenchymal stem cells into the cardiomyocyte lineage via epigenetic manipulations.
Date: May 24, 2017
Creator: Bhuvanalakshmi, G.; Arfuso, Frank; Kumar, Alan Prem; Dharmarajan, Arunasalam & Warrier, Sudha R.
System: The UNT Digital Library